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Condensation nuclei

Lecture 19

Absolutely pure air

Condensation is possible only on molecules

300-400 % supersaturation is needed (see Lec.18) results obtained in Wilson cloud chamber are the same

Cloud Chamber of

Carl Anderson (ca. 1935)

http://www.orau.org/ptp/collection/miscellaneous/cloudchamber.htm

Starting condensation on molecules requeres 1200% supersaturation.

Lecture 19. Condensation

2

nuclei

 

2 types of condensation nuclei in the real atmosphere

Insoluble but moistured

Soil

Rocks

Smoke

Organic substances

etc

Soluble

Particles of salts and acids (due to coal burning)

Coal contains 0.3-20% sulfur burning SO2

SO2 H2SO4 (soluble, hygroscopical)

20 million tonns of SO2 arrive

the atm. annualy

 

As a result of earth surface airing, forest fires, volcano eruptions

 

Lecture 19. Condensation

3

nuclei

 

http://homepages.nyu.edu/~pet205/sulfur3.gif

Lecture 19. Condensation

4

nuclei

 

The above satellite image clearly demonstrates the effect of cloud condensation nuclei on cloud formation. Ships travelling the ocean off of Europe produce aerosols as they burn fuel, and those aerosols help to form low clouds in the shallow, cool, and moist layer of marine air that exists there.

Lecture 19. Condensation

5

http://www.weatherquestions.com/What_are_condensation_nuclei.htm

nuclei

plume_910612.jpg

.svg

Lecture 19. Condensation

6

nuclei

 

Spray at the Cliffs of Moher, December 2007

Water-absorbing nuclei from marine splashes, froth

NaCl 77.8%

MgCl 10.9%

Sulfur oxides of Mg (magnesium), K (potassium), Ca

Strong wind (>10 m/s) 2.7*10 10 tons of marine salt come

into atm. annually

Lecture nuclei

Nuclei distribution according to…

1. Concentration (number

per cm3 near earth surface)

At large cities – 150000

At small towns -35000

At villages -9500

Over oceans, in mountains -940

SPb -280000(RSHU measurements)

2. Their nature:

Marine origin nuclei -20%

Burning products – 40%

Soil particles -20%

Unknown origin – 20%

Lecture 19. Condensation

8

nuclei

 

Nuclei

Active

 

Passive

taking

part

in over land;

condensation

process;

 

in the

lower

part

of

a

cloud

their

number is 102 to 103 per cm3

;

over sea;

Balloon measurements

Z, km

n

0

13000

0.1-0.5

8800

0.5-1.0

3250

1.0-1.5

2540

1.5-2.0

1440

2.0-2.5

1170

2.5-3.0

640

3.0-4.0

340

Lecture 19. Condensation

9

nuclei

 

Nuclei concentration variation with height depends on thermal stratification

Day time: unstable stratification, intensive eddy exchange rate of variation is slow

Early morning: stable stratification, weak eddy exchange rate of variation is faster

n(z) n0e z / l

l is not const, ~ location

ll

"0"ground level

L=1400 m for Moscow, layer 0-3 km

L=1740 m for Moscow, layer 3-6 km

Lecture 19. Condensation

10

nuclei