Sartori The War Gases Chemistry and analysis

SUBJECT INDEX

357

diPhenyl iodoarsine, 311, 312 dimethyl arsonium iodide, 317

triiodide, 312, 317 urea, 69, 82, 83 et seq.

triPhenyl arsine, 19, 298, 302, 303, 305 guanidine, 203

tetraPhenyl diarsine, 312, 313 tetrachloroarsenic anhydride, 317

diPhenylamine chloroarsine. See

Phenarsazine chloride.

Phosgene, 2, 4, 6, 8, 10, u, 12, 27, 28,

3°. 3i, 57, 59, 81, 83, 87, 88, 89 analysis, 81, 83, 87, 88, 89

manufacture, 62 preparation, 60 properties, 65 bromo, 74

preparation, 75 properties, 75

bromochloro, 69

di-. See Trichloromethyl chloroformate.

tri-. See Hexachloromethyl carbonate.

Physical classification of the war gases, 37

properties of the war gases, i, 4 Physiopathological classification of the

war gases, 28

properties of the war gases, i, 15 et seq.

of dichloroethyl sulphide, 242 of lachrymators, 3

of phosgene, 74 of sternutators, 3

Picric acid, 46, 166, 167, 174, 175 sodium salt, test for hydrocyanic

acid, 205

Polymerisation, 13, 143, 149, 183, 190,

237

Potassium iodide test for bromine, 42,43 for clilorine, 41

mercuriiodide test for dichloroethyl

sulphide, 246

permanganate test for dichloroethyl sulphide, 246

Powder, black, 46

Pressure of the war gases, vapour, 4 Projectiles, corrosion by war gases, 14 isoPropenyl chloroformate, 71 Properties desired in war gases, 33

of the war gases, general, Chapter I. Propionate, ethyl a chloro, 17

J3 chloro, 17

Propyl chlorosulphonate, 255 Protection of projectiles, 14

Prussian blue reaction for cyanogen compounds, 190, 195, 204

PS (chloropicrin, q.v.). See Table XIV.

Rationite (dimethyl sulphate and chlorosulphonic acid), 262

Ray and Das's test for chloropicrin, 172,

177

Resorcinol test for chloropicrin, 179

Resorufln test for bromine, 42 Robertson's method for analysis of

arsenical war gases, 330

Rogers's method for analysis of arsenical war gases, 331

Rubber, action of bromobenzyl cyanide on, 200

of carbonyl bromide on, 75

of dichloroethyl sulphide on, 225 of dichloroformoxime on, 79

of trichloronitroso methane on,

165

of hydrocyanic acid on, 185

of methyl fluorosulphonate on, 266 of phosgene on, 72

Rumanian method for manufacture of chloropicrin, 167

Schiff's reaction for bromine, 42 Schroter's test for dichloroethyl

sulphide, 248

Schulze's analytical method for benzyl chloride, 138

Schuttzenberger and Grignard's method for manufacturing phosgene, 62

Selenide, dichloroethyl, 217 Selenious acid reagent for

dichloroethyl sulphide, 233, 247,249 Selenium compounds as war gases, 217 1.4 Selenothiane, 240

Semi-persistent war gases, 28

Senf gas. See Dichloroethyl sulphide. Sensitivity, threshold of pathological, 2 Ships, disinfestation of, by chloropicrin,

165

Silver nitrate test for carbon monoxide,

53

SK (ethyl iodoacetate, q.v.). See Table XIV.

Smokes, particulate, 272,313

Sodium arsenite test for cyanogen iodide, 209

ethylate test for chloropicrin, 178 iodide test for phosgene, 86 iodoplatinate test for dichloroethyl

sulphide, 246

peroxide test for chloropicrin, 180 sulphide test for dichloroethyl

sulphide, 247

sulphite test for chloropicrin, 179 Solid war gases, 27

Spectroscopic test for carbon monoxide,

54

Stabilisers for war gases, 13, 143, 183 Stannic chloride compound with

hydrocyanic acid, 187

Stassfurt salts as raw materials for bromine manufacture, 38

Steinkopf's method of preparing dichloroethyl sulphide, 219

Sternite (phenyl dichloroarsine and diphenyl chloroarsine), 302

Stibine as war gas, 15 diphenyl chloro, 297

cyano, 297

358	SUBJECT
Stilbene, dicyano, 199
Structure of war gas	molecules,
Chapter II.

Styryl dichloroarsine, p chloro, 285

Sulphamide, 259 Sulphanilic acid, 269

Sulphate, PP' dichloroethyl, 261 dichloromethyl, 95, 255, 257 methyl hydrogen, 261 dimethyl, 262, 269

analysis, 269 manufacture, 264 preparation, 263 properties, 264

Sulphide war gases, 214 et seq. diacetonyl, 149

benzyl, 132

P bromoethyl ethyl, 215

flfl' dibromoethyl, 16, 18, 215, 243 preparation, 243

properties, 243

p chloroethyl ethyl, 215 vinyl, 238

chloromethyl, 215

p chlorovinyl arsenious, 292

a chlorovinyl P' chloroethyl, 234 P chlorovinyl j8' chloroethyl, 234 dichloroacetyl, 216

PP' dichlorobutyl, 215 88' dichlorobutyl, 216 aoc' dichloroethyl, 25, 215

PP' dichloroethyl, 6, 7, 8, 10, n, 12,

13,	16,	18,	25,		27,		28,	30,	31,
215, 216, 217,				246, 249, 250
analysis, 246, 249, 250
manufacture, 220
preparation, 217
properties (physical), 223
(chemical), 226
<xj3 dichloroethyl vinyl,						237
PP' dichloropropyl, 215
yy' dichloropropyl,				216
dichlorovinyl diarsenious,295
a.pp' trichloroethyl, 233
oux.'pP' tetrachloroethyl,						237
apPP' tetrachloroethyl,						233
PP'yy' tetrachloropropyl, 216
outa. PP' pentachloroethyl, 235
aaa'j8/3'/3'hexachloroethyl, 235									•
aa/J/30/3'hexachloroethyl, 233
a.am'PPP'p' heptachloroethyl, 235
dicyanobenzyl, 199
P ethoxy ethyl vinyl, 238
P' hydroxyethyl, 238
PP' diethoxy ethyl, 238, 243
ethyl arsenious, 283					236, 237, 244,
PP' diiodoethyl,			215,
248

methyl arsenious, 278 phenacyl, 159, 162 diphenyl arsenious, 311

dibromide, pp'	dichloroethyl, 230
tetrabromide,	pp' dichloroethyl,
230
dichloride, /?/?'	dichloroethyl, 230,
231, 234

INDEX

Sulphide trichloroiodide, pp' dichloroethyl, 232

pentachloroiodide, pp' dichloroethyl, 232

test for aliphatic arsines, hydrogen, 328

for dichloroethyl sulphide, sodium, 247

diSulphide, diethylene, 236, 247 diSulphides, alkyl, 172 triSulphide, diethylene, 237

Sulphilimine group, 232

Sulphite test for chloropicrin, sodium, 179

Sulphone, pp' dibromoethyl, 244 PP' dichloroethyl, 228, 229 PP' diiodoethyl, 245

diSulphone, ethylene, 236 diSulphonic acid, nitromethane, 171 triSulphonic acid, methane, 171

methyl mercaptan, 214

Sulphonic anhydride, trichloromethyl, 212

Sulphoxide, PP' dibromoethyl, 244

PP' dichloroethyf, 228, 229, 231,

234

aa'j8/5' tetrachloroethyl, 232 PP' diiodoethyl, 245

Sulphur atom in war gases, effect on properties, 17

compounds as war gases, Chapter XIV.

Sulphuric acid, methyl, 261 esters, 253

Sulphuryl chloride, 258, 269, 270 analysis, 269, 270 preparation, 258

properties, 259

Sulvinite (ethyl chlorosulphonate, q.v.). See Table XIV.

Surpalite (trichloromethyl chloroformate, q.v.). See Table XIV.

Symmetry of war gas molecules, 22

Telluride, dichloroethyl, 217 Tension of war gases, vapour, 4

Textiles, effect of war gases on, 153, 225, 233, 265, 317

Theories of relation between structure and action of war gases, 23

1.4 Thiazane, 239

4 ethyl, 239

4 methyl, 239

4 phenyl, 239 derivatives, 239, 244

Thioarsane, phenyl, 240 diThiocarbamate, calcium phenyl, 201

Thiocarbanilide, 201 Thiocyanate, methyl, 211

phenacyl, 160

isoThiocyanate, phenyl, 201, 202, 203 Thiocyanate, diphenyl arsenious, 312 test for iron pentacarbonyl, 204 Thiodiglycol, ethylene, 218, 222, 226

Thioethers as war gases, 214 et seq.

SUBJECT

Thioglycol dichloroethyl ester, ethylene, 216

diethyl ethylene, 241

Thiophenol test for chloropicrin, 178

Thiopbotgene, 211, 212, 213 manufacture, 214 preparation, 213 properties, 214

diThiophosgene, 214

Thiosulphate, phenacyl sodium, 160 sodium cyanobenzyl, 199

p Thioxane, 236

Thymol test for chloropicrin, 179 Tin chloride (stannic), 187

(stannous), 241 Titanium chloride, 187, 241 T.N.T., 46

Toluene, monobromo, 17 diTolyl chloroarsine, 20

Tonite (chloroacetone, q.v.). See Table XIV.

Toxic smokes, 272, 313 war gases, 28, 29

Toxic-suffocant (lung irritant) war gases, 28

Toxidty of war gases, 2, 3

Toxophor-Auxotox theory of the war gases, 24, 29

Toxophon, 24, 29

T Stoff (benzyl bromide,xylyl bromide, q.v.). See Table XIV.

Unsaturation in the molecules of war gases, 22

Urea, diphenyl, 69, 82, 83 et seq., 113 Urethane, N chloroacetyl, 119

trichloromethyl N diphenyl, 113 Urotropine. See Hexamethylene

tetramine.

Van der Laan's analysis method for benzyl bromide, 139

Vapour tension of war gases, 4 Vesicant gases, 18, 22, 28

VUlanttte (methyl chlorosulphonate, q.v.). See Table XIV.

Vincennite, 185

Vivrite (cyanogen chloride and arsenic trichloride), 188

Volatility of the war gases, 6, 9

War gases:

action, delayed biological, 242 on blondes, 242

on brunettes, 242

on building materials, 225 on cork, 266

on foodstuffs, 73, 114 on metals. See Metals, on negroes, 242

on rubber, 72, 75, 79, 165, 185, 200, 225,266

on textiles, 225, 233, 265, 317

INDEX

359

War gases—contd. adsorption by alumina, 50

by carbon, 44, 73,114,173,180, 317 by silica gel, 327 fn. i, 331

aerosols as, 297, 313, 327 fn. i analysis, qualitative chemical, 40,

53, 81, 98, 123, 138, 144, 176, 204, 246, 269, 326

by odour, 40, 81, 176 quantitative, 42, 55, 83, 98, 124,

145, 179, 206, 249, 270, 329 antigas niters for (and seeAdsorption

by carbon), 68, 70

arsenic atom in, 18, 319 etseq. biological action. See Chapters I

and II. irritant, 2, 28 labyrinthic, 92

lachrymatory, 2, 3, 16 et seq. lung irritant, 28

orticant, 21, 147, 155, 161, 217

toxic, 3, 21, 29 suffocant, 28

vesicant, 17 et seq., 28, 58, 59, 242, 279, 284, 293, 295, 297, 302, 313

blondes, action on, 242 brunettes, action on, 242 carbonyl group in, 23, 24 classification, biological, 28

chemical, 29 Chugaev, 29 Engel, 32 Jankovsky, 29 Zitovic, 29

chronological, Table XIV and p. 32 military, 27

physical, 27 physiopathological, 28

corrosive action on metals. See Metals,

cyanide group in, 20, 21, 24, Chapter XIII.

decontamination, 13, 36, 73, 153,

154, 231, 232, 233, 242, 284 explosion-stability, 14, 200, 325 halogen atom in, 15, 23, 45 inorganic, 15, 271

labyrinthic, 92 lachrymatory, 2, 3, 16 etseq.

lung irritant (toxic-suffocant), 28 meteorological conditions and, 10,

ii, 12, 33

military nomenclature. See Tables XIV, XV.

molecular symmetry of, 22 negroes, action on, 242 nitrate group in, 21

nitro group in, 21, 23 number used, vii

orticant, 21, 147, 155, 161, 217 oxime group in, 21

oxygen atom in, 23 peacetime uses of, 96, 165, 262

penetration into building materials, etc., 225

360	SUBJECT INDEX

War gases—contd. persistence, 10, 28, 244

polymerisation, 13, 143, 149, 183, 190, 237

properties, biological, I, 15 et seq,, 24 chemical, i and passim

desired, 33

physiopathological, i, 15 et seq., 24 shell markings for, 28

stabilisation, 13, 143, 183, 190 stability, 12, 13, 14, 17, 59, 200, 325 storage, 13, 143

sulphur atom in, 17 toxophor-auxotox theory of, 24 unsaturation in, 22

vesicant, 17 et seq., 28, 58, 59, 242, 279, 284, 293, 295, 297, 302, 313

Xylyl bromide, 13, 14, 136 analysis, 138

Xylyl bromide, manufacture, 137 preparation, 137 properties, 138

Xylylene bromide, 136

Yablich's reagent for dichloroethyl sulphide, 247

Yant's test for phosgene, 84 Yellow Cross gases, 28

Yp&tte. See Dichloroethyl sulphide.

Zinc chloride compound with hydrocyanic acid, 187

Zitovic's classification of the War gases, 29

Zyklon, A, 104

B, 104, 190

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