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THERMODYNAMIC PROPERTIES

 

 

 

6.111

TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements

and Inorganic Compounds (

Continued

)

 

 

 

 

 

 

 

 

 

 

 

Physical

f H

f G

S

C

p

Substance

State

kJ · mol 1

kJ · mol 1

J · deg 1 · mol 1

J · deg 1

· mol 1

RbHSO

 

4

 

std. state

RbI

 

 

 

 

std. state

RbNO

2

 

RbNO

3

 

 

std. state

Rb

2 O

 

 

Rb

2 O

2

 

RbOH

 

 

 

std. state

Rb 2 PtCl6

 

std. state

RbReO

 

4

 

std. state

Rb

2 S

 

 

Rb

2 SeO

4

 

std. state

Rb

2 SO

4

 

 

std. state

Ruthenium

 

Ru

 

 

 

RuBr

3

 

RuCl 3

 

RuI

3

 

 

RuO

2

 

 

RuO

4

 

 

Samarium

 

Sm

 

 

 

Sm

3 std. state

SmCl

2

 

SmCl

3

 

 

std. state

SmF

3

 

 

SmF

· 3

1

2 H 2O

SmI

3

 

 

Sm(IO

3 )3

Sm(NO

 

3 )2

Sm

2 O

3

 

Sm

2 (SO

4 )3

Scandium

 

Sc

 

 

 

Sc

3 std. state

ScBr 3

 

ScCl 3

 

ScF

3

 

 

ScOH

 

2

 

 

 

Sc

2 O

3

 

c

1159.0

 

 

 

aq

1138.51

1039.98

253.1

 

c

333.8

328.9

118.4

53.18

aq

306.35

335.56

232.6

 

c

367.4

306.2

172.0

 

c

495.05

395.85

147.3

102.1

aq

458.52

395.30

267.8

 

c

339

 

 

 

c

472.0

 

 

 

c

418.19

 

 

 

aq

481.16

441.24

110.75

 

c

1245.6

1109.6

406

 

aq

1170.7

1056.6

464

 

c

1102.9

996.2

167

 

aq

1038.5

978.6

322.6

 

aq

469.4

482.0

228.4

 

c

1114.2

 

 

 

aq

1101.7

1009.2

297.1

 

c

1435.61

1316.96

197.44

134.06

aq

1411.60

1312.56

263.2

 

c

0

0

28.53

24.1

c

138.0

 

 

 

c

205.0

 

 

 

c

65.7

 

 

 

c

305.0

 

 

 

c

239.3

152.3

146.4

 

lq

228.5

152.3

183.3

 

c

0

0

69.58

29.54

aq

691.6

666.5

211.7

21

c

815.5

 

 

 

c

1025.9

 

 

 

aq

1193.3

1060.2

42.7

431

c

1778.0

 

 

 

c

1825.1

 

 

 

c

620.1

 

 

 

c

1381

 

 

 

c

1212.1

 

 

 

c

1823.0

1734.7

151.0

114.5

c

3899.1

 

 

 

c

0

0

34.64

25.52

aq

614.2

586.6

255.0

 

c

743.1

 

 

 

c

925.1

 

121.3

93.64

c

1629.2

1555.6

92

 

aq

861.5

801.2

134.0

 

c

1908.8

1819.41

76.99

94.2

6.112

 

 

 

SECTION

6

 

 

 

 

TABLE 6.3

Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements

 

 

 

 

and Inorganic Compounds (

Continued

)

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Physical

f H

f G

S

 

C

p

 

 

 

Substance

State

kJ · mol 1

kJ · mol 1

J · deg 1

· mol 1

J · deg 1

· mol 1

 

 

 

 

 

 

 

 

 

 

Selenium

 

 

 

 

 

 

 

 

 

Se

 

 

 

 

c

0

0

41.97

 

24.98

 

 

 

 

 

 

g

227.1

187.0

174.8

22.1

 

SeBr

2

 

 

g

21.0

 

 

 

 

 

SeCl 4

 

 

c

188.3

 

 

 

 

 

SeF

6

 

 

g

1117.0

1017.0

313.8

 

110.5

 

SeO

 

 

 

 

g

53.4

26.8

234.0

31.3

 

SeO

 

2

 

 

c

225.4

 

 

 

 

 

SeO

 

3

 

 

c

166.9

 

 

 

 

 

SeO

 

 

 

 

aq

509.2

369.9

13

 

 

 

 

32std. state

 

 

 

SeO

 

2

 

 

aq

599.2

441.4

54.0

 

 

 

 

4

 

 

 

 

 

Silicon

 

 

 

 

 

 

 

 

 

Si

 

 

 

 

c

0

0

18.81(8)

 

20.00

 

 

 

 

 

 

g

450.(8)

 

167.981(4)

 

 

 

SiBr

4

 

 

lq

457.3

433.9

277.5

 

146.4

 

 

 

 

 

 

g

415.5

431.8

377.9

 

97.1

 

SiBrCl

3

 

g

 

 

350.1

 

90.9

 

SiC alpha

 

c

62.8

60.2

16.49

 

26.76

 

 

beta

 

c

65.3

62.8

16.61

 

26.9

 

SiCl 4

 

 

lq

686.93

620.0

239.7

 

145.3

 

 

 

 

 

 

g

657.0

617.0

330.7

 

90.26

 

SiClBr

3

 

g

 

 

377.1

 

95.3

 

SiClF 3

 

 

g

1318

1280

309

 

79.4

 

SiF 4

 

 

 

g

1615.0(8)

1572.7

282.76(50)

 

73.62

 

SiH

 

4

 

 

g

34.3

56.8

204.65

 

42.83

 

SiHBr

 

3

 

g

317.6

328.5

348.6

 

80.8

 

SiHCl

3

 

lq

539.3

482.5

227.6

 

 

 

 

 

 

 

 

g

513.0

482.0

313.7

 

75.8

 

SiHF

3

 

 

g

 

 

271.9

 

60.5

 

SiH

 

2 Cl2

 

g

320.5

295.0

285.7

 

60.5

 

SiH

 

3 Cl

 

g

142

119

250.8

 

51.10

 

SiH

 

3 F

 

 

g

377

353

238.4

 

47.20

 

Si

2 H

6

 

 

g

80.3

127.2

272.7

 

80.79

 

SiI

4

 

 

 

c

189.5

191.6

258.1

 

108.0

 

 

 

 

 

 

lq

174.60

187.49

294.30

 

159.79

 

Si

3 N

4

 

 

c

743.5

642.1

101.3

 

99.5

 

SiO

 

 

 

 

g

99.6

126.4

211.6

 

29.9

 

SiO

 

2 quartz

c

910.7(10)

856.4

41.46(20)

 

44.4

 

 

high cristobalite

c

905.5

853.6

50.05

 

26.58

 

SiOF

2

 

 

g

967

951

271.3

 

53.69

 

SiS

2

 

 

 

c

213.4

212.6

80.3

 

77.5

 

Silver

 

 

 

 

 

 

 

 

 

Ag

 

 

 

 

c

0

0

42.55(20)

 

25.4

 

 

 

 

 

 

g

284.9(8)

 

172.997(4)

 

 

 

Ag

std. state

aq

105.79(8)

77.12

73.45(40)

 

21.8

 

Ag

2 in 4 M

HClO 4

aq

268.6

269.0

88

 

 

 

AgAt

 

 

 

c

45.2

 

133.1

 

55.7

 

AgBr

 

 

 

c

100.37

96.90

107.11

 

52.38

 

AgBrO

 

3

 

c

10.5

71.3

151.9

 

 

 

AgCl

 

 

 

c

127.01(5)

109.8

96.25(20)

 

50.79

 

AgClO

2

 

c

8.79

75.7

134.56

 

87.32

 

 

 

 

 

 

 

 

 

 

 

 

 

 

THERMODYNAMIC PROPERTIES

 

 

 

6.113

TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements

and Inorganic Compounds (

Continued

)

 

 

 

 

 

 

 

 

 

 

 

Physical

f H

f G

S

C

p

Substance

State

kJ · mol 1

kJ · mol 1

J · deg 1 · mol 1

J · deg 1

· mol 1

AgClO

3

AgClO

4

 

std. state

AgCN

 

 

 

Ag(CN)

 

2 std. state

Ag

2

CrO

4

Ag

2

CO

3

Ag

2

C 2 O

4

AgF

 

 

 

AgF

 

2

 

AgI

 

 

 

AgIO

 

3

 

AgN

 

3

 

Ag(NH )

3 2 std. state

AgNO

 

3

 

 

std. state

AgO

 

 

 

Ag

2

O

 

Ag

2

O 3

 

Ag

2

S argentite

Ag

3

Sb

 

AgSCN

 

 

Ag

2

Se

 

Ag

2

SO

4

 

std. state

Ag

2

Te

 

Sodium

 

 

 

Na

 

 

Na std. state

NaAg(CN)

2 std. state

NaOAc

 

 

std. state

NaAlCl4

Na3 AlCl6

NaAlF 4

Na3 AlF6

NaAlH

4

NaAlO

2

NaAl(SO

4 )2 std. state

NaAlSiO

4

NaAsO

2

std. state

Na3 AsO

4

std. state

NaAu(CN)

2

NaBF 4

std. state

NaBH 4

std. state

c

30.3

64.5

 

142.0

 

c

31.13

 

 

162.3

 

aq

23.77

68.49

 

254.8

 

c

146.0

156.9

107.19

 

66.73

aq

270.3

305.4

 

192

 

c

731.74

641.83

 

217.6

142.26

c

505.9

436.8

 

167.4

112.26

c

673.2

584.1

 

209

 

c

204.6

 

 

83.7

51.92

c

360.0

 

 

 

 

c

61.84

66.19

115.5

56.82

c

171.1

93.7

 

149.4

102.93

c

308.8

376.1

104.2

 

aq

111.29

17.24

 

245.2

 

c

124.4

33.47

 

140.92

93.05

aq

101.80

34.23

 

219.2

64.9

c

12.15

13.83

 

58.5

44.0

c

31.1

11.21

 

121.3

65.86

c

33.9

121.4

 

100.0

 

c

32.59

40.67

 

143.9

76.53

c

23.0

 

 

171.5

101.7

c

87.9

101.38

131.0

 

63

c

38

44.4

 

150.71

81.76

c

715.9

618.4

 

200.4

131.4

aq

698.10

590.36

 

165.7

251

c

37.2

43.1

 

154.8

87.5

c

0

0

 

51.30(20)

28.15

g

107.5(7)

 

 

153.718(3)

 

aq

240.34(6)

261.88

 

58.45(15)

46.4

aq

30.12

43.5

251

 

c

708.81

607.27

 

123.0

79.9

aq

726.13

631.28

 

145.6

40.2

c

1142.0

996.4

 

188.3

154.98

c

1979.0

1829

 

347.0

244.1

g

1869.0

1827.5

 

345.7

105.9

c

3361.2

3136.7

 

239.5

215.89

c

115.5

 

 

 

 

c

1137.3

1069.2

 

70.40

73.64

aq

2590

2238

 

222.6

 

c

2092.8

1978.2

 

124.3

 

c

660.53

 

 

 

 

aq

669.15

611.91

 

99.6

 

c

1540

 

 

 

 

aq

1608.50

1434.19

 

14.2

 

aq

2.1

23.9

 

230

 

c

1844.7

1750.1

 

145.31

120.3

aq

1812.1

1748.9

 

243

 

c

188.6

123.9

 

101.3

86.8

aq

199.60

147.61

 

169.5

 

6.114

 

SECTION

6

 

 

 

TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements

and Inorganic Compounds (

Continued

)

 

 

 

 

 

 

 

 

 

 

 

Physical

f H

f G

S

C

p

Substance

State

kJ · mol 1

kJ · mol 1

J · deg 1 · mol 1

J · deg 1

· mol 1

NaBO 2

 

 

 

c

977.0

std. state

aq

1012.49

NaBO 3

· 4H

2 O

c

2114.2

Na2 B 4 O

7

 

 

c

3291.1

std. state

aq

3271.1

Na2 B 4 O

7

· 10H 2 O

c

6298.6

NaBr

 

 

 

c

361.08

std. state

aq

361.66

NaBr 3

std. state

aq

370.54

NaBrO std. state

aq

384.3

NaBrO

3

 

 

c

334.09

std. state

aq

307.19

NaBrO

4

std. state

aq

227.19

Na2 [Cd(CN)

4 ]

aq

52.3

NaCl

 

 

 

c

411.2

std. state

aq

407.27

NaClO std. state

aq

347.3

NaClO

2

 

 

c

307.02

std. state

aq

306.7

NaClO

3

 

 

c

365.77

std. state

aq

344.09

NaClO

4

 

 

c

383.3

std. state

aq

369.45

NaCN

 

 

 

c

87.5

std. state

aq

89.5

Na3 [Co(NO

2 )6 ]

c

1423.0

Na2 CO

3

 

 

c

1130.7

 

 

 

 

aq

1157.4

Na2 CO

3

· H

2 O

c

1431.26

Na2 CO

3

· 10H 2 O

c

4081.32

Na2 C 2 O

4

 

 

c

1318.0

std. state

aq

1305.4

Na2 CrO

4

 

 

c

1342.2

std. state

aq

1361.39

Na2 Cr 2 O

7

 

c

1978.6

std. state

aq

1970.7

Na ethoxide

c

413.80

NaF

 

 

 

c

576.6

std. state

aq

572.75

Na3 [Fe(CN)

6 ] std. state

aq

158.6

Na4 [Fe(CN)

6 ] std. state

aq

505.0

Na formate

 

c

666.5

std. state

aq

666.67

NaH

 

 

 

c

56.34

Na2 HAsO

 

4

std. state

aq

1386.58

NaH 2 AsO

4

std. state

aq

1149.68

NaHCO

3

 

c

950.81

std. state

aq

932.11

NaHCrO

 

4

std. state

aq

1118.4

NaHF 2

 

 

 

c

920.27

std. state

aq

890.06

920.7

73.54

65.94

940.81

21.8

 

3096.0

189.0

186.8

3076.9

192.9

 

5516.6

586

614.5

349.00

86.82

51.38

365.85

141.4

95.4

368.95

274.5

 

295.4

100

 

242.6

128.9

 

243.34

220.9

 

143.93

258.57

 

16.3

439

 

384.1

72.1

50.51

393.17

115.5

90.0

298.7

100

 

 

115.9

 

244.8

160.3

 

262.34

123.4

 

269.91

221.3

 

254.9

142.3

111.3

270.50

241.0

 

76.4

115.6

70.4

89.5

153.1

 

1044.4

135.0

112.3

1051.6

61.6

 

1285.41

168.11

145.60

3428.20

564.0

550.32

 

 

142

1197.9

163.6

 

1235.0

176.61

142.13

1251.64

168.2

 

1825.1

379.9

 

546.3

51.11

46.85

540.70

45.2

60.3

56.5

447.3

 

352.63

231.0

 

600.00

103.76

82.68

613.0

151

41.4

33.55

40.02

36.39

1238.51

116.3

 

1015.16

176

 

851.0

101.7

87.61

848.72

150.2

 

1026.8

243.1

 

852.20

90.92

75.02

840.02

151.5

 

 

THERMODYNAMIC PROPERTIES

 

 

 

6.115

TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements

and Inorganic Compounds (

Continued

)

 

 

 

 

 

 

 

 

 

 

 

Physical

f H

f G

S

C

p

Substance

State

kJ · mol 1

kJ · mol 1

J · deg 1 · mol 1

J · deg 1

· mol 1

Na2 H

2 [Fe(CN) 6 ]

NaH

2 PO

4

std. state

Na2 HPO

4

std. state

Na2 H

2 P 2 O 7

NaHS

 

 

std. state

NaHSeO

3

std. state

NaHSeO

4

std. state

NaHSO

 

4

std. state

NaI

 

 

std. state

NaI 3

 

 

NaIO

3

 

std. state

NaIO

4

 

std. state

Na methoxide

std. state

NaMnO

4 std. state

Na2 MnO

4

std. state

Na2 MoO

4

std. state

Na2 Mo

2 O 7

NaN

3

 

std. state NaNH 2

NaNbO 3

std. state NaNO 2

std. state NaNO 3

std. state Na2 [Ni(CN) 4 ] NaO 2

Na2 O

Na2 O 2

NaOCN cyanate std. state

NaOH

std. state Na3 PO 4

std. state Na4 P 2 O 7

std. state

aq

24.7

134.64

335

 

c

1536.8

1386.2

127.49

116.86

aq

1536.4

1392.27

149.4

 

c

1748.1

1608.3

150.50

135.31

aq

1772.38

1613.06

84.5

 

c

2764.8

2522.5

220.20

198.15

c

237.23

 

 

 

aq

257.73

249.83

121.8

 

c

759.23

 

 

 

aq

754.67

673.41

194.1

 

c

821.40

 

 

 

aq

821.74

714.2

208.4

 

c

1125.5

992.9

113.0

 

aq

1127.46

1017.88

190.8

38

c

287.9

286.1

98.50

52.1

aq

295.31

313.47

170.3

95.8

aq

291.6

313.4

298.3

 

c

481.79

 

135.1

92.1

aq

461.50

389.95

177.4

 

c

429.28

323.09

163.0

 

aq

391.62

320.49

280

 

c

367.8

294.80

110.58

69.45

aq

433.59

332.46

17.6

 

aq

781.6

709.2

250.2

 

c

1156.0

 

 

 

aq

1134

1024.7

176

 

c

1468.12

1354.30

159.70

141.71

aq

1478.2

1360.2

145.2

 

c

2245.05

2058.19

250.6

217.15

c

21.71

93.76

96.86

76.61

aq

35.02

86.2

166.9

 

c

123.9

64.0

76.90

66.15

c

1315.9

1233.0

117

 

aq

1265.7

1194.1

155

 

c

358.65

284.60

103.8

 

aq

344.8

294.1

182.0

51.0

c

467.85

367.06

116.52

92.88

aq

447.48

373.21

205.4

40.2

aq

112.6

51.9

335

 

c

260.2

218.4

115.9

72.14

c

414.2

375.5

75.04

69.10

c

510.9

449.6

94.8

89.3

c

405.39

358.2

96.7

86.6

aq

386.2

359.4

165.7

 

c

425.6

379.4

64.4

59.5

aq

469.15

419.20

48.1

102.1

c

1917.40

1788.87

173.80

153.47

aq

1997.9

1804.6

46

 

c

3188

2969.4

270.29

241.12

aq

3231.7

2966.9

117

 

6.116

 

SECTION

6

 

 

 

TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements

and Inorganic Compounds (

Continued

)

 

 

 

 

 

 

 

 

 

 

 

Physical

f H

f G

S

C

p

Substance

State

kJ · mol 1

kJ · mol 1

J · deg 1 · mol 1

J · deg 1

· mol 1

NaReO 4

std. state

Na2 S

std. state

Na2 S 2

std. state

NaSCN

std. state

Na2 Se

 

 

 

Na2 SeO

3

 

std. state

Na2 SeO

4

 

Na2 SiF 6

 

 

Na2 SiO

3

 

 

Na2 Si 2 O

5

 

NaSnBr

3

 

NaSnCl 3

 

Na2 SO

3

 

 

std. state

Na2 SO

4

 

 

std. state

Na2 SO

4

· 10H

2 O

Na2 S 2 O

3

 

 

std. state

Na2 S 2 O

3

· 5H

2 O

Na2 S 2 O

4

dithionate

std. state

Na2 S 2 O

7

 

 

Na2 S 2 O

8

 

 

Na2 Te

 

 

 

Na2 TeO

 

4

 

Na2 TiO

3

 

 

Na2 UO 4

beta

Na3 UO 4

 

 

NaVO

3

 

 

 

std. state

Na3 VO

4

 

 

Na2 V

2 O

 

7

 

Na2 WO

4

 

Na2 [Zn(CN)

4 ]

Strontium

 

 

 

Sr

 

 

 

 

Sr 2 std. state

Sr(OAc)

 

 

2

 

Sr 3 (AsO

 

4 )2

 

SrBr

2

 

 

 

SrCl 2

std. state

Sr(ClO 4 )2

std. state

c

1057.09

953.74

151.5

133.89

aq

1027.6

956.5

260.2

 

c

364.8

349.8

83.7

82.8

aq

443.3

438.1

103.3

 

c

397.0

392

151

 

aq

450.2

444.3

146.4

 

c

170.50

 

 

 

aq

163.68

169.20

203.84

6.3

c

341.4

 

 

 

c

958.6

 

 

 

aq

989.5

893.7

130

 

c

1069.0

 

 

 

c

2909.6

2754.2

207.1

187.1

c

1554.9

1462.8

113.8

111.9

c

2470.1

2324.1

164.1

157.0

aq

615.1

608.8

310

 

aq

727.2

692.0

318

 

c

1100.8

1012.5

145.94

120.25

aq

1115.87

1010.44

87.9

 

c

1387.1

1270.2

149.6

128.2

aq

1389.51

1268.40

138.1

201

c

4327.26

3647.40

592.0

 

c

1123.0

1028.0

155

 

aq

1132.40

1046.0

184.1

 

c

2607.93

2230.1

 

 

c

1232.2

 

 

 

aq

1233.9

1124.2

209.2

 

c

1925.1

1722.1

202.1

 

aq

1825.1

1638.9

362.3

 

c

349.4

 

 

 

c

1270.7

 

 

 

c

1591.2

1496.2

121.67

125.65

c

1893.3

1777.78

166.02

146.65

c

2025.1

1901.2

198.20

173.01

c

1145.79

1064.12

113.68

97.57

aq

1128.4

1045.6

109

 

c

1757.87

1637.83

190.0

164.85

c

2918.84

2712.52

318.4

269.74

c

1544.7

1429.8

160.3

139.8

aq

138.1

77.0

343

 

c

0

0

55.0

26.79

aq

545.8

559.44

32.6

 

c

1487.4

 

 

 

c

3317.1

3080.3

255

 

c

717.6

697.1

135.1

75.3

aq

788.89

767.39

132.2

 

c

828.9

781.1

114.9

75.59

aq

880.10

821.95

80.3

 

c

762.69

 

 

 

aq

804.46

576.68

331.4

 

 

THERMODYNAMIC PROPERTIES

 

 

 

6.117

TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements

and Inorganic Compounds (

Continued

)

 

 

 

 

 

 

 

 

 

 

 

Physical

f H

f G

S

C

p

Substance

State

kJ · mol 1

kJ · mol 1

J · deg 1 · mol 1

J · deg 1

· mol 1

SrCO

 

3

SrC

2 O

4

SrF

2

 

Sr formate

SrHPO

 

4

Sr(H

2 PO 4 )2

SrI 2

 

 

std. state

Sr(IO

 

3 )2

SrMoO

4

Sr(NO

 

2 )2

Sr(NO

 

3 )2

 

std. state

SrO

 

 

SrO

2

 

Sr(OH)

2

Sr

3 (PO

4 )2

SrS

 

 

SrSe

 

 

SrSeO

3

SrSeO

4

SrSiO

 

3

Sr

2 SiO

4

SrSO

 

3

SrSO

 

4

Sr

2 TiO

4

Sulfur

 

S rhombic

 

monoclinic

S

22

 

S

2

 

 

S

8

 

 

S 2 Br 2

 

SCl 2

 

SClF 5

S 2 Cl2

 

SCN

 

 

 

SF 4

 

 

SF 6

 

 

S 2 F10

 

SO

 

 

 

SO

 

2

 

SO

 

3

 

SOCl

2

SOF

2

 

SO

 

2 Cl2

SO

 

2 ClF

SO

 

2 F2

c

1220.1

1140.1

97.1

81.42

aq

1222.9

1087.3

89.5

 

c

1370.7

 

 

 

c

1216.3

1164

82.1

70.0

c

1393.3

 

 

 

c

1821.7

1688.7

121

 

c

3134.7

 

 

 

c

558.1

557.7

159.1

77.95

aq

656.18

662.62

190.0

 

c

1019.2

855.2

234

 

c

1561.1

 

128.9

117.07

c

762.3

 

 

 

c

978.22

780.0

194.56

149.87

aq

960.52

782.12

260.2

 

c

592.0

561.9

54.4

45.0

c

654.4

 

54

79.45

c

959

881

97

74.9

c

4122.9

 

 

 

c

472.4

467

68.2

48.7

c

385.8

 

 

 

c

1047.7

 

 

 

c

1142.7

 

 

 

c

1633.9

1549.8

96.7

88.53

c

2304.6

2191.2

153.1

134.26

c

1177.0

 

 

 

c

1453.1

1341.0

117.0

107.78

aq

1455.1

1304.0

12.6

 

c

2287.4

2178.6

159.0

143.68

c

0

0

32.054(50)

22.60

c

0.360

0.070

33.03

23.23

g

277.17(15)

 

167.829(6)

 

aq

33.1

85.8

14.6

 

g

128.60(30)

 

228.167(10)

 

g

101.25

49.16

430.20

156.06

lq

13.0

 

 

 

lq

50.0

28.5

184

91.0

lq

1065.7

 

 

 

lq

59.4

39

224

124.3

aq

76.4

92.7

144.3

40.2

g

763.2

722.0

299.6

77.60

g

1220.5

1116.5

291.5

96.96

g

2064

1861

397

176.7

g

6.3

19.9

222.0

30.2

g

296.81(20)

300.13

248.223(50)

39.88

g

395.7

371.02

256.77

50.66

g

212.50

198.3

309.8

66.5

g

544

502

278.7

56.81

g

364.0

320.0

311.9

77.01

g

556

513

303

71.6

g

759

712

284.0

66.0

6.118

 

SECTION

6

 

 

 

TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements

and Inorganic Compounds (

Continued

)

 

 

 

 

 

 

 

 

 

 

 

Physical

f H

f G

S

C

p

Substance

State

kJ · mol 1

kJ · mol 1

J · deg 1 · mol 1

J · deg 1

· mol 1

SO

 

32

 

SO

 

42

 

S

2O

 

32

 

S

2O

 

42

 

S

2O

 

82

 

Tantalum Ta

TaB 2

TaBr 5 TaC Ta2 C TaCl5 TaF5 Ta2 H TaI5 TaN TaO 2 Ta2 O 5 TaOCl 3

Technetium Tc

Tc 2 O 7

Tellurium Te

TeBr 4

TeCl 4

TeF 6

TeO 2 Te(OH) 3

Terbium

Tb

Tb 3 std. state TbCl 3

std. state TbO 2

Tb 2 O 3

Tb 2 (SO 4 )3 std. state Thallium

Tl

Tl std. state Tl3 std. state TlBr

std. state TlBr 3

TlBrO 3

std. state TlCl

std. state TlCl3

std. state TlClO 3

aq

635.5

486.5

29.0

 

aq

909.34(40)

744.5

18.50(40)

293.0

aq

652.3

522.5

67.0

 

aq

753.5

600.3

92.0

 

aq

1344.7

1114.9

244.3

 

c

0

0

41.47

25.40

c

209.2

 

44.4

48.12

c

598.3

 

305.4

155.73

c

144.1

142.7

42.37

36.79

c

197.5

 

83.7

60.96

c

859.0

746

222

148

c

1903.6

 

195.0

130.46

c

32.6

69.0

79.1

90.8

c

490

 

343

155.6

c

251

 

50.6

42.1

g

201

209

280

44.0

c

2046

1911.0

143.1

135.0

g

780.7

 

361.5

98.53

c

0

0

33.47

24.27

c

1113

 

 

 

c

0

0

49.70

25.70

c

190.4

 

 

 

c

326.4

 

209

138.5

g

1318.0

 

335.77

116.90

c

322.6

270.3

79.5

63.89

aq

322.6

496.1

111.7

 

c

0

0

73.22

28.91

aq

682.8

651.9

226.0

17.0

c

997.1

 

 

 

aq

1184.1

1045.6

59.0

393.0

c

971.5

 

 

 

c

1865.2

 

 

115.9

aq

4131.7

3597.4

 

 

c

0

0

64.18

26.32

aq

5.36

32.38

125.5

 

aq

196.6

214.6

192.0

 

c

173.2

167.36

120.5

50.50

aq

116.19

136.36

207.9

 

aq

168.2

97.1

54.0

 

c

136.4

53.14

168.6

 

aq

78.2

30.5

288.7

 

c

204.10

184.93

111.30

50.92

aq

161.80

163.64

182.00

 

c

315.1

 

 

 

aq

305.0

179.1

23.0

 

aq

93.7

35.6

287.9

 

 

THERMODYNAMIC PROPERTIES

 

 

 

6.119

TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements

and Inorganic Compounds (

Continued

)

 

 

 

 

 

 

 

 

 

 

 

Physical

f H

f G

S

C

p

Substance

State

kJ · mol 1

kJ · mol 1

J · deg 1 · mol 1

J · deg 1

· mol 1

Tl2 CO

3

TlF

 

std. state

TlI

 

std. state

TlNO

3

Tl2 O

TlOH

std. state

Tl2 S

Tl2 Se

Tl2 SO

4

std. state

Thorium

 

Th

 

Th 4 std. state

ThBr

4

ThC

1.94

ThCl 4

ThF 3

 

ThF 4

 

 

undissoc; std. state

ThH

2

 

ThI

4

 

ThN

 

 

Th 3 N

4

Th(NO

3 )4

ThO

2

 

ThOCl

2

ThOF

2

Th(OH)

3

 

Th(OH)

2

2

Th 3 P 4

 

ThS

2

 

Th 2 S 3

 

Th(SO

4 )2

Thullium

Tm

 

 

Tm

3 std. state

TmCl

3

 

std. state

Tm

2 O

3

Tin

 

 

Sn white

gray

Sn 2 in aqueous HCl Sn 4 in aqueous HCl SnBr 2

c

700

 

614.6

155.2

 

c

324.6

 

 

83.3

54.77

aq

327.27

 

311.21

111.7

 

c

123.9

 

125.39

127.6

52.51

aq

49.83

83.97

236.8

 

c

243.93

 

152.46

160.7

99.50

aq

202.0

 

143.7

272.0

 

c

178.7

 

147.3

126

 

c

238.9

 

195.8

88

 

aq

224.64

 

189.66

114.6

 

c

97.1

93.7

151.0

 

c

59.0

59.0

172.0

 

c

931.8

 

830.48

230.5

 

aq

898.56

 

809.40

271.1

 

c

0

 

0

51.8(5)

27.32

g

602.(6)

 

 

190.17(5)

 

aq

769.0

 

705.1

422.6

 

c

965.3

 

927.2

230

 

c

146

 

147.7

68.49

56.69

c

1186.2

1094.1

190.4

120.3

g

1166.1

1160.6

339.2

73.3

c

2097.8

2003.4

142.05

110.7

aq

2115.0

1947.2

105

 

c

139.8

 

100.0

50.71

36.69

c

664.8

 

655.2

255

 

c

391.2

 

363.6

56.07

45.2

c

1315.0

1212.9

201

155.90

c

1441.4

 

 

 

 

c

1226.4(35)

1169.20

65.23(20)

61.76

c

1232.2

1156.0

123.4

91.25

c

1665.2

1589.5

105

 

aq

1030.1

920.5

343.0

 

aq

1282.4

1140.9

218.0

 

c

1140.2

1112.9

221.8

 

c

626.3

 

620.1

96.2

 

c

1083.7

1077.0

180

 

c

2542.6

2310.4

159.0

173.47

c

0

0

 

74.01

27.03

aq

697.9

 

661.9

243.0

25.0

c

986.6

 

 

 

 

aq

1199.1

1055.6

75.0

385.0

c

1888.7

1794.5

139.8

116.7

c

0

 

0

51.08(8)

26.99

aq

301.2(15)

 

 

168.492(4)

 

c

2.09

 

0.13

44.14

25.77

aq

8.9(10)

27.2

16.7(40)

 

aq

30.5

 

2.5

117

 

c

243.5

 

 

 

 

6.120

 

 

SECTION

6

 

 

 

 

TABLE 6.3 Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements

 

 

 

 

and Inorganic Compounds (

Continued

)

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Physical

f H

f G

S

 

C

p

 

 

 

 

Substance

State

kJ · mol 1

kJ · mol 1

J · deg 1

· mol 1

J · deg 1

· mol 1

 

 

 

 

 

 

 

 

 

 

SnBr

4

 

c

377.4

350.2

264.4

 

136.44

 

 

 

 

 

 

g

314.6

331.4

411.9

 

103.4

 

SnCl 2

 

c

325.1

 

130

 

79.33

 

 

std. state

aq

329.7

299.6

172

 

 

 

SnCl 4

 

lq

511.3

440.2

258.6

 

165.3

 

 

 

 

 

 

g

471.5

432.2

365.8

 

98.3

 

SnH

 

4

 

g

162.8

188.3

227.7

48.95

 

SnI

2

 

 

c

143.5

 

 

 

 

 

SnI

4

 

 

g

 

 

446.1

 

105.4

 

SnO tetragonal

c

280.71(20)

251.9

57.17(30)

 

44.31

 

SnO

 

2

tetragonal

c

577.63(20)

515.8

49.04(10)

 

52.59

 

Sn(OH)

 

aq

286.2

254.8

50.0

 

 

 

 

 

 

 

Sn(OH)

2

c

561.1

491.6

155.0

 

 

 

SnS

 

 

 

c

100

98.3

77.0

 

49.25

 

SnS

 

2

 

c

167.4

 

87.4

 

70.12

 

Titanium

 

 

 

 

 

 

 

 

Ti

 

 

 

 

c

0

0

30.72(10)

 

25.0

 

 

 

 

 

 

g

473.(3)

 

180.298(10)

 

 

 

TiB

 

 

 

c

160

160

35

 

29.7

 

TiB

 

2

 

c

280

275

28.5

 

44.3

 

TiBr

2

 

c

402

383

108

 

78.7

 

TiBr

3

 

c

548.5

523.8

176.6

 

101.7

 

TiBr

4

 

c

616.7

589.5

243.5

 

131.5

 

TiC

 

 

 

 

c

184

180

24.2

 

33.81

 

TiCl 2

 

c

513.8

464.4

87.4

 

69.8

 

TiCl 3

 

c

720.9

653.5

139.7

 

97.2

 

TiCl 4

 

lq

804.2

737.2

252.3

 

145.2

 

 

 

 

 

 

g

763.2(30)

726.3

353.2(40)

 

95.4

 

TiF

3

 

c

1435

1362

88

 

92

 

TiF

4

 

c

1649

1559

133.96

 

114.27

 

TiH

 

 

2

 

c

144

105.1

29.71

 

30.09

 

TiI

 

4

 

 

c

375

371.5

249.4

 

125.6

 

TiN

 

 

 

 

c

265.8

243.8

52.73

 

37.08

 

TiO

 

 

 

 

c

519.7

495.0

50.0

 

39.9

 

TiO

 

 

2

 

c

944.0(8)

888.8

50.62(30)

 

55.0

 

Ti

2 O

3

 

c

1520.9

1434.2

78.8

 

97.4

 

Ti

3 O

5

 

c

2459.4

2317.4

129.3

 

154.8

 

Tungsten

 

 

 

 

 

 

 

W

 

 

 

 

c

0

0

32.6

 

24.3

 

WBr

5

 

c

312

270

272

 

155

 

WBr

6

 

c

348.5

290.8

314

 

181.4

 

W(CO)

 

6

c

953.5

 

331.8

 

242.5

 

WCl

4

 

c

443

360

198.3

 

129.7

 

WCl

5

 

c

515

402

217.6

 

155.6

 

WCl

6

 

c

602.5

456

238.5

 

175.4

 

WF

6

 

lq

1747.7

1631.4

251.5

 

 

 

 

 

 

 

 

g

1721.7

1631.4

341.1

 

119.0

 

WO

 

 

2

 

c

589.9

533.86

50.5

 

56.1

 

WO

 

 

3

 

c

842.9

764.1

75.9

 

73.8

 

WO

 

 

2

aq

1075.7

 

 

 

 

 

 

 

4

 

 

 

 

 

 

WOCl

4

c

671

549

173

 

146

 

 

 

 

 

 

 

 

 

 

 

 

 

Соседние файлы в папке Lange's Handbook of Chemistry (15th Edition)