- •Preface
- •Acronyms
- •Introduction
- •Background and objectives
- •Content, format and presentation
- •Radioactive waste management in context
- •Waste sources and classification
- •Introduction
- •Radioactive waste
- •Waste classification
- •Origins of radioactive waste
- •Nuclear fuel cycle
- •Mining
- •Fuel production
- •Reactor operation
- •Reprocessing
- •Reactor decommissioning
- •Medicine, industry and research
- •Medicine
- •Industry
- •Research
- •Military wastes
- •Conditioning of radioactive wastes
- •Treatment
- •Compaction
- •Incineration
- •Conditioning
- •Cementation
- •Bituminisation
- •Resin
- •Vitrification
- •Spent fuel
- •Process qualification/product quality
- •Volumes of waste
- •Inventories
- •Inventory types
- •Types of data recorded
- •Radiological data
- •Chemical data
- •Physical data
- •Secondary data
- •Radionuclides occurring in the nuclear fuel cycle
- •Simplifying the number of waste types
- •Radionuclide inventory priorities
- •Material priorities
- •Inventory evolution
- •Assumptions
- •Errors
- •Uncertainties
- •Conclusions
- •Acknowledgements
- •References
- •Development of geological disposal concepts
- •Introduction
- •Historical evolution of geological disposal concepts
- •Geological disposal
- •Definitions and comparison with near-surface disposal
- •Development of geological disposal concepts
- •Roles of the geosphere in disposal options
- •Physical stability
- •Hydrogeology
- •Geochemistry
- •Overview
- •Alternatives to geological disposal
- •Introduction
- •Politically blocked options: sub-seabed and Antarctic icecap disposal
- •Sea dumping and sub-seabed disposal
- •Antarctic icesheet disposal
- •Technically impractical options; partitioning and transmutation, space disposal and icesheet disposal
- •Partitioning and Transmutation
- •Space disposal
- •Icesheets and permafrost
- •Non-options; long-term surface storage
- •Alternatives to conventional repositories
- •Introduction
- •Alternative geological disposal concepts
- •Utilising existing underground facilities
- •Extended storage options (CARE)
- •Injection into deep aquifers and caverns
- •Deep boreholes
- •Rock melting
- •The international option: technical aspects
- •Alternative concepts: fitting the management option to future boundary conditions
- •Conclusions
- •References
- •Site selection and characterisation
- •Introduction
- •Prescriptive/geologically led
- •Sophisticated/advocacy led
- •Pragmatic/technically led
- •Centralised/geologically led
- •Conclusions to be drawn
- •Lessons to be learned (see Table 4.2)
- •Site characterisation
- •Can we define the natural environment sufficiently thoroughly?
- •Sedimentary environments
- •Hydrogeology
- •The regional hydrogeological model
- •More local hydrogeological model(s)
- •Crystalline rock environments
- •Lithology and structure
- •Hydrogeology
- •Hydrogeochemistry
- •Any geological environment
- •References
- •Repository design
- •Introduction: general framework of the design process
- •Identification of design requirements/constraints
- •Concept development
- •Major components of the disposal system and safety functions
- •A structured approach for concept development
- •Detailed design/specifications of subsystems
- •Near-field processes and design issues
- •Design approach and methodologies
- •Design confirmation and demonstration
- •Interaction with PA/SA
- •Demonstration and QA
- •Repository management
- •Future perspectives
- •References
- •Assessment of the safety and performance of a radioactive waste repository
- •Introduction
- •The role of SA and the safety case in decision-making
- •SA tasks
- •System description
- •Identification of scenarios and cases for analysis
- •Consequence analysis
- •Timescales for evaluation
- •Constructing and presenting a safety case
- •References
- •Repository implementation
- •Legal and regulatory framework; organisational structures
- •Waste management strategies
- •The need for a clear policy and strategy
- •Timetables vary widely
- •Activities in development of a geological repository
- •Concept development
- •Siting
- •Repository design
- •Licensing
- •Construction
- •Operation
- •Monitoring
- •Research and development
- •The staging process
- •Attributes of adaptive staging
- •The decision-making process
- •Status of geological disposal programmes
- •Overview
- •Status of geological disposal projects in selected countries
- •International repositories
- •Costs and financing
- •Cost estimates
- •Financing
- •Conclusions
- •Acknowledgements
- •References
- •Research and development infrastructure
- •Introduction: Management of research and development
- •Drivers for research and development
- •Organisation of R&D
- •R&D in specialised (nuclear) facilities
- •Introduction
- •Inventory
- •Release of radionuclides from waste forms
- •Solubility and sorption
- •Waste form dissolution
- •Colloids
- •Organic degradation products
- •Gas generation
- •Conventional R&D
- •Engineered barriers
- •Corrosion
- •Buffer and backfill materials
- •Container fabrication
- •Natural barriers
- •Geochemistry and groundwater flow
- •Gas transport and two-phase flow
- •Biosphere
- •Radionuclide concentration and dispersion in the biosphere
- •Climate change
- •Landscape change
- •Underground rock laboratories
- •URLs in sediments
- •Nature’s laboratories: studies of the natural environment
- •General
- •Corrosion
- •Cement
- •Clay materials
- •Degradation of organic materials
- •Glass corrosion
- •Radionuclide migration
- •Model and database development
- •Conclusions
- •References
- •Building confidence in the safe disposal of radioactive waste
- •Growing nuclear concerns
- •Communication systems in waste management programmes
- •The Swiss programme
- •The Japanese programme
- •Examples of communication styles in other countries
- •Finland
- •Sweden
- •France
- •United Kingdom
- •Comparisons between communication styles in Finland, France, Sweden and the United Kingdom
- •Lessons for the future
- •What is the way forward?
- •Acknowledgements
- •References
- •A look to the future
- •Introduction
- •Current trends in repository programmes
- •Priorities for future efforts
- •Waste characterisation
- •Operational safety
- •Emplacement technologies
- •Knowledge management
- •Alternative designs and optimisation processes
- •Materials technology
- •Novel construction/immobilisation materials: the example of low pH cement
- •Future SA code development
- •Implications for environmental protection: disposal of other wastes
- •Conclusions
- •References
- •Index
196 A. Hooper
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Fig. 8.2. Example of funding arrangements for R&D on radioactive waste disposal – note that this is only one of many funding models. For an overview of regulatory arrangements, see Table 7.1.
may include the research arm of a power utility, or even international agencies with specialised facilities. ‘‘National research agencies’’ includes institutes/laboratories for nuclear research with specialised facilities for handling radioactive materials. They may also include the national geological survey (where this exists) and institutes/laboratories for environmental research.
As indicated by Fig. 8.2, funds flow to the three kinds of R&D organisations from the waste producers and the regulator. National research agencies (often established on a non-profit basis) and universities will also receive government funding, which gives them the ability to pursue their own R&D and, hence, a degree of independence. To avoid conflicts of interest, research organisations (or, alternatively, individual researchers) are usually prevented from working for the implementers and the regulator at the same time, but this is by no means universal (see, e.g., www.jaea.go.jp).
Although there are obviously differences in the main areas of concern to most national radwaste R&D programmes (dependent, e.g., on local geological conditions or repository design), there are several common themes and these will now be examined.
8.2. R&D in specialised (nuclear) facilities
8.2.1. Introduction
One difference between radwaste R&D and ‘‘standard’’ industrial R&D is the focus on radioactive materials. Due to the unique hazards involved, it is common to use specialised facilities to allow the work to be conducted safely. Usually these facilities consist of shielded ‘‘hot cells’’ (see Fig. 8.3) for work on highly radioactive materials – e.g., significant quantities of alpha-emitting radionuclides (e.g., actinides). For less active
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Fig. 8.3. A so-called ‘‘hot cell’’ – a heavily shielded box for working on highly radioactive material. The operator can work on the box contents by means of the remotely controlled manipulators (note that the window at bottom right is made of very thick lead glass) (image courtesy of Nirex).
materials, purpose-built glove-boxes are often sufficient to both protect the operators and to provide atmosphere control for working on, e.g., the sorption of radionuclides on a reducing host rock (Fig. 8.4). Such facilities are expensive to build, operate and maintain, not least because of the need for safety and the rigorous regulatory regime that applies. The use of radioactive materials in experiments allows the application of specialised radioanalytical techniques that enable minute quantities of radioactivity to be detected. It is only by the application of such techniques, for instance, that it is possible to measure plutonium solubility values of the order of 10 10 mole dm 3.
R&D that is done in this type of facility is described in the following two sub-sections.
8.2.2. Inventory
As noted in Chapter 2, adequate knowledge of the inventory of radionuclides in the waste is essential for all phases of radioactive waste management. Many countries with significant quantities of radioactive wastes now have well developed and publicly accessible national radioactive waste inventories (e.g., Alder and McGinnes, 1994; Nirex, 2002; Andra, 2004). Usually, these have been developed and improved over many
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Fig. 8.4. Sealed glove-boxes in a radiochemistry laboratory. These are used for working on less radioactive material than is used in hot cells and have the added advantage that it is also possible to work under a controlled atmosphere (e.g., very low oxygen content for working on reducing groundwaters and rock) (image courtesy of JAEA).
years using detailed radionuclide assays in facilities at the site of origin of the waste. Where there are special requirements, samples may be sent away for analysis at specially equipped centres.
The radionuclide inventory in HLW and SF is usually derived by calculations using well-tested and validated computer programs. For other types of waste (with the exception of disused sealed sources), the diversity of the waste streams makes the task more difficult and some wastes may need to be subjected to detailed radioanalysis to measure the type and quantity of radionuclides that are present. It is a constant feature of postclosure safety assessments (key drivers for R&D – see details in Chapter 6) that the radionuclides that come closest to the regulatory targets are not ones that would be considered important for any other aspect of radioactive waste management. An example is 129I which is important to post-closure safety because of its long half-life, its mobility in the environment and its high toxicity. Conversely, radionuclides that are all-important for operational and transport safety (e.g., 60Co, 137Cs) are significantly less important as far as post-closure safety is concerned – a consequence of their relatively short half-life.
From this it can be seen that, in addition to driving the R&D programme in general, safety assessments may also drive a programme of investigation into the inventory. Furthermore it is clear that post-closure SAs may introduce a need for inventory information about radionuclides that, in other circumstances, might be given relatively little attention. As noted in Chapters 2 and 6, a consideration for the future is that changes to public policy – such as a commitment to near-zero releases of radioactivity to the environment – will also change the areas of interest in the inventory and may produce a need for additional R&D.