Добавил:
Опубликованный материал нарушает ваши авторские права? Сообщите нам.
Вуз: Предмет: Файл:

Новые достижения в химии и химической технологии растительного сырья. Материалы III всероссийской конференции. Книга 2 [2007]

.pdf
Скачиваний:
38
Добавлен:
10.08.2013
Размер:
36.37 Mб
Скачать

!"#$ %&'#" " (")*+, (&-./0 1&(+2&3& -'"4$#,5* -'" 4&6$%04$##&7 1&($8#", '$940*"84$, -&:03'$, )0/0'#&4 :"01$*$, 30)*'"*0/, ,89$ ;$- (.:%0, '0:"%.("*0/, #$9'0(3",/, 8(&%06$)*9$##</ #&9&&1'08&90#",/.

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

B&-./ 1&(+2&7 "4$$* &12"'#<7 0'$0( -'&"8'0)*0#",, 9 D(*07- )%&4 %'0$ '0)-'&)*'0#$# -&9)$4$)*#&. E'&9$:$##<$ '$).')&9$:6$)%"$ "))($:&90#", -&%08<905* 9&84&;#&)*+ -'&4<2($##</ 803&*&9&% (&- -./0 1&(+2&3& 9& 9)$/ '07/ %'0,. F'&4$ *&3&, "4$$*), 4#&3&($*#"7 &-<* 99$:$#", '0)*$#", 9 %.(+*.'. 80 '.1$;&4. G"4"6$)%"7 )&)*09 (")*+$9 (&-./0 1&(+2&3& "8.6$# #$:&)*0*&6#&.

H$(+5 '01&*< ,9(,(&)+ "8.6$#"$ /"4"6$)%&3& )&)*090 (")*+$9 " -'$-0'0*&9 (&-./0 1&(+2&3&, -'&"8'0)*05?$3& 9 D(*07)%&4 %'0$.

I %06$)*9$ &1J$%*&9 "))($:&90#", ")-&(+8&90(" )9$;$$ " 9&8:.2- #&-)./&$ )<'+$, #0)*&7, )&% )9$;"/ (")*+$9, )./&7 @%)*'0%*.

K0)*"*$(+#&$ )<'+$ 803&*09("90(" 9 '08("6#</ -& %("40*"6$)%"4

.)(&9",4 " .'&9#5 *$/#&3$##&7 #03'.8%" '07/ D(*07)%&3& %'0, 80 -$'"&: ) 2001 -& 2005 3. L%)*'0%* (")*+$9 )./&7 -&(.6$# 4$*&:&4 '$- 40!$'0!"" ) ")-&(+8&90#"$4 9 %06$)*9$ @%)*'03$#*0 9&:< &6"?$##&7. M&% 3&*&9"(" -.*$4 -'$))&90#", )9$;"/ (")*+$9.

N(, "8.6$#", /"4"6$)%&3& )&)*090 (")*+$9 " -'$-0'0*&9 (&-./0 1&(+2&3& -'&9&:"(" %06$)*9$##<7 " %&("6$)*9$##<7 0#0("8.

O8.6$#"$ )&)*090 >$#&(+#</ )&$:"#$#"7 9 (")*+,/ (&-./0 1&(+2&3& -'&9&:"(" /"4"6$)%"4" " >"8"%&-/"4"6$)%"4" 4$*&:04". N(, 9<:$($#", >$#&(+#</ )&$:"#$#"7 "8 '0)*"*$(+#&3& )<'+, ")-&(+8&90(" @%)*'0%!"5 )-"'*&4 @*"(&9<4 70%, ) -&)($:.5?$7 @%)*'0%!"#&7 " /'&40*&3'0>"- 6$)%&7 &6")*%&7. O:$#*">"%0!"5 >(09&":&9 -'&9&:"(" 4$*&:&4 1.- 40;#&7 " *%&)(&7#&7 /'&40*&3'0>"". E&:1"'0(" .)(&9", /'&40*&3'0- >"'&90#", " .)*0#&9"(" (.62.5 '08:$(,5?.5 )-&)&1#&)*+ )")*$4< PQI (6 : 1 : 4) #0 -(0)*"#%0/ «Sorbfil». N(, :$*$%*"'&90#", 9$?$)*9 ")-

260

!"#$%"&'#( )'%#(*+,- .)"/"0-++,- )-'0-+1, (2!()1"&,3 )'21&") '#4/(- +(5 .#")(6' 1%, 2!()1"&,3 )'21&") 7-#-%' (III) .#")(6' 1%, !'), '//('- 8', )'21&") 29#$:';(#' +'1)(5 6('%"1()"&'++,3). <"!"#+(1-#$+94 (+- :")/';(4 " 21)9819)- :-+"#$+,. 2"-6(+-+(3 !"#9*'#( 2 (2!"#$%"&'+(-/ /-1"6' =>?@. A21'+"-+" +'#(*(- 10 2"-6(+-+(3 :-+"#$+"3 !)()"6,, (% 8"1"),. (6-+1(:(;()"&'+, )91(+, 8&-);-1(+, '!(0-+(+, .#")"0-+"&'5 8(2#"1' ( -- !)"(%&"6+,-.

B)(1-)(5/( ";-+8( 2#97(#( &)-/-+' 96-)7(&'+(5 ( 2!-81), 'C- 2")C;(( &-D-21&. <"/(+()94D(/( 2"-6(+-+(5/( 5#(2$ )91(+ ( !)"(%&"6+"- .#")"0-+"&"3 8(2#"1, 2 &)-/-+-/ 96-)7(&'+(5 10,5 /(+.

E)( (22#-6"&'+(( 29."0" F821)'81' /-1"6"/ =>?@ 921'+"-+" +'#(*(- :#'&"+"(6"& ( :-+"#"8(2#"1, (6-+1(:(;()"&'+, )91(+ (

.#")"0-+"&'5 8(2#"1'.

G9//9 '#8'#"(6"& (%-8'#( (% 2,)$5 & &(6- 2"#-3 2 !"/"D$4 8(2#"1, .#")(21"&"6")"6+"3 1%, !"2#- F821)'8;("++"3 ( .)"/'1"- 0)':(*-28"3 "*(218( (22#-6"&'#( &-D-21&' 2 !"/"D$4 AH-GHI, JB- GHI, =>?@. = ."6- (22#-6"&'+(3 921'+"-+", *1" '#8'#"(6, #"!9-

.' C"#$K"0" !)-621'ȝ 2#"7+94 2/-2$ &-D-21&.

I-1"6"/ =>?@-IG "!)-6-#-+, /"#-89#5)+,- /'22, +-8"1"),. '#8'#"(6"&, ' 1'87- 921'+"-+" +'#(*(- *-1+"0" *(2#' '1"/"& '%"1' & (. 21)9819)-. A21'+"&(1$ .(/(*-2894 21)9819)9 &,6-#-++,. '#8'#"(- 6"& +- !)-621'&(#"2$ &"%/"7+,/.

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n-6"8"%'+, 0-82'1)('8"+1'+', 0-!1'8"%'+.

I-1"6"/ '1"/+"-'C2")C;("++"3 2!-81)":"1"/-1)((, (+&-)2("+- +"3 &"#$1'/!-)"/-1)(( 921'+"-+" 2"6-)7'+(- 7-#-%' (128,40 /0/80), 8"C'#$1' (2,59 /0/80), +(8-#5 (1,48 /0/80), ;(+8' (7,4 /0/80), /-6( (7,4 /0/80) & #(21$5. #"!9.' C"#$K"0". E)"&-6-+' F8"#"0(*-28'5 ";-+8' 2,- )$5, 2"8' ( F821)'81'. G"6-)7'+(- "2"C" 1"82(*+,. F#-/-+1"& +- !)-- &,K'#" 6"!921(/"0" 9)"&+5, 921'+"-++"0" G'+E(L 2.3.2.1078-01.

261

!"#$%&%' (#)*+%,-$%''./ 0'0)*1 '%(#-#".2 3"455 6*#)#3*+%,(* 0(- -*$'.2 ,#%&*'%'*/. 7,-0'#$)%'#, +-# (#)*+%,-$%''#% ,#&%"80'*% &4- 6*)9'.2 $%:%,-$ $ )*,-9;2 )#5420 6#)9<#3# ,#,-0$*)# 6,61–8,38%, $ ,#(%

– 15,15%, $ =(,-"0(-% – 23,89%; >)0$#'#*$ $ )*,-9;2 – 1,27–1,35%, $ ,#(% – 0,68%, $ =(,-"0(-% – 2,35%; 0,(#"6*'#$#/ (*,)#-. $ )*,-9;2 – 26,9– 38,05 ?3%, $ ,#(% – 141,0 ?3%, $ =(,-"0(-% – 918,0 ?3%, ,4??0 0)(0)#*$ $ )*,-9;2 – 0,04%, ,4??0 )*5#>*)9'.2 $%:%,-$ – 3,3%, *1 '*2 2)#"#>*)- ). 1,28–1,45%, (0"#-*'#*&. 5,80–7,72 ?3%; 5#)*,020"*$ $ )*,-9;2

5,26–6,01%, $ ,#(% – 0,26%, $ =(,-"0(-% – 22,7% (-06).).

!"#$%"

!"#$%&%'# (#?5)%(,'#% *14+%'*% )*,-9%$ )#5420 6#)9<#3# >)#". @)-0;. 7,-0'#$)%'# '0)*+*% $ *,,)%&4%?#? )%(0",-$%''#? "0,-*-%)9- '#? ,."9% * 5"%50"0-02 &46*)9'.2 $%:%,-$, >)0$#'#*$ ("4-*'0, ($%"A%-*'0, 05*3%'*'0), >%'#)#(*,)#- (2)#"#3%'#$#/ (*,)#-. * %% 5"#*1$#&'.2), 5#)*,020"*$, 0)(0)#*$, 0,(#"6*'#$#/ (*,)#-., (0- "#-*'#*$, 8*"'.2 (*,)#-, ?*'%"0)9'.2 ,#)%/.

B#)*+%,-$%''# #5"%&%)%'. #,'#$'.% 6*#)#3*+%,(* 0(-*$'.% ,#- %&*'%'*; $ )*,-9;2 )#5420 6#)9<#3# * 5"%50"0-02 '0 *2 #,'#$%: >)0- $#'#*$ (,."9% – 1,4%, ,#( – 0,7%, ,42#/ =(,-"0(- – 2,4%), &46*)9'.2 $%:%,-$ (,."9% – 8,4%, ,#( – 15,1%, =(,-"0(- – 23,8%), 5#)*,020"*$ (,."9% – 6,0%, ,#( – 0,26 %, =(,-"0(- – 22,7 %), 0,(#"6*'#$#/ (*,)#-.

(,."9% – 38,1 ?3%, ,#( – 141,0 ?3%, =(,-"0(- – 918 ?3%).

C%-#? DEFGCH 4,-0'#$)%'. #"*%'-*"#$#+'.% ?#)%(4);"- '.% ?0,,. '%(#-#".2 0)(0)#*$ )#5420 6#)9<#3# * '0)*+*% +%-'#3# +*,)0 0-#?#$ 01#-0 $ *2 ,-"4(-4"%. B#)*+%,-$%''#% ,#&%"80'*% 0)(0- )#*$ ,#,-0$*)# – 0,04%.

H#&%"80'*% 6*#)#3*+%,(* 0(-*$'.2 ,#%&*'%'*/ $ )*,-9;2, ,#(% * =(,-"0(-% )*,-9%$ )#5420 6#)9<#3#

I"4550 6*#)#3*+%,(*

J*,-9;

H#( ,$%8*2

E(,-"0(-

0(-*$'.2 ,#%&*'%'*/

)*,-9%$

 

 

K46*)9'.% $%:%,-$0, %

8,38!0,51

15,15!0,32

23,89!0,15

L)0$#'#*&., %

1,27!0,12

0,68±0,02

2,35±0,10

@,(#"6*'#$0; (*,)#-0, ?3%

38,05±1,03

141,0±1,62

918,0±14,31

@)(0)#*&., %

0,039±0,004

G)#"#>*))., %

1,28±0,04

B0"#-*'#*&., ?3%

7,72±0,23

!#)*,020"*&., %

6,01±0,12

0,26±0,01

22,7±0,21

262

!"#$%$&$' ()*$+,-$''./ +0+,)- &1"021&3'0/ 2#)(411 (")&351- ,1'0-)6, &1'0&$'0-)6 (1+&0,., 1,9–,$,#)%$()%1$', 1–')2,)&$'- "#0")'0&, 7#80+,–7–$'–3–0&, n–%0(09)', 8$(+),#1)(0',)', 8$",)(09)', ()#0,1'01%., :&0#021&&.). ;<55) &1"021&3'.: -$=$+,- - &1+,36: &0"<:) >0&3?080 – 3,30%, 19 '1: :&0#021&&0- – 1,50 %, ()#0,1'01%0-

– 7,24 58%.

@$,0%05 ),05'0)>+0#>410''0/ +"$(,#020,05$#11 - &1+,36: &0- "<:) >0&3?080 <+,)'0-&$'0 +0%$#A)'1$ A$&$9) (128,40 58/(8), (0>)&3,)

(2,59 58/(8), '1($&6 (1,48 58/(8), 41'() (7,40 58/(8), 5$%1 (7,40 58/(8).

;0%$#A)'1$ 0+0>0 ,0(+1*'.: 7&$5$',0- (+-1'4), ()%516, 5.?36(), #,<,1) - +.#3$, +0($ 1 7(+,#)(,$ '$ "#$-.?)$, %0"<+,15080 <#0-'6, <+,)'0-&$''080 '0#5),1-'0/ %0(<5$',)41$/.

!"#$%"&"'()*$( "))+(,$-./"( ARTEMISIA

PONTICA L. !+$01 )"2"0"

,.+. &3435673, &... %38983, -.:. .;<=>?<846

!"#"$%&%'$(%) *"$+,-'$.#/001) 2/,%3%0$(%) +0%#/'$%./., !"#"$%&%'$( (4"$$%5)

6%&%'$(%) &".-0%7/$(%) $-, 8'% 9:;, 9"2$( (4"$$%5)

!"#$#%

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

!%'15 19 ,)(1: #)+,$'1/ 6-&6$,+6 Artemisia pontica L., "#15$- '6C=)6+6 - ')#0%'0/ 5$%141'$ ()( -09><A%)C=$$ )""$,1,, <&<*-

263

!"#$%% &'$%(")%*'%, +,-").'("#$%%, "*,'/%012'*,*+%, ,+*'3')4#- $%% 5)%65,(+, &)'2%*70+51 &)' 8)+*-'"01*+9 "5,2%, +&4-+07- [1, 2]. :6*".+ *%52+,)7 *" 2*+/+(%.+(+% '5&+013+("*'%, 6%,"01*;9 -'2'<%- 5.'9 "*"0'3 6"**+/+ )"5,%*'7 *% &)+(+6'057. =+>,+24 ?%01# *"!%/+ '550%6+("*'7 7('0+51 &)+(%6%*'% 5)"(*',%01*+/+ @',+-'2'<%5.+/+ "*"0'3" *"63%2*+9 <"5,' A. pontica 607 45,"*+(0%*'7 +&,'2"01*+/+ ()%2%*' ' 2%5," 58+)" 5;)17.

A",%)'"0 '550%6+("*'7 (*"63%2*"7 <"5,1 A. pontica) 8;0 5+8)"* ( %5,%5,(%**;- 2%5,"- &)+'3)"5,"*'7 (5,%&*"7 3+*" B")"8'*5.+9 0%5+- 5,%&', C")/",5.'9 )"9+*; D0,"95.+/+ .)"7) ' '3 2%5, .401,'(')+("*'7 (>.5&%)'2%*,"01*;% 4<"5,.' E'8')5.+/+ 8+,"*'<%5.+/+ 5"6" &)' FGH, F+25.; 5. I%&1%(+, F+/4<'*5.'9 )"9+*, JE:).

!"#$%& '(()"%$*+,'-

K)".?'+**;9 5+5,"( &+0'5"-")'6+( '550%6+("0' /)"('2%,)'<%- 5.'2 2%,+6+2 [3]; "*"0'3 /'6)+.5'.+)'<*;- .'50+, ' @0"(+*+'6+( (;&+0*70' 5&%.,)+@+,+2%,)'<%5.'2 ' -)+2",+5&%.,)+@+,+2%,)'<%- 5.'2 2%,+6"2' (842"/" – «L%*'*/)"65."7 5)%6*77», 5'5,%2" )"5,(+- )',%0%9 .'50+," 4.545*"7 2% ' «L%*'*/)"65."7 2%60%**"7», 5'5,%- 2" )"5,(+)',%0%9 .'50+," 4.545*"7 15% 5++,(%,5,(%**+).

F"80'?" 1. M")".,%)'5,'." 2%5," ' ()%2%*' 58+)" 5;)17 Artemisia

pontica L.

N M")".,%)'5,'." 2%5," 58+)", ()%27 58+)", @"3" )"3(','7 )"5,%*'7 +8)"3?"

1J+(+5'8')5."7 +80"5,1, C")/",5.'9 )"9+*, 38 .2 +, /. C")/",,

11.08.06, ,)"(", @"3" (%/%,"?''

2D0,"95.'9 .)"9, D0%95.'9 )"9+*, 20.08.06, ,)"(", @"3" (%/%,"?''

3/. F+25., E'8')5.'9 8+,"*'<%5.'9 5"6 &)' FGH, 22.08.06, ,)"(", @"3" (%/%,"?''

4J+(+5'8')5."7 +80"5,1, C")/",5.'9 )"9+*, 38 .2 +, /. C")/",, 11.08.06, ,)"(", @"3" 84,+*'3"?''

5D0,"95.'9 .)"9, D0%95.'9 )"9+*, 16.08.06, ,)"(", @"3" 84,+*'3"- ?''

6/. F+25., E'8')5.'9 8+,"*'<%5.'9 5"6 &)' FGH, 22.08.06, ,)"(", @"3" 84,+*'3"?''

7J+(+5'8')5."7 +80"5,1, C")/",5.'9 )"9+*, 38 .2 +, /. C")/",, 11.08.06, ,)"(", @"3" ?(%,%*'7

8

D0,"95.'9 .)"9, D0%95.'9 )"9+*, 20.08.06, ,)"(", @"3" ?(%,%*'7

9

/. F+25., E'8')5.'9 8+,"*'<%5.'9 5"6 &)' FGH, 22.08.06, ,)"(",

 

@"3" ?(%,%*'7

10J+(+5'8')5."7 +80"5,1, F+/4<'*5.'9 )"9+*, 5. I%&1%(+, 26.08.06, ,)"(", @"3" ?(%,%*'7

264

!"#$%&'(')

!"#$%$&$'($ )#*+,(-''-.- /-/0*1* "-&(/*2*#(%-1 1 /3#4$ A. pontica "-+*5*&- '*&(6($ 0*+(2 .#7"" +*+ 1-%-#*/01-#(83$ "-&(/*- 2*#(%3, "$+0('-13$ 1$9$/01*, .$8(,$&&:&-53 ;, .$8(,$&&:&-53 <.

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

K*>&(,* 2. =-%$#@*'($ )#*+,(B "-&(/*2*#(%-1 (1 % -0 1-5%7?'-- /72-.- /3#4A)

L

<-%-#*/01-#(8*A

F$+0('-13$

M$8(,$&&:&-53

M$8(,$&&:&-53

->#*5,*

)#*+,(A

1$9$/01*

;

<

1

9,3 ± 0,2

3,9 ± 0,1

6,8 ± 0,2

2,3 ± 0,1

2

5,5 ± 0,1

7,1 ± 0,3

10,6 ± 0,4

2,6 ± 0,1

4

6,8 ± 0,1

3,5 ± 0,1

12,6 ± 0,4

3,8 ± 0,2

5

5,0 ± 0,1

5,4 ± 0,1

8,4 ± 0,3

2,9 ± 0,1

7

6,8 ± 0,2

3,5 ± 0,1

16,3 ± 0,5

3,6 ± 0,2

8

5,4 ± 0,1

3,9 ± 0,2

10,9 ± 0,4

2,9 ± 0,1

9

5,6 ± 0,1

2,4 ± 0,1

13,6 ± 0,4

3,2 ± 0,1

10

6,8 ± 0,2

4,8 ± 0,2

10,7 ± 0,3

2,5 ± 0,1

265

!"#$%'"%()*+,-). %/%0)1 (0%2#/#)3#2 4#-%1%0 /%0)*)+ 8 2+- 5+,&2 (0%2#/#)3/#. ,&"6-&6"7 ()1 -#"78 )3+/&)()9)"#2%/ "6&)/). :4+-&"#(#$+&")*+,-#+ #4"+3+0+/)+ ,#3+";%/)< 2+5+,&2 4"#2#3)- 0#,= 2 >0?%&%8 , 8"#$%'"%$$ ) 2 ),8#3/78 ,4)"Ė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– 7,49 ) 6,80% (:)BF:, '. G#$,- ) D:H, ,. I+4=+2# ,##&2+&,&2+//#).

!"#$%"

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

!"#$%'%&

1.I%,&)&+0=/7+ "+,6",7 :::I. L2+&-#27+ "%,&+/)<, )8 8)$)*+,-). ,#- ,&%2, ),4#0=1#2%/)+. :+$. Asteraceae. :KB., 1993. :. 7–13.

2.G%"%/ M.M. K"#&)2#2#,4%0)&+0=/7+ ) "%/#1%;)20<?5)+ ,2#.,&2% >()"/78 $%,+0 /+-#"78 2)3#2 4#07/+. ) &7,<*+0),&/)-%: 3),. … -%/3.B)#0./%6-. G#$,-, 1983. :. 16–18.

3.:$)"/#2% N.O. P,,0+3#2%/)+ 4#0),%8%")3#2 -60=B%B7 #,+//+. Leotodon autumnalis L. // O-&6%0=/7+ 4"#B0+$7 ,#13%/)< /#278 0+- -%",&2+//78 4"+4%"% 4")"#3/#'# 4"#),8#;3+/)<: ,B. $%&+". ! $+;36/%"#3/#'# ,Q+13% R)(%"$ 2006. :KB., 2006. :. 292–293.

266

!"#$%&%''(% )"*+"*( , !-.'*.$-/0.1// !($23 / )$%).$.-"# 4/!-"-%5. 6"527"8"

%.!. .9:;<=>=?;

!"#"$%&'( )*%+,"$%-./001( #/,'2'0%&'( +0'./$%'-/-, +3. 4"5"/.%&"6, 89, !"#"$", 443099 (7*%%'6)

E-mail: vakur@samaramail.ru

!"#$# %&'()(*+# ,)+-.)/) (Chelidonium majus L., '*0. 1#2)$3* !"#averaceae) &45#$6# 7"&0*68*('8 $ 0*5&9&6'2): 7"#2(&2* & ),+#5#*( "#46)'()")66*: ;#"0#2)+)/&%*'2): #2(&$6)'(-<, 2)()"#8 ),='+)$+*6# 7"&'=('($&*0 "85# 7"&")563> ,&)+)/&%*'2& #2(&$63> ')*5&6*6&: (?@A), $2+<%#8, $ 7*"$=< )%*"*5-, #+2#+)&53, ;+#$)6)&53, '#7)6&63, 2#")(&6)&53, )"/#6&%*'2&* 2&'+)(3 & 5". [1, 2]. B#6** =%*630& A#0- C1D ,3+) ='(#6)$+*6), %() $)7"*2& ),E*7"&68()0= 06*6&< )'6)$630 #+2#+)&5)0 8$+8*('8 6* >*+&5)6&6, # 2)7(&4&6 [3, 6]. F")0* ()/), "#4"#- ,)(#6) 6)$)* +*2#"'($*66)* '"*5'($) «G&'()(*+# 6#'():2#»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

K*+- 6#'()8E&> &''+*5)$#6&: "#4"#,)(2# ),J*2(&$63> 0*()5)$ '(#65#"(&4#9&& ("#$3 %&'()(*+# ,)+-.)/) & 7"*7#"#()$ 6# */) )'6)$*.

L 2#%*'($* ),J*2(# &''+*5)$#6&8 '+=H&+& ),"#493 ("#$3 %&'()- (*+# ,)+-.)/), '),"#663* $ 7*"&)5 ' 0#8 7) &<+- 2005 /. & 2006 /. $ )2"*'(6)'(8> A#0#"3 & A#0#"'2): ),+#'(& ()2". '. L)'2"*'*62#); $)5- 6)-'7&"()$3* &4$+*%*6&8 &4 $)45=.6)-'=>): & '$*H*'),"#66): ("#$3 %&'()(*+# ,)+-.)/); ),"#493 6#'():2& %&'()(*+# ,)+-.)/), 7)+=%*6-

267

!"# $% &'(&')%*'!!%+ *#,!%-%.// / 0*'!1'&*!"2/ 2#*%1'2/ / &')%3/+ 0*'!1'&*!"+ %)&'(#4 (567) 8%$*/(/!'.

9(2#-:3#!!%# (3–5 22) ;%(1<=!%-0<,%# &'0*/*#-:!%# 0"&:# 3/0- *%*#-' )%-:=%.% (150 .) >80*&'./&%;'-/ 1#0?*/8&'*!"2 8%-/3#0*;%2 70% >*/-%;%.% 0$/&*' 2#*%1%2 !'0*'/;'!/?. @-? $%-!%.% /0*%A#!/? 0"&:? 1;# $%0-#1<BA/# >80*&'84// $&%;%1/-/ ; <0-%;/?, 8/$?A#.% &'0*;%&/*#-?. 7)C#1/!#!!"# >80*&'8*" <$'&/;'-/ !' &%*'4/%!!%2 <$'&/*#-# $%1 ;'8<<2%2 $&/ *#2$#&'*< 40–60 6. 6.<A#!!"+ >80- *&'8* ;"0<=/;'-/ !' 0/-/8'.#-# L 40/100 (30 .).

D$'&'*/;!%# &'(1#-#!/# >80*&'8*/;!", ;#A#0*; %0<A#0*;-?-/ 2#*%1%2 '10%&)4/%!!%+ 8%-%!%3!%+ ,&%2'*%.&'E// 0 /0$%-:(%;'!/#2 0/-/8'.#-? 2'&8/ L 40/100 282 (F#,/?). G ,&%2'*%.&'E/3#08<B 8%-%!8< !' 0-%+ 0/-/8'.#-?, 0E%&2/&%;'!!"+ ; ,-%&%E%&2# (;"0%*' 0%&)#!*' – 8 02, 1/'2#*& – 6 02), $#!%0/-/ 0<,%+ $%&%=%8 (>80*&'8*+0/-/8'.#-:). H%-%!8< >-B/&%;'-/ ,-%&%E%&2%2, ' *'8I# ,-%&%E%&2%2, 0%1#&I'A/2 ; &'(-/3!", 8%!4#!*&'4/?, >*/-%;"+ 0$/&* (3, 5, 7, 10, 15, 20, 30, 40%).

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«H%$*/(/!-0*'!1'&*!"+ %)&'(#4».

6/0$%-:(%;'!/#2 567 8%$*/(/!' &'(&')%*'!" 2#*%1/8/ 8'3#0*- ;#!!%.% / 8%-/3#0*;#!!%.% '!'-/(' ;%1!%-0$/&*%;", /(;-#3#!/+ /( *&';" 3/0*%*#-' )%-:=%.%. K6L-'!'-/( >80*&'8*%; $&%;%1/-/ ; 0/0*#- 2# &'0*;%&/*#-#+ ,-%&%E%&2:2#*'!%-:;%1' (26 : 14 : 3). P' ,&%2'*%-

.&'22# !' <&%;!# $?*!' 567 8%$*/(/!' %)!'&<I/;'#*0? 1%2/!/&<B-

A## $?*!% 0 ;#-/3/!%+ Rf %8%-% 0,45, /2#BA## I#-*<B %8&'08< ; ;/- 1/2%2 0;#*# / ?&8%-I#-*<B E-<%#!4/B $&/ $&%02%* ,&%2'*%-

.&'22" ; MJ-0;#*# $&/ 1-/!# ;%-!" 366 !2, ' *'8I# 8/&$/3!%- 8&'0!<B %8&'08< $&/ $&%?;-#!// '8*/;%2 @&'.#!1%&E' (8%$*/(/!).

64#-:B &'(&')%*8/ 2#*%1/8/ 8%-/3#0*;#!!%.% %$#-#!/? 0<22" '-8'-%/1%; ; *&';# 3/0*%*#-' )%-:=%.% /(<3#!" MJ-0$#8*&" ;%1!%- 0$/&*%;", /(;-#3#!/+ /( 1'!!%.% 0"&:?. 5#./0*&'4/B 0$#8*&%; $&%;%1/- -/ 0 $%2%A:B 0$#8*&%E%*%2#*&' Specord 40 (Analytik Jena). P'/)%-## $%- 8'('*#-:!"2 1-? MJ-0$#8*&%; &'0*;%&' 8%$*/(/!' / 1-? %3/A#!!%.% !'

268

!"#$%& '()*$+$, $#-./0&*!1! 2'#/3!2' ,3(,&/#, *'"#$*0* -!1(!4&+$, -2$ %($+& 3!(+. 360 +*. 5 "'6/3& '+'($/$6"!7 8.(' 3.82'+' %($+' 3!(+. 360 +* &4& $ -! /!7 -2$6$+&, 6/! 3 9/!7 !8('#/$ -!1(!4')/ $ %20- 1$& '("'(!$%., #!%&2:'4$, 3 /2'3& 6$#/!/&(' 8!(;<!1!, ' $*&++!: =&- ($%!+$+, #'+13$+'2$+, =&(&2$/2$+. >!%&2:'+$& '("'(!$%!3 3 /2'3& 6$#- /!/&(' 8!(;<!1! 3'2;$20&/ 3 -2&%&('= !/ 0,90 %! 1,75%.

>?&(;) 2'@2'8!/"$ *&/!%$"$ "!($6/3&++!1! !-2&%&(&+$, A('- 3!+!$%!3 +'*$ 8.($ !-2&%&(&+. !-/$*'(;+.& 0#(!3$, 9"#/2'"?$$ /2'3. 6$#/!/&(' 8!(;<!1!: 9"/2'1&+/ 70% 9/'+!(; #!!/+!<&+$& #.2;&- 9"#/2'1&+/ – 1 : 30; 32&*, 9"#/2'"?$$ $@3(&6&+$& +' 3!%,+!7 8'+& -2$ /&*-&2'/02& 85–90 °> 3 /&6&+$& 45 *$+. 5 =!%& 2'@2'8!/"$ *&/!%$"$ +'*$ $@06&+. BC-#-&"/2. 3!%+!-#-$2/!3.= $@3(&6&+$7 $##(&%0&*!1! 2'#/&+$,. D&1$#/2'?$) #-&"/2!3 /'":& -2!3!%$($ # -!*!4;) #-&"/2!-

A!/!*&/2' Specord 40 (Analytik Jena).

E2$ 2'@2'8!/"& *&/!%$"$ "!($6/3&++!1! !-2&%&(&+$, #0**. A('3!+!$%!3 $#-!(;@!3'($ 2&'"?$) "!*-(&"#!!82'@!3'+$, # 2'#/3!- 2!* '()*$+$, =(!2$%' %(, $#"()6&+$, 3"('%' 3 @+'6&+$& !-/$6"!7 -(!/+!#/$ %201$= 120-- #!&%$+&+$7. 5 9/!* #(06'& +'8()%'&/#, 8'/!- =2!*+.7 #%3$1 %($++!3!(+!3!7 -!(!#. A('3!+!$%!3, "!/!2.7 !8+'- 20:$3'&/#, 3 BC-#-&"/2& 3 3$%& *'"#$*0*' -!1(!4&+$, -2$ %($+& 3!(+. 412 +*. F/! +'=!%$/ -!%/3&2:%&+$& 3 0#(!3$,= %$AA&2&+?$'(;- +!7 #-&"/2!A!/!*&/2$$: *'"#$*0* -!1(!4&+$, -2$ 412 +*.

G@06&+$& BC-#-&"/2!3 H>I 20/$+' -!"'@'(!, 6/! 2'#/3!2 %'++!1! #/'+%'2/' 3 -2$#0/#/3$$ '()*$+$, =(!2$%' $*&&/ /!/ :& *'"#$*0* -!1(!4&+$, (412 +*). >(&%!3'/&(;+!, 20/$+ *!:&/ 8./; $#-!(;@!3'+ 3 *&/!%$"& '+'($@' 3 "'6/3& H>I [2, 8].

>$#-!(;@!3'+$&* 2'@2'8!/'++!7 *&/!%$"$ -2!'+'($@$2!3'+ 2,% !82'@?!3 #.2;, $ -!"'@'+!, 6/! #!%&2:'+$& A('3!+!$%!3 3 /2'3& 6$#- /!/&(' 8!(;<!1! 3'2;$20&/ 3 -2&%&('= !/ 0,50 %! 1,01%. J' +'< 3@1(,%, 9/! %'&/ !#+!3'+$& -2&%(!:$/; 3 "'6/3& +$:+&1! -2&%&(' -!"'@'/&(; #!%&2:'+$, #0**. A('3!+!$%!3 +& *&+&& 0,50%.

D&@0(;/'/. #/'/$#/$6"!7 !82'8!/"$ -2!3&%&++.= !-./!3 #3$%&- /&(;#/30)/ ! /!*, 6/! !<$8"' &%$+$6+!1! !-2&%&(&+$, #0**. A('3!- +!$%!3 3 /2'3& 6$#/!/&(' 8!(;<!1! # %!3&2$/&(;+!7 3&2!,/+!#/;) 95%

#!#/'3(,&/ !3,97%.

!"#$%"

1. G@ /2'3. 6$#/!/&(' 8!(;<!1! 3.%&(&+! $+%$3$%0'(;+!& #!&%$- +&+$&, $%&+/$A$?$2!3'++!& "'" "!-/$@$+, $ !8!#+!3'+' +&!8=!%$*!#/; $#-!(;@!3'+$, 3 *&/!%$"'= '+'($@' %'++!1! '("'(!$%' 3 "'6/3& H>I.

269

Соседние файлы в предмете Процессы и аппараты химических производств