Новые достижения в химии и химической технологии растительного сырья. Материалы II всероссийской конференции [2005]
.pdf!"#$%&$ '.'., ()*$+)&$ ,.,., -$.$/01)& ,.-., 2$34%& ,.5.
!"#$%&"$ '(#$)* +, -).& /0%1)23)41)* %56+17 ........................ |
230 |
2$.06)&$ ,.A., !$70.)&$ 8.9., !$3*".0+$ 8.:., |
|
;$<=>%/)& ?.@. #)40%-&1+0 20)1+83)%+1& 9 ")%15: |
|
+ "&33(#1)* $"&1+ PAEONIA ANOMALA L........................................... |
236 |
8"#)>%/)&$ 5.'., :.$A+01)&$ B.'. +,(/01+0 2+'.01$)9, |
240 |
974030117: +, 3020#$")9 ;90$)9 CARTHAMUS TINCTORIUS L. ...... |
|
CD%>%+1)& '.'., ,70.)& 8.'. #+1$0$+/0#"+0 + |
|
2)3(#+1$0$+/0#"+0 +,)2%01)+47 # ;+"3)2%)2&1)97. |
243 |
8%&'.01$).......................................................................................... |
C$/)& -.,., C"+%E)& '.'., :"F0+ ,.'. '3+"),+47 RHODIOLA ROSEA L.
9740301+0, &1&3+, #)#$&9&, 9#$%0/17* #+1$0, ......................... 246
GD%E%+)& 8.G. #+1$0, 3(2+1+1+3 83&9)1)+4)9............................ |
248 |
GD%E%+)& 8.G. #+1$0, N-(!-6($+%+)%)4&1+3) &1&6&,+1& |
250 |
+ 3(2+1+1&.......................................................................................... |
|
!$=&$D)& H.'. 10")$)%70 2%09%&<01+5 1+$%&$)9 "-$0%2+10)3& + |
|
+,)6)%10)3& ........................................................................................ |
252 |
IJ<1)+)& '.,., ?*.$E0>)& ,.K. ;+"3).&'1+%)9&1+0 |
255 |
102%0403=17: 2%)+,9)417: "&.8)%7 ........................................... |
|
!"DJ)+ '.?., C$+1."70+$ 5.,. $90%4)8&,17* |
256 |
.0:&1):+.+/0#"+* #+1$0, 2%)+,9)417: 3&22&")1+$+1&....... |
|
;%D%6%+J10+$ (.5., 8%7%/)&$ B.5., G)D>$F%&$ ?.,.,
G)DA/01)& ,.K. #+1$0, #0%)#)40%-&<+: 2%)+,9)417: 3,4-!"#$-
19!,28-!2)"#+)30&1-4(23)-01-3-)9)* "+#3)$7............................. |
258 |
'07+<1)&$ B.'., C)+)>$.%& I.,. +#2)3=,)9&1+0 |
|
3+$+*4+6)%1+3"(2%&$1)') ").230"#& 9 #+1$0,0 4(>+#$7: |
259 |
90<0#$9................................................................................................ |
|
8$D#"E0+ '.,. T0:1)3)'+/170 #2)#)67 2)3(/01+5 2%02&%&$)9 |
|
435 %$01+09)4#$9& +, 2+:$7 ....................................................... |
261 |
:$E$.D04103 ,.I., :.0F%&A103 (.,., 9"A0+$ (.,., -0#)310+ C.!.,
,A/$LJ%&$ 2.9. "&$&3+$+/0#"&5 $%&1#8)%.&;+5 &3"&3)+4)9
A1&6&,+#& + $&6&"& ........................................................................... |
264 |
11
!"#$%&'()%* +.,., -./)./.)0 1.2., 3(4%' 2.5. !"#$%&&
'$&()&*")+,'-' ('."*#,&/ 0 1!'%"((#2 (&,*"3# 1')&4"!'0 ,#
'(,'0" 50-",')# ................................................................................ |
268 |
607%/"88%'0 9.2., -./)./.)0 1.2. ,'067 8&*"!1",'067 (1&!* &3
1'."$ ('(,6 (&9&!($'7 (PINUS SIBIRICA DU TOUR) .......................... |
270 |
:80;(8.) ,.,., 1(8()<.)0 2.=., 3(;()%'0 1.>. &(()"8'0#,&"
$#*#)&*&."($'7 #$*&0,'(*& 1'!:&!&,'0, &44'9&)&3'0#,,62
,# 1')&4"!,62 1)",$#2 (&,*"*&."($'-' & 1!&!'8,'-' |
273 |
1!'&(2';8",&/ .................................................................................. |
!"?'.@()0 1.2. &3<.",&" ('(*#0# & *'$(&$'-:#!4#$')'-&."($&2
(0'7(*0 -"$(#,'0'-' & 5*#,')+,'-' 5$(*!#$*'0 9"!"(*6....... |
277 |
!"?'.@()0 1.2., -%40A8() 2.:., 1B)($@()0 :.C., 5.D.8()0 E.F. |
|
&,*",(&:&$#%&/ 1!'%"((# 068")",&/ 9"*<)&,# &3 9"!"(*6 |
|
& *"(*&!'0#,&" "-' *'$(&$'-:#!4#$')'-&."($&2 (0'7(*0 ..... |
282 |
-07./() 3., G*0$ ,., -0B0D*H 2. &3<.",&" #,*&'$&()&*")+,'7
#$*&0,'(*& 5$(*!#$*# &3 )&(*+"0 & )<$0&%6 5,8"4&.,'-' 0&8#
*<!%&& MUSCARI BOURGAEI BAKER IN J................................................ |
286 |
108%4()0 I.>., =0J%$()0 3.-. :&*'2&4&."($#/ 2#!#$*"!&(*&$# |
|
9<9",.&$# )&)&")&(*,'-' ............................................................... |
292 |
608%8()0 2.>., K0B"$()0 L.3., ,"$%.) I.3., 247.M()0 5.3., |
|
608%8() N.-., OP.7%8.) G.-. <!(#,'06" *!&*"!1",'&86 |
|
0 !#3)&.,62 '!-#,#2 *#*#!,&$# $')=."-' |
|
ONOPORDUM ACANTHIUM L. ................................................................... |
294 |
1($(B(#"/() 5.,., O.A'.B0 5.I., 68.Q'%B() 5.2., !(8<@() 1.5.,
O.A'.B0 N.2. #,*'%,6 1)'8'0 !#(*",&7 9'*#,&."($'-' (#8#
9")-<: !#(*",&/ ("4"7(*0 BERBERIDACEAE & CAPRIFOLIACEAE ...... |
297 |
1($(B(#"/() 5.,., O.A'.B0 5.I., O.A'.B0 N.2., K0#(J'%B 9.I.
('1'(*#0)",&" #,*'%,'0'-' ('(*#0# 1)'8'0 !#3)&.,62
0&8'0 (4'!'8&, ................................................................................. 300
2'M('() 5.,., ED7(8()DB0& ,.2., !(R#*.'B( I.,., C0$J%B()0 5.,., 1M.#.'< 3.2. '1*&4&3#%&/ 068")",&/
)&4',,'-' 5:&!,'-' 4#()#............................................................ |
303 |
S.#8RB ,.+., 9)M"4()0 E.-. 4";1'1<)/%&',,#/ &34",.&0'(*+ |
|
1!&3,#$'0 0 1)'8#2 $#)&,6 '96$,'0",,'7 & ;&4')'(*& |
|
-')<9'7 $!#(,'/!($'-' $!#/ .......................................................... |
307 |
12
!"#$ %.&., !'()"$* +.,., -#(#./0#$* 1.2. !"#"$ #$%$&'#" ()
*"+!$, -"./01 .................................................................................... |
311 |
3#45.* 6.2., 7#8/*) 9.:., ;"<*."$* 6.+., ;*=>5.* ;.2., %#'."$ 2.+., 2.5854"$ ?.?., ,"$5)"$ +.;. +"&'+$2/-(+/3%$$
4$,&'#($ 5"!"- ( ."-(6(*-(7$&*(0 .8'(7-$!!90 :,:'- |
|
'+(*$'"!"# – 1!1-"2"# /!(*1-;!", 2+/..9 #'"+(7!90 |
|
5$'1<"-('"# #9&=(0 +1&'$!(, – !1 .+"+"&'*( |
|
CUCUMIS SATIVUS L. ( FAGOPIRUM ESCULENTUM MOECH.................... |
316 |
2.5854"$ ?.?., ;"@*A#$ +.+., 3#45.* 6.2., B"4*.C("$* ,.2.,
-"4>5A &.+. #-(8!($ +1&'('$-;!90 ."-(&101+(4"# !1 +"&'
*"+!8 .+"+"&'*"# CUCUMIS SATIVUS L. .............................................. |
321 |
+5A)'/)5.* 6.2., !(DE*."$ +.?., F$#(#$ G.H., ;*4=*/"$ +.+.,
:#.I5.* -.,., 2(<'I"$* G.&. &"4$+>1!($ ?$!"-;!90 &"$4(!$!(,
# #"4!90 ( &.(+'"#90 ()#-$7$!(80 () -(&';$# +1&'$!(,
&$5$,&'#1 2+/=1!*"#90 ................................................................. |
325 |
2./5="$* 6.2., 1#(<#( -.+., ;#J/#8 6.2. ()/7$!($ 0(5(7$&*"2"
&"&'1#1 !14)$5!", 71&'( ALOCASIA MACRORRHIZA ........................ |
330 |
&5I"$* ,.+., 2.C(##$* ,.K. ".+$4$-$!($ 1!'("*&(41!'1- |
|
'"*"?$+"-1 # +1&'('$-;!90 51&-10 5$'"4"5 |
334 |
5(*+"*1-"+(5$'+((.......................................................................... |
|
B(*$A#.)" &.,., :"8/"L"$* ?.2., 3(*=)5.* 1.&., B'=(5.* M.B. |
|
()/7$!($ 0(5(7$&*"2" &"&'1#1 5$&'!"2" +1&'('$-;!"2" |
338 |
&9+;8 .................................................................................................... |
|
9"(N*) O.&., O>*."$* +.?. (&."-;)"#1!($ *"+9 -(&'#$!!(69, |
|
."+1>$!!", 2+(<15( FOMITOPSIS OFFICINALIS (VILL.: FR.) |
|
BOND. ET SING ........................................................................................ |
340 |
-'#$* M.2., 345/(') &.6., B*L5.)5.* 1.M., &*L0.5)"$* 6.,. |
|
(&&-$4"#1!($ 0(5(7$&*"2" &"&'1#1 "'0"4"# .$+$+1<"'*( |
|
&$58! 2+$7(0(, -;!1 ( +1.&1............................................................ |
344 |
;')>* 6.2., :*."$ +.+., B*L5.)5.* 1.M., !'()"$* +.,.
&+1#!('$-;!"$ ?('"0(5(7$&*"$ (&&-$4"#1!($ !$*"'"+90
#(4"# +"41 POLYGONUM L. .................................................................. |
348 |
-5E"."$ +.,. ?$!"-;!9$ &"$4(!$!(8 '(5;8!1 51+=1-- |
"# |
(THYMUS MARSCHALLIANUS WILL.), .+"()+1&'13%$2" !1 |
350 |
'$++('"+(( &(<(+( ............................................................................. |
13
!"#$%&'(% ).!., *%+",-(% ..!., /%01234"#-( 5.6.,
789:"#% 7.6., ;%0"0-( <.!., ;2=#%,">%#-(% ..?., @4"#-:-( 6.A.
!"#$#%&$ #' ()"%*+#, BUPLEURUM AUREUM L (FISCH) .................... |
354 |
/,"$-,8: /.B., C20%$"# D.B., !%=0'##":-(% 5.6. -#&$&.#/*"!# |
|
)!%#0+1* 0*2*"%0) !&(1 3*(*04*0 50&6+15 7&(&3 ................... |
358 |
?'4E:- 5.6., /-=3"F'(% !.6. #""$*3&0)+#* -#&$&.#/*"!&6 |
359 |
)!%#0+&"%# "7*8#9#/*"!#5 0*2*"%0 %&(9) ................................ |
|
C,%(G-(% H.H., IJK:- C.)., ;%=%#-( 6.6., .J&-(% /.<. |
|
5#:#/*"!#6 "&"%)0 ;!"%()!%&0 $)-)'+#!) 0,'&$#"%+&.& |
|
FILIPENDULA ULMARIA L. MAXIM........................................................... |
362 |
C.@7@6) 5.6. &"+&0+1* -#&$&.#/*"!# )!%#0+1* 0*2*"%0) |
366 |
-#&:)""1 $#:&++#!) !#%)6"!&.&................................................. |
|
14
!"#$% I. #$&'()*( * #+',#$+" '#)'+)-. /'01')()$'+ * $/")(, + 1&'2(##".
.*0*!(#/', 1(&(&"3'$/* &"#$*$(4%)'5' #-&%6
1'4*0(&)"6 7'&0" *)89/$'&" *)$(&7(&')"
# 1&'$*+'+*&9#)', "/$*+)'#$%:
0.". ";<;=>?, ".". #?@ABC?D=>, #.E. &?F<G=>?
!"#$%$&$ '%(%% % )%*%+% ,-.%(/0-1 23 45*, &.. 2. 67890%, 7:,
;7<+/"$ (5*:/+%#$7") =-mail: azizovamalika@mail.ru
!"#$% &'(")"%$#*+,- #+./%)"0"1 2+."34++"3" #+)40540"+' # 6/- )47 $)#&/(89## #+)40540"+":0';"1'+#8 81(84)$8 +"1,& 2)'6"& 1 :"0<:4 $ 1#0/$+, ;':"(41'+#8.
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– +'#:"(<C#7 #+- )404$ 604.$)'1(8?) $18;< $)0/%)/0, # 5/+%9## / &+"3"*#$(4++,- 0'$- )#)4(<+,- 14>4$)1, +" .'(4%" +4 8$4+ &4-'+#;& #+./%9##.
15
!"#$%&'()(# *#+),")-++./. 01"2+2+/) 3.4+. ,.&%52(' ,"#- ,)")(6 0 $)7)++632 0-.80(-)32. 9. 0")-+#+2: 0 02+(#(25#01232 2+- 7%1(.")32 2+(#";#".+) 0%<#0(-#++63 ,"#23%<#0(-.3 .=&)7):( ,"#- ,)")(6 +) .0+.-# ")0(2(#&'+6> -#<#0(- 2$-$) -.$3.4+.0(2 ,.&%5#+2? 2> 2$ 7#@#-./. 06"'? 0 ,.3.<': 7.0()(.5+. ,".0(6> (#>+.&./28.
A 520&% ()12> ,"2".7+6> 2+7%1(.".- .(+.0?(0? ,.&2;#+.&6, - 5)0(+.0(2 /.002,.& 2 #/. ,".2$-.7+6#. B&)/.7)"? 0")-+2(#&'+. ,".- 0(.3% 0(".#+2: 2 -.$3.4+.0(2 ")$+..=")$+6> >2325#012> ,"#-")<#- +28 /.002,.& ?-&?#(0? %7.=+.8 3.7#&': 7&? .,"#7#+2? 0-?$2 >232- 5#01.8 0("%1(%"6 0. 0,.0.=+.0(': 1 2+7%1*22 2+(#";#".+), ,".(2-.- -2"%0+.8 )1(2-+.0(': 2 ,".?-+2#3 23 (.1025#012> 0-.80(-.
!7)++.3 0..=<#+22 ,"#70()-+6 "#$%&'()(6 >2325#012>, ;2$2- 1.->2325#012> 2 3#721.-=2.&./25#012> 20,6()+28 +.-./. ,.&23#"+./., -.7.")0(-."23./. 2+7%1(.") 2+(#";#".+) 0 ,".(2-.-2"%0+.8 )1(2-+.- 0(':, ,.&%5#++./. ,%(#3 >2325#01./. 0.5#()+2? ,".2$-.7+./. Na- 1)"=.1023#(2&*#&&:&.$6 0 ,"2".7+63 ,.&2;#+.&.3 – /.002,.&.3.
C$-#0(+., 5(. /.002,.& ?-&?#(0? 2+7%1(.".3 2+(#";#".+), .7+)1. 2$-$) 7.0()(.5+. -60.1.8 (.1025+.0(2 2 /27".;.=+.0(2 +# ,"23#+?#(- 0? - ,")1(25#01.8 3#72*2+#.
D *#&': 0+24#+2? (.1025+.0(2 ,%(#3 =&.12".-12 5)0(2 )1(2-+6> ;%+1*2.+)&'+6> /"%,, 2 ,"27)+2? -.7.")0(-."23.0(2 +)32 200.- -)+) -.$3.4+.0(' 3.72;21)*22 /.002,.&) 0 "#)1*2.++.-)1(2-+632 ,".2$-.7+632 7"%/./. ,".2$-.7+./. ,"2".7+./. ,.&23#") Na- 1)"=.1023#(2&*#&&:&.$6 (Na-KME).
F#)1*2.++.-)1(2-+6# ,".2$-.7+6# ,.&%5#+6 ,%(#3 .120+2? Na-KME ")$&25+.8 0(#,#+2 $)3#<#+2? (DG) -.7+63 ")0(-.".3 8.7- +.8 120&.(6. D-.80(-) .120++6> .=")$*.- Na-KME ,#"#0()-+6 - ()=&2*#.
A)1 -27+. 2$ ()=&2*6, 0 %-#&25#+2#3 0(#,#+2 $)3#<#+2? AHE
0+24)#(0? 0.7#"4)+2# 0-.=.7+6> /&21.-6> /"%,, - ,.&.4#+22 D2 2 D3 /&:1.,2".+.$+6> 1.*. C$ ()=&2*6 ()14# -27+., 5(. 0.7#"4)+2# )&'7#/27+6> /"%,,, .,"#7#++. ,. ")0>.7% 8.7+.8 120&.(6, $)3#(+. -6@#, 5#3 $+)5#+2?, .,"#7#++6# 8.7.3#("25#012 2 ,. 3#(.7% !2&'- 0.+) 2 9)72(), 5(. .=I?0+?#(0? ")0>.7.3 5)0(2 .120&2(#&? +) ,.=.5- +%: "#)1*2: .120+2? )&'7#/27+6> /"%,, 7. 1)"=.102&'+6>.
16
!"#$%'(") *+)+,%#-"." #",%'/0+1 "-+#2%003* "4$/56"( NaKM7 $/52+,0"8 9: ;"2<,%03 ;$"+5("&03%, #"&%$=/>+% -"(/2%0'0" #(15/0038 ."##+;"2 #2%&<?>%." #'$"%0+1:
CH2OH |
|
|
|
CH2OCH2COONa |
|
O |
|
|
|
|
O |
OH |
|
CH2 |
CH |
OH |
O |
|
|
||||
|
CH |
O |
CH |
O |
|
|
|
|
|||
OCH2COONa |
|
|
|
OH |
|
|
CH |
|
CH |
|
|
|
O O |
O |
O |
|
|
HO |
CH |
|
HC |
OH |
|
HO |
|
|
|
OH |
|
HO |
|
CH3 CH3 |
|
OH |
|
|
CH |
CH |
|
||
|
|
|
|||
H3C |
CH3 |
|
H3C |
CH3 |
|
n
n=3-5 )"2@ %
A/2+,+% &/00"8 #'$<-'<$3 ;"&'(%$=&%0" BC-, DE-, FGH + I!H #;%-'$"#-";+,%#-+)+ )%'"&/)+ + 5/$%.+#'$+$"(/0" ( J"#<&/$#'(%00"8 #+#'%)% $%.+#'$/6++ + +#;3'/0+8 *+)+,%#-+* #"%&+0%0+8 ;"& K+L- $") C-37, ;$+#("%0 0")%$ ."#<&/$#'(%00"8 $%.+#'$/6++ – 9762890.
E<0-6+"0/2@038 #"#'/( "-+#2%003* "4$/56"( Na-KM7 $/52+,0"8 #'%;%0+ 5/)%>%0+1 + #'%;%0+ ;"2+)%$+5/6++
|
B#*"&0/1 |
9"&%$=/0+% /2@&%.+&03* .$<;;, )"2@ % |
N+#2" #("- |
|||
|
Na-KM7 |
4"&03* .2+- |
||||
|
|
|
|
|||
|
|
|
|
|
|
-"2%(3* |
|
|
|
;" $/#*"&< |
;" 8"&")%- |
;" )%'"&< |
|
|
9: |
9! |
'$+,%#-")< |
M+2@#"0/ + |
.$<;; ( |
|
|
"-+#2+'%21 |
|||||
|
|
|
)%'"&< |
!/&+'/ |
CG7, )"2@% |
|
|
|
|
|
|||
|
|
|
|
|
|
|
|
84 |
600 |
23,6 |
18,5 |
17,6 |
9,0 |
|
80 |
650 |
31,2 |
27,2 |
26,4 |
13,4 |
|
72 |
720 |
34,6 |
29,4 |
28,6 |
14,6 |
|
54 |
740 |
38,0 |
31,9 |
30,6 |
15,7 |
|
43 |
870 |
40,7 |
34,5 |
33,8 |
17,1 |
|
34 |
920 |
47,9 |
38,1 |
37,6 |
19,0 |
17
!"#$%&'(, )&( *+,-.*$/+* 012 + /(%%+3(- 3( %&456&54$ %(*$47,& +*$'&+)'8$ 95'6:+(',-.'8$ /45338 – ,-.*$/+*'8$ + /+*4(6%+-.'8$, (&-+),;<+$%= >-$6&4(9+-.'(%&.;. ?6%3$4+@$'&,-.'( 5%&,'(#-$'(, )&(, <$-()'(A %4$*$ B(-$$ >-$6&4(9+-.'8$ ,-.*$/+*'8$ /45338 *+- ,-.*$/+*, 012 4$,/+45;& @$'$$ «6+%-8@+» /+*4(6%+-.'8@+ /4533,- @+ /(%%+3(-, % (B4,"(#,'+$@ 3(-5,:$&,-.'(A %#="+ %&456&54(A 2,2'- *+,:$&,-.-(1,6,7-&4+(6%+-3-@$&+--5-+"(34(3+--8-',9&,-.*$/+*) 2,3- *+,-.*$/+*,-6-C-6,4B(6%+@$&+-:$--;-("8.
D4(*56&8 4$,6:++, %(*$47,<+$ 1–5 @(-. % %#=",''(/( /(%%+3(-,, E(4(F( 4,%(4=-+%. # #(*$ + +@$-+ E,4,6&$4+%&+)$%65; #="6(%&.
! – 0,08–0,12.
DC 4$"5-.&,&,@ @$*+6(-B+(-(/+)$%6+E +%38&,'+A 5%&,'(#-$'(, )&( +'&$49$4(', +'*5:+45;<+A ,6&+#'(%&. 34$3,4,&,, %(*$47,<+A 3 @(-. % %#=",''(/( /(%%+3(-,, ",#+%+& (& *("8 + %3(%(B, $/( ##$*$'+=
# (4/,'+"@. D4+ #'5&4+B4;F+''(@ + #'5&4+@8F$)'(@ ##$*$'++ +'- *56&(4, # *("$ 100 @//6/ #$%, @,6%+@,-.'8$ &+&48 +'&$49$4(', (1280 $*/@-) (&@$),;&%= # %8#(4(&6$ 64(#+. D4+ 3(*6(7'(@ ##$*$'++ @,6%+@,-.',= 34(*56:+= %8#(4(&()'(/( +'&$49$4(', *(%&+/,$& 640– 1280 $*/@- 34+ *("$ 50 @//6/ #$%,. D4+ 3$4(4,-.'(@ ##$*$'++ +'*56&(- 4, *(%&,&()'( #8%(6+$ &+&48 +'&$49$4(', (640–1280 $*/@-) 4$/+%&4+- 45;&%= # 64(#(&(6$ 7+#(&'8E 34+ *("$ +'*56&(4, 10 @//6/ #$%,, )$4$" 48 ). !'&$49$4('(#8A ($& (4/,'+"@, 7+#(&'8E ', ##$*$'+$ *,''(/( +'*56&(4, E,4,6&$4+"5$&%= 34(*(-7+&$-.'(A :+465-=:+$A (*( 72–96 )) +'&$49$4(', # 64(#(&(6$.
D(-+@$4',=, #(*(4,%(4+@,= 9(4@, 34$3,4,&,, %(*$47,<$/( 3 @(-. % /(%%+3(-,, 34(F-, 3(-'8A >&,3 @$*+6(-B+(-(/+)$%6+E, *(– 6-+'+)$%6+E + 6-+'+)$%6+E +%38&,'+A. G$3,4&,@$'&(@ /(%5*,4%$'- '(/( 6('&4(-= 6,)$%,, >99$6&+#'(%&+, B$"(3,%'(%&+ -$6,4%$''8E %4$*% + @$*+:+'%6(A &$E'+6+ 1H IJ (' 4,"4$F$' # 6,)$%$ -$)$B- '(/( + 34(9+-,6&+)$%6(/( %4$*%, (&,B-$&6+) 3(* ',"#,'+$@ «0,/(- :$-» 34(&+# #+45%'(/( /4+33,, /$43$%, + CIK!.
18
!""#$%&'()!$ '&*+&,)&"-! ./0$)!1 )()&2(*+$2)34 0("-!5 +!62&62!"-(##!0$"6&7 5$##8#&*3 " 9$#$&:2(*/8;!+! "'&7"-'(+!
".2. (<=>?@A>, +.+. :>BC>DA>, (.(. ">?EFG><@A, ".H. 2>IJK@A>
!"#$%$&$ '%(%% % )%*%+% ,-.%(/0-1 23 45*, &.. 2. 67890%, 7:,
;7<+/"$ (5*:/+%#$7") =-mail: osppsp@polimer.uzsci.net
!"#$%#$"&'())"*+(, -+)).)%/( (!01) ,2),+'&, %34"5 "/ &(- 567 $(&8$%&'$(4+4467 8$%"/2%3467 -+)).)%/6, "&8%)9/:+567 8$(#- '"*+" 2% 2&+7 &;+$(7 <"/4+3+,'+)94%&'" *+)%2+#(.
=4(&'%,>++ 2$+5, 54%?"+ %@)(&'" 8$(#'"*+%?% 8$"5+4+4", !01 %8$+3+),.'&, %&%@+44%&',5" &8%&%@( +A 8%):*+4",, ;"/"*+%B &'$:#':$6, ;"/"#%-7"5"*+"7 &2%B&'2 " 8$"$%3%B "&7%34%?% &6$9,. C/2+&'46 $(/)"*46+ &8%&%@6 8%):*+4", !01: 5+7(4"*+"B ($(/5%)), '+$5%5+7(4"*+"B, 7"5"*+"B (?"3$%)"/), %&(<3+4"+ -+)).)%/6 "/ $(&'2%$%2 2 ;%$5+ 8%$%D#(. E#(/(4465" 5+'%3(5" 8%):*(.' !01 & &")94% (5%$'"/"$%2(44%B &'$:#':$%B (8%$%D#%2(, -+)).)%/( &% &'+8+-
49.#$"&'())"*4%&'" (F0) = 36–58%) " #$"&'())"*+%B &'$:#':$%B, F0 = 63–83%, & 3%2%)94% D"$%#"5 3"(8%/%4%5 $(&8$+3+)+4", *(&'"- 8% $(/5+$%5 (20–400 5#5). G'" %@$(/-6 !01 %?$(4"*+44% 4(@:7(.' 2 2%- 3+, " "7 2%346+ &"&'+56 8%32+$<+46 &"4+$+/"&:. E#(/(446+ %@$(/-6 !01 3%&'('%*4% D"$%#% 8$"5+4,.'&, 2 2"3+ )+?#%&68:*+?% 8%$%D#( 2 ;($5(-+2'"*+%B, 8($;.5+$4%B " 8">+2%B 8$%56D)+44%&'" 2 #(*+&'- 2+ (3&%$@+4'%2 " ;")9'$:.>"7 5('+$"()%2 '+74"*+%?% 4(/4(*+4",.
=4(&'%,>++ 2$+5, "/2+&'4%, *'% 8$" #"&)%'4%5 ?"3$%)"/+ 7)%8- #%2%B -+)).)%/6 8%):*(+'&, !01 & 8$+3+)94%B &'+8+49. 8%)"5+$"- /(-"" 165–180 " &'+8+49. #$"&'())"*4%&'" 77–83%. H$" 3()94+BD+5 ?"3$%)"/+ 8$%3:#'( 8$%-+&& 8$%'+#(+' 3%&'('%*4% @6&'$% 3% %@$(/%2(- 4", &(7($%2.
1+)9. 4(D"7 "&&)+3%2(4"B @6)% "/6(4"+ &8%&%@%2 8%):*+4", 4(4%$(/5+$467 *(&'"- !01 " "&&)+3%2(4"+ "7 ;"/"#%-7"5"*+"7 &2%B&'2 " &'$:#':$467 %&%@+44%&'+B.
=#(*+&'2+ "&7%34%?% &6$9, 26@$(4( 7)%8#%2(, -+)).)%/( & FH = 1740. H$%-+&& ?"3$%)"/( -+)).)%/6 8$%2%3")" 2 4% 2%34%5 $(&'2%$+
(/%'4%B #"&)%'6 8$" '+58+$(':$+ 100±2 ºF 2 '+*+4"+ 3,5 *. H$%3:#' ?"3- $%)"/( %@%/4(*")" #(# !01-1. = (4()%?"*467 :&)%2",7 -+)).)%/: 8%3-
19
!"#$%&' $'(#)&'*+ ! ,-. /)&", 0% +12%0)!3" 4S283TD /#' 5%12)2" 2450 467 1 !8)(0)9 :);0)12<= 1300 -2 ! 2"5"0'" 30 :'0, ' /)&+5"00>9 /#)(+32 )?)*0%5'&' 3%3 4@A-2. B)1#"(12!): ('1/"#$'#)!%0'C 4@A-1 ! !)(0)9 1#"(" 0% +&<2#%*!+3)!): (DE) ('1/"#$%2)#" /)&+5"0 /#"/%#%2 4@A-3, % ('1/"#$'#)!%0'": 4@A-2 ! %0%&)$'50>8 +1&)!'C8 – 4@A-4.
40)$)3#%20>: 1)5"2%0'": ,-. 1+F3' ' DE ('1/"#$'#)!%0'C 4@A-1 /)&+5"0 /#"/%#%2 4@A-5.
-2%?&'7" 1 /#'!"("0> G'*'3)-8':'5"13'" /%#%:"2#> )?#%*7)! 4@A, /)&+5"00>8 '* 8&)/3)!)9 7"&&=&)*> ! #%*&'50>8 +1&)!'C8.
@%3 !'(0) '* 2%?&'7> 1, !>1)3'" *0%5"0'C 12"/"0' 0%?+8%0'C ' !)()+("#H%0'C 4@A-5 )?IC10C=21C 2":, 52) /#' :0)$)3#%20): 0%$#"- !" /)( !)*("912!'": ,-. '*&+5"0'C #%*)$#"! !&%H0)9 :%11> 4@A () *%(%00)9 2":/"#%2+#> /#)'18)('2 ?>12#), /#%32'5"13' ?"*>0"#7')0-
0)' /) !1":+ )?I":+. B#' J2): ! 5%12'7%8 4@A, 3%3 /#%!'&), ':""2 :"12) )?#%20>9 $#%('"02 2":/"#%2+#>, 2.". *0%5"0'" 2":/"#%2+#> !0+2#' 5%12'7 !>F", 5": 0% '8 /)!"#80)12'. ,&"()!%2"&<0), *% 15"2 0%#%12%0'C (%!&"0'C /%#% !0+2#' 5%12'7 4@A /#)'18)('2 #%*#>! 1 #%*#+F"0'": /)!"#80)12' :'3#)3#'12%&&'2)! 7"&&=&)*> 1 )?#%*)!%- 0'": :'3#)2#";'0. B#' DE ('1/"#$'#)!%0'' J2'8 )?#%*7)! ! !)(0)9 1#"(" /#)2"3%"2 #%*#+F"0'" 4@A /) :'3#)2#";'0%:, 52) ' /#'!)('2 3 )?#%*)!%0'= :'3#)3#'12%&&'2)! 1 #%*:"#0)12<= 1–3 :3:.
-/#)7"11" !>1+F'!%0'C '&' )1%H("0'C ! 1/'#2" '&' %7"2)0" )0' ?>12#) 1&'/%=21C ! %$&):"#%2> 1 #%*:"#0)12<= 20–40 :3:.
->1+F"00>9 4@A-5 /#' /)$#+H"0'' ! !)(+ ()12%2)50) ?>12#) 0%?+8%"2, )(0%3) %$&):"#%2> 0" #%*#+F%=21C, 2.". $'(#)$"&' '* (%00)- $) )?#%*7% 4@A /)(!"#H"0> 1'0"#"*'1+.
K%?&'7% 1. L'*'3)-8':'5"13'" /%#%:"2#> )?#%*7)! 4@A, /)&+5"00>8 ! #%*&'50>8 +1&)!'C8
M'G# )?#%*7)! |
->8)(, % |
,@, % |
,B, % |
,#"(0'9 #%*:"#, :3: |
,2"/"0< 0%- ?+8%0'C ! !)(",% |
-)()+("#- H%0'C, % |
4@A-1 |
94 |
78 |
185 |
225 |
95 |
280 |
4@A-2 |
90 |
83 |
172 |
165 |
121 |
317 |
4@A-3 |
92 |
72 |
167 |
156 |
100 |
290 |
4@A-4 |
88 |
78 |
154 |
82 |
330 |
128 |
4@A-5 |
68 |
84 |
148 |
7 |
900 |
430 |
->8)( 4@A ! % 1 #%*:"#0)12<=
<25 |
<10 |
:3: |
:3: |
63,8 |
23,0 |
93,6 |
62,4 |
83,8 |
34,6 |
95,9 |
70,2 |
96,6 |
96,4 |
20