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Abbreviations

The following list provides a selection of the less common abbreviations used in this book. Those of common usage such as py, acac, THF, NMR, DFT have been left out.

The abbreviations are listed in alphabetical order. When a number, a Greek letter or another special character precedes the abbreviation, this is listed ignoring such character.

 

A

AAMP

4-amino-5-(aminomethyl)-2-methylpyrimidine

aampy

2-acetylamino-6-methylpyridine

acbt

anion of 2-amino-4-chlorobenzothiazole

ACR

acridine

Acr-4-carboxamide

N-[2-(dimethylamino)hexyl]acridine-4-carboxamide

AcrNH2

9-(2-aminoethyl)amino-6-chloro-2-methoxyacridine

AcrNMe2

6-chloro-9-(2-dimethylaminoethyl)amino-2-methoxyacridine

adbtz

11-aminodibenzo[b,f](1,4)thiazepine

admp

2-amino-4,6-dimethylpyridinate

admpym

2-amino-4,6-dimethylpyrimidinate

`-Ala

alanine zwitterion (+NH3CH2CO2)

Amb

R(-)2-amino-1-butanol

ambt

anion of 2-amino-4-methylbenzothiazole

ammpy

2-(aminomethyl)pyridine

amp

2-aminopyridine

ampy

2-amino-6-methylpyridine

AniPyF

N,N'-p-anisylpyridylformamidinate

797

798Multiple Bonds Between Metal Atoms Appendix

ap

anion of 2-anilinopyridine

8-aq

8-aminoquinoline

asp

2-acetoxybenzoate

AZ

azathioprine

azin

anion of 7-azaindole

 

B

4S-BACIM

2-methyl-1-propyl 1-acetyl-2-oxoimidazolidine-4(S)-

 

carboxylate

BAII

bis(pyridylimino-isoindolinate)

bcnp

1,8-naphthyridine-2,7-dicarboxylate

bdppp

2,6-di[(C6H5)2P]pyridine

bhp

anion of 6-bromo-2-hydroxypyridine

BINO

binaphthoxide

BNAZ or 4S-BNAZ

benzyl-2-oxoazetidine-4(S)-carboxylate

BNOX or 4S-BNOX

4(S)-benzyl-2-oxooxazolidine

bpa

bis(2-pyridylmethyl)amine

BPAP

2,6-bisphenylaminopyridinate

bpbg

biphenylbiguanide

bpnp

2,7-bis(2-pyridyl)-1,8-naphthyridine

4S-BPPIM

2-methyl-l-propyl 1-(3-phenylpropanoyl)-2-oxoimidazolidine-

 

4(S)-carboxylate

bpynap

2,7-bis(2-pyridyl)-1,8-naphthyridine

1,4-bq

1,4-benzoquinone

Br2calix[4]arene(CO2H)2

25,26,27,28-tetrapropoxy-5,17-dibromo-calix[4]arene-11,23-

 

dicarboxylic acid

5-Brsalpy

(2-pyridyl)-2-oxy-5-bromobenzylaminato

btmp

(benzylthiomethyl)diphenylphosphine

btp

2,6-bis-(N'-1,2,4-triazolyl)pyridine

But2bipy

4,4'-bis(tert-butyl)-2,2'-bipyridine

But-H2S4

1,2-bis(2-mercapto-3,5-di-Butphenylthio)ethane

4-But-py

4-tert-butylpyridine

But-salophen

N,N'-o-phenylenebis(salicylidenamine)

Multiple Bonds Between Metal Atoms 799

Appendix

C

CH3N[P(OCH2CH3F3)2]2

C4H4NCO2

C4H3SCO2

C4H3SCONH

C10H15CO2

calix[4]arene(CO2H)4

cap

carb

CEP

4S-CHAZ

chea

bis(bis(trifluoroethoxy)phosphine)methylamine

pyrrole-2-carboxylate

thiophene-2-carboxylate

thiophene-2-amidate

1-adamantylcarboxylate

25,26,27,28-tetra-n-propoxycalix[4]arene-5,11,17,23- tetracarboxylic acid

caprolactamate (anion of 1-aza-2-cycloheptanone)

anion of carboline

P(NCCH2CH2)3

cyclohexyl 2-oxoazetidine-4(S)-carboxylate

1-cyclohexylethylamine

CHIP

anion of 1'-3'-dihydrospiro[cyclohexane-1,2'-[2H]imidazo-

 

[4,5b]pyridine

chp

anion of 6-chloro-2-hydroxypyridine

5-Clsalpy

(2-pyridyl)-2-oxy-5-chlorobenzylaminate

Cl-tpy

4'-chloro-2,2':6,2"-terpyridine

CNPh

phenylisocyanide

CNPhCF3

trifluoromethylphenylisocyanide

CNPhNMe2

p-dimethylaminophenylisonitrile

4-CN-py

4-pyridinecarbonitrile

COD

cycloocta-1,5-diene

COT

1,3,5,7-cyclooctatetraene

(S,R)-CPFA-P

(S,R)-(1-N,N'-dimethylaminoethyl)-2-(dicyclohexylphosphi-

 

no)-ferrocene

18-crown-6

the crown ether 1,4,7,10,13,16-hexaoxacyclooctadecane

Cy

cyclohexyl or c-C6H11

cyt

cytosine

 

 

 

D

daapy

2,6-diacetylaminopyridine

dabco

1,4-diazabicyclooctane

800Multiple Bonds Between Metal Atoms Appendix

dach damt DAniF

DAnimF

DAnioF

dapy

DArF

DClPhF

DCl2PhF DCNNQI DCyF DDA dedp DEtBz depa

depe

dFMEPY or 5S-dFMEPY dGuo

diglyme DMAD dimen dimenol dippp

DMAA or dma DMAP or 5S-DMAP dmapd

dmat 2,3-dmbq DM-DCNQI dmdppm dme

DMeBz

1,2-diaminocyclohexane

2,4-diamino-6-methyl-s-triazine

N,N'-di-p-anisylformamidinate

N,N'-di-m-anisylformamidinate

N,N'-di-o-anisylformamidinate

2,6-diaminopyridine

N,N'-diarylformamidinate

N,N'-di-p-chlorophenylformamidinate

[(3,5-Cl2C6H3)2N)2CH]<

N,N'-dicyanonaphthaquinone diimine

N,N'-dicyclohexylformamidinate 2,3,5,6-tetramethyl-p-phenylenediamine (durenediamine) Et2PCH2CH2PPh2

N,N'-di(ethyl)benzamidinate 4,4'-diethyl-2,2'-dipyridylamide CH3CH2PCH2CH2PCH2CH3 methyl-(5S)-3,3-difluoro-2-oxopyrrolidine-carboxylate deoxyguanosine

CH3O(CH2)2O(CH2)2OCH3

dimethyl acetylene dicarboxylate 1,8-di-isocyanomenthane 5,7-dimethyl-1,8-naphthyridine-2-ol Pri2P(CH2)3PPri2

N,N'-dimethylacetamide

N,N'-dimethyl-2-pyrrolidone-5(S)-carboxamide 2,6-dimethyl-4-aminopyrimidine 4,5-dimethyl-2-methylaminothiazolato 2,3-dimethyl-1,4-benzoquinone 2,5-dimethyl-N,N'-dicyanoquinonediimine Ph2PCH2PMe2

dimethoxyethane, CH3O(CH2)2OCH3

N,N'-di-methylbenzamidinate

 

 

 

 

Multiple Bonds Between Metal Atoms

801

 

 

 

 

 

 

Appendix

DMeODMBz

N,N'-dimethyl-3,5-dimethoxybenzamidinate

dmf

dimethylformamide

dmg

anion of dimethylglyoxime

dmhp

anion of 2, 4-dimethyl-6-hydroxypyrimidine

dmmp

anion of 4,6-dimethyl-2-mercaptopyrimidine

dmopehhypy

1,3-dimethyl-2,4-dioxo-9-(1-phenylethyl)-1,3,6,7,8,9-hexa-

 

hydropyrimido[2,1-f]purine

dmp

anion of 2,6-dimethylpyridine

dmpe

bis(dimethylphosphino)ethane, Me2P(CH2)2PMe2

dmph

anion of 2,4-dimethyl-6-oxopyrimidine

dmpm

bis(dimethylphosphino)methane, Me2PCH2PMe2

dmptsczda

dimethyl-4-phenylthiosemicarbazidediacetate

dmpyethybz

1,2-dimethoxy-4,5-bis[(2-pyridyl)ethynyl]benzene

DMPyF

N,N'-5,5'-dimethyl-2,2'-dipyridylformamidinate

Dm-MePhF

[(m-MeOC6H4N)2CH]<

DMSO or dmso

dimethylsulfoxide

DMTF

N,N'-dimethylthioformamide

DOSP

N-dodecylbenzenesulfonylprolinate

dpa

anion of 2,2'-dipyridylamine

dpae

Ph2AsCH2CH2AsPh2

dpam

bis(diphenylarsino)methane, Ph2AsCH2AsPh2

dpapm

diphenylarsinodiphenylphosphinomethane, Ph2PCH2AsPh2

DPB

diporphyrinatobiphenylene

 

 

 

 

dpcp

Ph2PCH(CH2)3CHPPh2

dpdbp

Ph2PCH2CH2P(p-ButC6H4)2

dpdt

Ph2PCH2CH2P(p-tol)2

DPhAc

[PhNC(CH3)NPh]<

DPhBz

N,N'-diphenylbenzamidinate

DPhF

N,N'-diphenylformamidinate

Dp-BrPhF

(p-BrC6H4N)2CH

Dp-ClPhF

(p-ClC6H4N)2CH

Dp-FPhF

(p-FC6H4N)2CH

802Multiple Bonds Between Metal Atoms Appendix

DPh3,5-diClF

N,N'-di-3,5-dichlorophenylformamidinate

DPhFF

N,N'-di-p-fluorophenylformamidinate

DPhm-ClF

N,N'-di-m-chlorophenyl-formamidinate

DPhIP

anion of 2,6-di(phenylimino)piperidine

DPhTA

N,N'-di-phenyltriazenate

DPmF

dipyrimidinylformamidinate

dpmp

(Ph2PCH2)2PPh

dpnapy

2,7-bis(diphenylphosphino)-1,8-naphthyridine

dppa

(Ph2P)2NH

dppb

Ph2PCH(Me)CH(Me)PPh2

dppbe

1,2-bis(diphenylphosphino)benzene

dppe

1,2-bis(diphenylphosphino)ethane, Ph2P(CH2)2PPh2

dppee

cis-Ph2PCH=CHPPh2

dppm

bis(diphenylphosphino)methane, Ph2PCH2PPh2

dppma

(Ph2P)2NMe

dppn

benzo[i]dipyrido[3,2-a:2',3'-c]phenazine

1,3-dppp

Ph2P(CH2)3PPh2

dppz

dipyrido[3,2-a:2',3'-c]phenazine

DPyF

N,N'-di-2,2'-pyridylformamidinate

ds-im

dansyl-imidazole

ds-pip

dansyl-piperazine

DTBN

di-But-nitroxide

dtd

4,7-dithiadecane

dtdd

5,8-dithiadodecane

DTolF

N,N'-di-p-tolylformamidinate

DTolTA

N,N'-di-p-tolyltriazenato

DV-X_

discrete variational calculations

DXyl2,6F

N,N'-di-2,6-xylylformamidinate

 

 

 

E

EMAC

extended metal atom chain

en"

N,N -dimethylethylenediamine, CH3(H)N(CH2)2N(H)CH3

 

 

Multiple Bonds Between Metal Atoms

803

 

 

 

 

Appendix

EPPIM

ethyl 1-(3-phenylpropanoyl)-2-oxoimidazolidine-4(S)-

 

carboxylate

ESBO

edge-sharing bioctahedra

9-EtAdeH

9-ethyladenine

9-EtGH or 9-EtGuaH

9-ethylguanine

etpda

diethyltripyridyldiamide

1-EtT

anion of 1-ethylthymine

 

F

2-Fap

anion of (2-fluoroanilino)pyridine

2,5-F2ap

anion of 2-(2,5-difluoroanilino)pyridine

2,6-F2ap

anion of (2,6-difluoroanilino)pyridine

2,4,6-F3ap

anion of (2,4,6-trifluoroanilino)pyridine

F5ap

anion of (2,3,4,5,6-pentafluoroanilino)pyridine

FcCO2

ferrocenecarboxylate

Fcpe

3-ferrocenyl-2-propenate

FHMO

Fenske-Hall Molecular Orbital

fhp

anion of 6-fluoro-2-hydroxypyridine

form

any formamidinate ligand

FPhPyF

N,N'-p-fluorophenylenepyridylformamidinate

FSBO

face-sharing bioctahedron

 

G

gly

glycine

GudH

guanidinium cation

guH2

guanine

Guo

guanosine

 

H

Hadmp

2-amino-4,6-dimethylpyridine

HBPAP

2-(PhN)-6-(PhN)py

Hdpa

bis-2-(pyridyl)amine

HDPhTA

N,N'-diphenyltriazine

HDXyl2,6F

N,N'-di-2,6-xylylformamidine

804Multiple Bonds Between Metal Atoms Appendix

hedp

1-hydroxyethylidenediphosphonato

hfacac

hexafluoroacetylacetonato

H-H

head-to-head

Hhq

2-quinolinol

Hmhq

4-methyl-2-quinolinol

Hmphonp

5-methyl-7-phenyl-1,8-naphthyridin-2-one

hp

anion of 2-hydroxypyridine

H2pc

phthalocyanine

hpp

anion of 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine

1R,2R,5S-hprmph

1R,2R,5S-2-hydroxy-5-isopropenyl-2-methylcyclohexyl-

 

diphenylphosphane

1S,2S,5R-hprmph

1S,2S,5R-2-hydroxy-5-isopropenyl-2-methylcyclohexyl-

 

diphenylphosphane

Hpyro

2-pyrrolidinone

H-T

head-to-tail

H2TMP

tetramesitylporphyrin

Hvall

2-piperidinone (β-valerolactam)

 

I

4S-IBAZ

isopropyl 2-oxoazetidine-4(S)-carboxylate

Im

imidazole

IMMe

2,4,4,5,5-pentamethyl-4,5-dihydro-1H-imidazolyl-1-oxy

indenyl

C9H7

Ino

inosine

4S-IPOX

isopropyl 2-oxooxazolidine-4(S)-carboxylate

 

L

lut

lutidine

 

 

 

M

MACIM or 4S-MACIM

methyl 1-acetyl-2-oxoimidazolidine-4(S)-carboxylate

mand

mandelate (_-hydroxy-_-phenylacetate, PhCH(OH)CO2<)

MANIM or S,S-MANIM

mandaloylimidazolidinone-4-carboxylate or methyl 4(S)-

 

1-[(2'S)-methoxy-2'-phenylacetyl]-2-oxoimidazolidine-4-

 

carboxylate

 

 

Multiple Bonds Between Metal Atoms

805

 

 

 

 

Appendix

map

anion of 2-amino-6-methylpyridine

MBOIM or 4S-MBOIM

methyl 1-benzoyl-2-oxoimidazolidine-4(S)-carboxylate

mbzap

2-((_-methylbenzylidene)amino)pyridine

MCHIM or 4S-MCHIM

methyl 1-(cyclohexylacetyl)-2-oxoimidazolidine-4(S)-

 

carboxylate

MDMIM

methyl 1-(d-menthoxyacetyl)-2-oxoimidazolidine-4(S)-

 

carboxylate

9-MeAdeH

9-methyladenine

1-MeAdo

1-methyladenosine

2-Meap

2-(2-methylanilino)pyridinate

4S-MEAZ

methyl 2-oxoazetidine-4(S)-carboxylate

1-MeC

anion of 1-methylcytosine

1-Mecyd

1-methylcytosine

Me-DuPHOS

(+)-1,2-bis(2S,5S)-2,5-dimethylphospholano)benzene or its

 

corresponding R enantiomer

Me-Im or 1-MeIm

N-methylimidazole

menapo

7-methyl-1,8-naphthyridin-2-onato-N,N'

MENTHAZ

menthyl 2-oxoazetidine-4(S)-carboxylate

mentholate

anion of menthol

meonp

7-methyl-1,8-naphthyridin-2-one

MEOX or 4S-MEOX

methyl 2-oxooxazolidine-4(S)-carboxylate

4,7-Me2phen

4,7-dimethyl-1,10-phenanthroline

3,4,7,8-Me4phen

3,4,7,8-tetramethyl-1,10-phenanthroline

mephnapoN,N'

5-methy-7-phenyl-1,8-naphthridin-2-onato-N,N'

mephnapoN,O

5-methy-7-phenyl-1,8-naphthridin-2-onato-N,O

mephonp

5-methyl-7-phenyl-1,8-naphthyridin-2-one

4S-MPAIM

methyl 1-phenylacetyl-2-oxoimidazolidine-4(S)-carboxylate

4S-MPOX

4(S)-methyl-5(S)-phenyl-2-oxooxazolidine

4S-MPPIM

methyl 1-(3-phenylpropanoyl)-2-oxoimidazolidine-4(S)-

 

carboxylate

MEPY or 5R-MEPY

methyl 2-oxopyrrolidine-5(R)-carboxylate

4-Mepy

4-methylpyridine

4-Mepyms

anion of 4-methylpyrimidine-2-thione

806Multiple Bonds Between Metal Atoms Appendix

4-MepyS

anion of 4-methyl-2-mercaptopyridine

5-MepyS

anion 5-methylpyridine-2-thiolate

3,5-Me2pz

anion of 3,5-dimethylpyrazole

Mepyzca

anion of 2-methylpyrazine-5-carboxylic acid

Mes

mesityl, 2,4,6-C6H2(CH3)3

5-Mesalpy

(2-pyridyl)-2-oxy-5-methylbenzylaminato

1-MeT

anion of 1-methylthymine

metro

metronidazole

1-MeU

anion of 1-methyluracil

mhp

anion of 6-methyl-2-hydroxypyridine

m-MeODMB

dimethyl-3-methoxybenzamidinate

MLMIM

methyl 1-(l-menthoxyacetyl)-2-oxoimidazolidine-4(S)-

 

carboxylate

mmtz

5-methylthio-2-mercaptothiadiazolinate

m-nitpy

2-(3-pyridyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-1-

 

oxyl-3-N-oxide

mpa

_-methoxy-_-phenylacetate

mphamnp

2-acetamido-5-methyl-7-phenyl-1,8-naphthyridine

MPP

2-methoxyphenylphosphine

MPPIM or 4S-MPPIM

methyl 1-(3-phenylpropanoyl)-2-oxoimidazolidine-4(S)-

 

carboxylate

2-mq

anion of 2-mercaptoquinoline

mtfpa

(R)-_-methoxy-_-(trifluoromethyl)phenylacetate

mtz

2-mercaptothiazolinate

 

N

Nap

naphthyl

NaphthAZ

(R)-1-naphthalen-1-yl-ethyl 2-oxoazetidine-4(S)-carboxylate

NCPhCN

1,4-dicyanobenzene

5S-NEPY

neopentyl 2-oxopyrrolidine-5(S)-carboxylate

Nic

N-nitroxyethyl-nicotinamide

nitet

2-ethyl-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-1-oxyl-

 

3-N-oxide