Lange's Handbook of Chemistry (15th Edition) / 63847 6

						THERMODYNAMIC PROPERTIES														6.81
TABLE 6.2					Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of
					Organic Compounds (	Continued	)
																		C	p
					Substance	Hm			Hv		Hs			400 K	600 K 800 K				1000 K
Triphenylmethane									100.0
Triphenylphosphine									96
Triphenylstibine										106.3
Tripropoxyborane										49.4
Tris(diethylamino)phosphine									60.7
Tris(trimethylsilyl)amine										54.4
Tropolone										83.7
Undecane						22.32		41.5		56.4	327.1		442.7			525.9			588.3
Ht		6.9		36.6
Undecanenitrile										71.1
Undecanoic acid						25.9				121.3
1-Undecene,				Ht 9.2 55.8		16.99		40.9		55.4 312.7			421.1			499.3			557.3
Uracil										126.5
Urea						15.1		87.9
( )-Valine										162.8
Vinyl acetate								34.4		34.8
Vinyl benzene										39.6
Vinylcyclohexane										39.7
4-Vinyl-1-cyclohexene							33.5		38.3
1,2-Xylene						13.61	36.2			43.4	171.7		234.2			278.8			311.1
1,3-Xylene						11.55	35.7			42.7	167.5		232.2		277.9			310.6
1,4-Xylene						16.81	35.7			42.4	166.1		230.8			276.7		309.7
TABLE 6.3					Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
					and Inorganic Compounds
					Physical	fH				fG				S					C	p
			Substance		State	kJ · mol	1			kJ · mol		1		1		· mol	1		1	· mol	1
														J · deg					J · deg
Actinium
Ac					c	0				0			56.5						27.2
Aluminum
Al					c	0				0			28.30(10)						24.4
					g	330.0(40)				289.4			164.554(4)						21.4
Al	3 std. state				aq	538.4(15)				485.3				325.(10)
Al	6 BeO		10		c	5624				5317			175.6						265.19
Al(BH			4)3		lq	16.3				145.0			289.1					194.6
AlBr		3			c	527.2				488.5			180.2						100.58
	std. state				aq	895				799				74.5
Al	4C	3			c	216				203			89
Al(CH			3 )3		lq	136.4				10.0			209.4						155.6
Al(OAc)			3		c	1892.4
AlCl		3			c	704.2				628.8			109.29						91.13
	std. state				aq	1033				878				152.3
AlCl		3	· 6H 2 O		c	2692				2269			377
AlF	3				c	1510.4(13)				1431.1			66.5(5)						75.13
	std. state				aq	1531.0				1322				363.2

6.82			SECTION	6
TABLE 6.3	Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
	and Inorganic Compounds (		Continued	)
	Physical		fH	fG		S			C	p
Substance	State	kJ · mol	1	kJ · mol	1	1	· mol	1	1	· mol	1
						J · deg			J · deg

AlF	3 · H 2 O
AlH	3
AlI	3
	std. state
AlK(SO			4)2		· 12H 2 O
AlN
Al(NO		3 )3 std. state
Al(NO		3 )3		· 6H		2 O
Al(NO		3 )3 · 9H				2 O
AlO			. state
	std2
Al	2 O 3	corundum
Al(OH)			3
Al(OH)					. state
			std4
AlP
AlPO	4 berlinite
Al	2 S 3
Al	2 Se	3
Al	2 SiO		5 andalusite
Al	2 (SO 4)3
	std. state
Al	2 Te	3
Americium
Am
Am	3
Am	4
Am	2 O	3
AmO	2
Ammonium
NH	3
undissoc; std. state
ND	3
NH std4 . state
NH	4OH undissoc;
	std. state
	ionized; std. state
NH	4OAc
	std. state
NH	4Al(SO 4)2
	std. state
NH	4AsO		2	std. state
NH	4H	2 AsO			3	std. state
NH	4H	2 AsO			4
	std. state
(NH 4)2 HAsO						4 std. state
(NH 4)3 AsO					4 std. state
NH	4Br
	std. state
NH	4BrO		3
NH	4 carbamate
NH	4Cl
	std. state
NH	4ClO		3	std. state

c	2297	2052	209
c	46.0		30.0	40.2
c	313.8	300.8	159.0	98.7
aq	699	640	12.1
c	6061.8	5141.7	687.4	651.0
c	318.1	287.0	20.14	30.10
aq	1155	820	117.6
c	2850.5	2203.9	467.8	433.0
c	3757.1	2929.6	569
aq	930.9	830.9	36.8
c	1675.7(13)	1582.3	50.92(10)	79.15
c	1284	1306	71	93.1
aq	1502.5	1305.3	102.9
c	166.5
c	1733.8	1618.0	90.79	93.18
c	724.0	640	116.85	105.06
c	565
c	2592.0	2444.8	93.2	122.76
c	3435	3507	239.3	259.4
aq	3790	3205	583.3
c	326
c	0	0	62.7
aq	682.8	671.5	159.0
aq	511.7	461.1	372
c	1757	1678	154.7
c	1005.0	950.2	96.2
g	45.94(35)	16.4	192.776(5)	35.65
aq	80.29	26.57	111.3
g	58.6	26.0	203.9	38.23
aq	133.26(25)	79.37	111.17(40)	79.9
aq	361.2	254.0	165.5
aq	362.50	236.65	102.5	68.6
c	616.14
aq	618.52	448.78	200.0	73.6
c	2352.2	2038.4	216.3	226.44
aq	2481	2054	168.2
aq	561.54	429.41	154.8
c	847.30	666.60	223.8
c	1059.8	833.0	172.05	151.17
aq	1042.07	832.66	230.5
aq	1171.1	873.20	225.1
aq	1286.7	886.63	177.4
c	271.8	175.2	113.0	96.0
aq	254.05	183.34	194.97	61.9
aq	199.58	60.84	275.10
c	657.60	448.07	133.5
c	314.5	202.9	94.6	84.1
aq	299.66	210.62	169.9	56.5
aq	236.48	87.40	275.7

THERMODYNAMIC PROPERTIES

6.83

TABLE 6.3

Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements

and Inorganic Compounds (

Continued

)

Physical

fH

fG

S

C

p

Substance

State

kJ · mol

1

kJ · mol

1

1

· mol

1

1

· mol

1

J · deg

J · deg

NH	4ClO	4
std. state
NH	4CN
std. state
NH	4CNO cyanate
std. state
(NH	4)2 CO		3	std. state
(NH	4)2 C	2 O	4 oxalate
(NH	4)2 CrO		4
std. state
(NH	4)2 Cr 2 O			7
NH	4 dithiocarbonate
NH	4F
std. state
NH	4 formate std. state
NH	4HCO	3
NH	4I
std. state
NH	4IO 3
std. state
NH	4N 3	azide
NH	4NO	2
NH	4NO	3
std. state
NH	4H 2 PO		4
std. state
(NH	4)2 HPO			4
std. state
NH	4H 3 P	2 O	7
NH	4HS
NH	4HSO	3
NH	4HSO	4
std. state
(NH	4)3 PO 4
std. state
(NH	4)4P 2 O		7	std. state
(NH	4)2 PtCl		6
NH	4ReO	4
(NH	4)2 S
NH	4SCN
NH	4HSeO		4 std. state
(NH	4)2 SeO		4
(NH	4)2 SiF 6
(NH	4)2 SO		3
(NH	4)2 SO		4
std. state
(NH	4)2 S 2 O		8
std. state
NH	4VO	3

c	295.3
aq	261.84
c	0.4
aq	18.0
aq	278.7
aq	942.15
c	1123.0
c	1167.3
aq	1144.3
aq	1755.2
c	126.8
c	463.96
aq	465.14
aq	558.06
c	849.4
aq	824.5
c	201.4
aq	187.69
c	385.8
aq	354.0
c	115.5
aq	142.7
aq	237.2
c	365.56
aq	339.87
c	1145.07
aq	1428.79
c	1556.91
aq	1557.16
aq	2409.1
c	156.9
aq	150.2
aq	758.7
c	1026.96
aq	1019.85
c	1671.9
aq	1674.9
aq	2801.2
c	803.3
c	945.6
aq	231.8
aq	56.1
aq	714.2
aq	864.0
c	2681.69
aq	900.4
c	1180.9
aq	1174.28
c	1648.08
aq	1610.0
c	1053.1

88.8	186.2	128.1
87.99	295.4
		134.0

92.9207.5

177.0 220.1

686.64 169.9

		226.0
886.59	277.0
1459.5	488.7
348.78	71.97	65.27
358.19	99.6	26.8
430.5	205.0	7.9
665.9	120.9
666.1	204.6
112.5	117.0	81.8
130.96	224.7	62.3

207.5 231.8

274.1112.6

268.6221.3

111.6	236.4	17.6
184.01	151.08	139.3
190.71	259.8	6.7
1210.56	151.96	142.26
1209.76	203.8
	188.0
1248.00	193.3
2102.6	326.0
50.6	97.5
67.2	176.1
607.0	253.1
835.38	245.2	3.8
1256.9	117
2236.8	335
		237.7
774.9	232.6
72.8	212.1
13.4	257.7	39.7
531.6	262.8
599.8	280.7
2365.3	280.24	228.11
645.0	197.5
901.70	220.1	187.49
903.37	246.9	133.1
1273.6	471.1
888.3	140.6	129.33

6.84			SECTION	6
TABLE 6.3	Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
	and Inorganic Compounds (		Continued	)
	Physical		fH	fG		S			C	p
Substance	State	kJ · mol	1	kJ · mol	1	1	· mol	1	1	· mol	1
						J · deg			J · deg

Antimony

Sb
SbBr		3
SbCl		3
SbCl		5
SbF 3
SbH		3
SbI	3
Sb	2 O	3
Sb	2 O	5
Sb	2 S	3
Sb	2 Te		3
Argon
Ar
Arsenic
As gray
AsBr		3
AsCl		3
AsF		3
AsH		3
AsI	3
AsO
		2
AsO		3
		4
As	2 O	5
As	4O	6		octahedral
As	2 S	3
Astatine
At
Barium
Ba
Ba	2 std. state
Ba(OAc)				2 acetate
	std. state
BaBr		2
	std. state
BaBr		2	· 2H 2 O
Ba(BrO				3 )2
BaC		2 O		4 oxalate
BaCl		2
BaCl		2	· 2H 2 O
Ba(ClO				3 )2
Ba(ClO				3 )2 · H 2 O
BaCO			3	witherite
BaCrO				4
BaF		2
	std. state
Ba(HCO				3 )2 std. state

c		0	0	45.7	25.2
g		262.3	222.1	180.3	20.8
c		259.4	239.3	207.1
g		194.6	223.9	372.9	80.2
c		382.0	323.7	184.1	107.9
lq		440.16	350.2	301
c		915.5
g		145.11	147.74	232.8	41.05
c		100.4		215.5	97.57
c		708.8		123.01	101.25
c		971.9	829.2	125.1	117.61
c		174.9		182.0	117.74
c	56.5		55.2	234
g		0	0	154.846(3)	20.79
c	0		0	35.1	24.64
g		130.0	159.0	363.9	79.16
lq		305.0	259.4	216.3	133.5
g		261.5	248.9	327.06	75.73
lq		821.3	774.2	181.2	126.2
g		785.8	770.8	289.1	65.6
g		66.44	68.91	222.8	38.07
c	58.2		59.4	213.05	105.77
aq		429.0	350.0	40.6
aq		888.1	648.4	162.8
c		924.87	782.3	105.4	116.5
c	1313.94		1152.52	214.2	191.29
c		169.0	168.6	163.6	116.3
c		0	0	121.3
c		0	0	62.48	28.10
aq		537.64	560.74	9.6
c	1484.5
aq	1509.67		1299.55	182.8
c		757.3	736.8	146.0	77.0
aq		780.73	768.68	174.5
c	1366.1		1230.5	226
c		752.66	577.4	243
c	1368.6
c		855.0	806.7	123.67	75.14
c	1456.9		1293.2	202.9	161.96
c		762.7
c	1691.6		1270.7	393
c	1213.0		1134.4	112.1	86.0
c	1446.0		1345.3	158.6
c	1207.1		1156.8	96.4	71.20
aq	1202.90		1118.38	17.0
aq	1921.63		1734.4	192.1

THERMODYNAMIC PROPERTIES

6.85

TABLE 6.3

Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements

and Inorganic Compounds (

Continued

)

Physical

fH

fG

S

C

p

Substance

State

kJ · mol

1

kJ · mol

1

1

· mol

1

1

· mol

1

J · deg

J · deg

Ba(H 2 PO			2 )2
BaI	2
std. state
Ba(IO		3 )2
std. state
BaMnO		4
BaMoO		4
Ba(NO		2 )2
Ba(NO		3 )2
std. state
BaO
BaO	2
Ba(OH)		2
Ba(OH)		2	· H 2 O
BaS
BaSe
BaSeO		3
BaSiF		6
BaSO		3
BaSO		4
BaTiO		3
Beryllium
Be
Be 2 std. state
BeAl	2 O 4 chrysoberyl
BeBr	2
Be 2 C
BeCl	2	form
BeCO		3
BeF	2 form
BeI	2
Be 3 N 2 cubic
BeO	form
BeO	2
	2
3BeO · B			2 O 3
Be(OH)		2	form
BeS
BeSeO		4
std. state
Be 2 SiO		4
BeSO		4
std. state
BeSO		4 · H 2 O
BeWO		4
Bismuth
Bi
BiBr	3
BiCl	3
BiH	3

c	1762.3
c	602.1	601.4	165.1	77.49
aq	648.02	663.92	232.2
c	1027.2	864.8	249.4	187.4
aq	980.3	816.7	246.4
c	1548	1439.7	138	140.6
c	1507.5	1439.7	144.3	114.7
c	768.2
c	988.0	792.6	213.8	151.38
aq	952.36	783.41	302.5
c	548.0	520.4	72.07	47.28
c	634.3
c	944.7	859.5	107	101.6
c	3342.2	2793.2	427
c	460.0	456.0	78.2	49.37
c	372
c	1040.6	968.2	167
c	1952.2	2794.1	163
c	1179.5
c	1473.19	1362.2	132.2	101.75
c	1659.8	1572.4	108.0	102.47
c	0	0	9.50(8)	16.38
g	324.(5)		136.275(3)
aq	382.8	379.7	129.7
c	2301.0	2178.5	66.29	105.38
c	353.5	337	108.0	69.4
c	91	88	16.3	43.2
c	490.4	445.6	75.81	62.43
c	1025.0		52.0	65.0
c	1026.8	979.4	53.35	51.82
c	192.5	187	121.0	71.1
c	588.3	532.9	34.13	64.36
c	609.4(25)	580.1	13.77(4)	25.56
aq	790.8	640.1	159.0
c	3105	2939	100	139.7
c	902.5	815.0	45.5	62.1
c	234.3	233.0	34.0	34.0
c	1205.2	1093.8	77.9	85.7
aq	982.0	820.9	75.7
c	2117	2003	64.19	95.6
c	1200.8	1089.4	77.97	85.70
aq	1290.0	1124.3	109.6
c	2423.75	2080.66	232.97	216.61
c	1513	1405	88.4	97.3
c	0	0	56.7	25.5
g	207.1	168.2	187.0	20.8
c	264	234	226	109
c	379.1	315.1	177.0	105.0
g	277.8

6.86			SECTION	6
TABLE 6.3	Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
	and Inorganic Compounds (		Continued	)
	Physical		fH	fG		S			C	p
Substance	State	kJ · mol	1	kJ · mol	1	1	· mol	1	1	· mol	1
						J · deg			J · deg

BiI 3

Bi 2 O 3

BiOCl

Bi 2 S 3

Bi 2 (SO 4)3

Bi 2 Te			3
Boron
B
BBr		3
B	4C
BCl		3
BF 3
BF 4 std. state
BH		3
BH
		4std. state
B	2 H	6	diborane(6)
B	5 H	9	pentaborane(9)
B	10	H 14		decaborane(14)
BN
B	3 N	3 H	6	borazine
BO
		2std. state
B	2 O	3
B(OH)
			4std. state
B	3 O	3 H	3 boroxin
B	2 S 3
Bromine
Br atomic
Br std. state
Br 2
Br 3 std. state
BrCl
BrF
BrF 3
BrF 5
BrO		std. state
BrO
		3std. state
BrO		4
Cadmium
Cd

Cd 2

CdBr 2

std. state

CdCl	2
std. state
CdCl	2	· 5/2H2 O

c	100.4	175.3
c	574.0	493.7	151.5	113.5
c	366.9	322.2	120.5
c	143.1	140.6	200.4	122.2
c	2544.3
c	78.24		260.91	152.21
c	0	0	5.90(8)	11.1
g	565.(5)		153.436(15)
lq	239.7	238.5	229.7	128.03
c	62.7	62.1	27.18	53.76
g	403.8	388.7	290.1	62.7
g	1136.0(8)	1119.4	254.42(20)	50.45
aq	1574.9	1487.0	179.9
g	100.0	111	187.9	36.22
aq	48.16	114.27	110.5
g	35.6	86.7	232.1	56.9
lq	42.7	171.8	184.2	151.13
c	29.83	212.9	234.9	221.2
c	254.4	228.4	14.80	19.72
lq	541.0	392.7	199.6
g	510	389	288.61	96.94
aq	772.37	678.94	37.24
c	1273.5(14)	1194.3	53.97(30)	62.8
aq	1344.03	1153.32	102.5
c	1262	11.56	167	98.3
c	240.6		100.0	111.7
g	111.87(12)	82.4	175.018(4)	20.8
aq	121.41(15)	103.97	82.55(20)	141.8
lq	0	0	152.21(30)	75.67
g	30.91(11)		245.468(5)
aq	130.42	107.07	215.5
g	14.6	0.96	239.91	34.98
g	93.8	109.2	229.0	32.97
lq	300.8	240.5	178.2	124.6
g	255.6	229.4	292.5	66.6
lq	458.6	351.9	225.1
g	428.9	351.6	323.2	99.6
aq	94.1	33.5	42.0
aq	67.07	18.6	161.71
aq	13.0	118.1	199.6
c	0	0	51.80(15)	25.9
g	111.80(20)		167.749(4)	20.8
aq	75.92(60)		72.8(15)
c	316.18	296.31	137.2	76.7
aq	318.99	285.52	91.6
c	391.6	343.9	115.3	74.7
aq	410.20	340.12	39.8
c	1131.94	944.08	227.2

							THERMODYNAMIC PROPERTIES								6.87
TABLE 6.3				Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
				and Inorganic Compounds (			Continued		)
					Physical		fH		fG		S			C	p
	Substance				State	kJ · mol		1	kJ · mol	1	1	· mol	1	1	· mol	1
											J · deg			J · deg
Cd(CN)		2			c		162.3
std. state					aq		225.5		267.4		115.1
CdCO	3				c		750.6		669.4		92.5
Cd(OAc)			2 std. state		aq		1047.9		816.4		100
CdF 2					c		700.4		647.7		77.4
std. state					aq		741.15		635.21		100.8
CdI 2					c		203.3		201.4		161.1			80.0
std. state					aq		186.3		180.8		149.4
CdI 4 std. state					aq		341.8		315.9		326
			2		aq		450.2		226.4		336.4
Cd(NH )3 4 std. state
Cd(NO		3 )2			c		456.3
std. state					aq		490.6		300.2		219.7
CdO					c		258.35(40)		228.7		54.8(15)			43.4
Cd(OH)		2			c		560.7		473.6		96.0
CdS					c		161.9		156.5		64.9			55.5
CdSO	4				c		933.4		822.7		123.0			99.6
std. state					aq		985.2		822.2		53.1
CdSO	4 · 8/3H2 O				c		1729.30(80)		1465.3		229.65(40)			213.3
CdSeO		4			c		633.0		531.8		164.4
std. state					aq		674.9		518.8		19.3
CdTe					c		92.5		92.0		100.0
Calcium
Ca					c		0		0		41.59(40)			25.9
					g		177.8(8)				154.887(4)
Ca 2 std. state					aq		543.0(10)		553.54		56.2(10)
Ca(OAc)			2		c		1479.5
std. state					aq		1514.73		1292.35		120.1
Ca 3 (AsO 4)2					c		3298.7		3063.1		226
Ca(BO		2 )2			c		2030.9		1924.1		104.85			103.98
CaB	4O	7			c		3360.3		3167.1		134.7			157.9
CaBr	2				c		682.8		663.6		130.0			75.04
std. state					aq		785.9		761.5		111.7
CaC	2				c		59.8		64.9		69.96			62.72
CaCl	2				c		795.4		748.8		108.4			72.9
std. state					aq		877.13		816.05		59.8
CaCl	2 · 2H 2 O				c		1402.9							738
CaCN	2	cyanamide			c		350.6
Ca(CN)		2			c		184.5
CaCO	3	calcite			c		1207.6		1129.1		91.7			83.5
aragonite					c		1207.8		1128.2		88.0			82.3
					aq		1220.0		1081.4		110.0
CaC	2 O	4			c		1360.6
CaC	2 O	4 · H 2 O			c		1674.9		1514.0		156.5			152.8
CaCrO		4			c		1379.1		1277.4		134
CaF 2					c		1228.0		1175.6		68.6			67.0
					aq		1208.1		1111.2		80.8
Ca(formate)				2	c		1386.6
CaH	2				c		181.5		142.5		41.4			41.0
CaHPO		4 · 2H 2 O			c		2403.58		2154.75		189.45			197.07
Ca(H	2 PO		2 )2	hypophosphite	c		1752.7
Ca(H	2 PO		4)2	std. state	aq		3135.41		2814.33		127.6

6.88			SECTION	6
TABLE 6.3	Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
	and Inorganic Compounds (		Continued	)
	Physical		fH	fG		S			C	p
Substance	State	kJ · mol	1	kJ · mol	1	1	· mol	1	1	· mol	1
						J · deg			J · deg

Ca(H		2 PO 4)2 · H 2 O
CaI	2
	std. state
Ca(IO		3 )2
Ca[Mg(CO				3 )2 ] dolomite
CaMoO			4
Ca	3 N	2
Ca(NO			2 )2
Ca(NO			3 )2
	std. state
CaO
Ca(OH)			2
Ca	3 P	2
Ca	3 (PO 4)2
Ca	2 P	2 O	7
Ca	10 (PO 4)6 F2
	fluoroapatite
CaS
CaSe
CaSiO			3
Ca	2 SiO		4
3CaO · SiO				2
CaSO		3 · 2H 2 O
CaSO		4
CaSO		4 ·1 ⁄2		H 2 O
CaSO		4 · 2H 2 O
Ca(VO			3 )2
CaWO			4
Carbon
C graphite
diamond
CN
(CN)		2	cyanogen
CNBr
CNCl
CNF
CNI
CNN		3	cyanogen azide
OCN
CO
CO	2
	undissoc; std. state
CO	2
	3
C 3 O 2 suboxide
COBr		2
COCl		2	phosgene
COClF
COF		2

c	3409.67	3058.42	259.8	258.82
c	533.5	528.9	142.0	77.16
aq	653.2	656.7	169.5
c	1002.5	839.3	230
c	2326.3	2163.6	155.18	157.53
c	1541.4	1434.7	122.6	114.3
c	439.3		105.0	113.0
c	741.4
c	938.2	742.8	193.3	149.37
aq	957.55	776.22	239.7
c	634.92(90)	603.3	38.1(4)	42.0
c	985.2	897.5	83.4	87.5
c	506

c	4120.8	3884.8	236.0	227.8
c	3338.8	3132.1	189.24	187.8
c	13,744	12,983	775.7	751.9
c	482.4	477.4	56.5	47.4
c	368.2	363.2	67
c	1634.9	1549.7	81.92	85.27
c	2307.5	2192.8	127.7	128.8
c	2929.2	2784.0	168.6	171.9
c	1752.7	1555.2	184	178.7
c	1425.2	1309.1	108.4	99.0
aq	1451.1	1298.1	33.1
c	1576.7	1436.8	130.5	119.4
c	2022.6	1797.5	194.1	186.0
c	2329.3	2169.7	179.1	166.8
c	1645.15	1538.50	126.40	114.14
c	0	0	5.74(10)	8.517
g	716.68(45)		158.100(3)
c	1.897	2.900	2.377	6.116
aq	150.6	172.4	94.1
g	306.7	297.2	241.9	56.9
g	186.2	165.3	248.36	46.9
g	137.95	131.02	236.2	45.0
g			224.7	41.8
c	166.2	185.0	96.2
g	225.5	196.6	256.8	48.3
c	387.4
aq	146.0	97.4	106.7
g	110.53(17)	137.16	197.660(4)	29.14
g	393.51(13)	394.39	213.785(10)	37.13
aq	413.26(20)	386.0	119.36(60)
aq	675.23(25)	527.9	50.0(10)
g	93.7	109.8	276.4	67.0
g	96.2	110.9	309.1	61.8
g	219.1	204.9	283.50	57.70
g			276.7	52.4
g	639.8	623.33	258.89	46.8

THERMODYNAMIC PROPERTIES

6.89

TABLE 6.3

Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements

and Inorganic Compounds (

Continued

)

Physical

fH

fG

S

C

p

Substance

State

kJ · mol

1

kJ · mol

1

1

· mol

1

1

· mol

1

J · deg

J · deg

COS carbonyl sulfide CS 2

CTe	2
Cerium
Ce	, fcc
Ce	3 std. state
Ce	4 std. state
CeCl		3
	std. state
CeF	3
CeI	3
Ce(NO		3 )3
CeO	2
Ce	2 O	3
CeS
Ce	2 (SO 4)3
	std. state
Ce	2 (SO 4)3 · 8H 2 O
Cesium
Cs
Cs	std. state
Cs acetate
CsBO		2
CsBr
	std. state
CsCl
	std. state
CsClO		4
Cs	2 CO	3
	std. state
CsF

std. state Cs formate

CsHCO		3
CsHF
CsHSO		4
CsI
	std. state
CsIO		3
CsNO		3
	std. state
Cs	2	O
CsOH
	std. state
Cs	2	PtCl 6 std. state
Cs	2	S
Cs	2	Se

g	142.0	166.9	231.56	41.50
lq	89.0			74.6
g	117.7	67.1	237.8	45.4
lq	164.8
c	0	0	72.0	26.9
aq	696.2	672.0	205.0
aq	537.2	503.8	301.0
c	1060.5	984.8	151.0	87.4
aq	1197.5	1065.7	38.0
c	1635.9	1556	115.1	99.3
c	669.3	674	209
c	1225.9
c	1088.7	1024.7	62.30	61.63
c	1796.2	1706.2	150.6	114.6
c	459.4	451.5	78.2	50.0
c	3954.3
aq	4176.9	3652.6	318
c	5522.9	5607.4
c	0	0	85.23(40)	32.20
lq	2.087	0.025	92.1	32.4
g	76.5(10)		175.601(3)
aq	258.00(50)	292.0	132.1(5)	10.5
aq	744.3	661.3	219.7
c	972.0	915.0	104.4	80.6
c	405.8	391.4	113.05	52.93
aq	379.8	396.0	215.5
c	442.8	414.4	101.18	52.44
aq	425.4	423.3	189.4	146.9
c	443.1	314.3	175.1	108.3
c	1139.7	1054.4	204.5	123.9
aq	1193.7	1111.9	209.2
c	553.5	525.5	92.8	51.1
aq	590.9	570.8	119.2
aq	683.8	643.0	226.0
c	966.1
c	923.8	858.9	135.2	87.3
c	1158.1
aq	1145.6	1047.9	264.8
c	346.6	340.6	123.1	52.8
aq	313.5	343.6	244.4	152.7
c	525.9	433.9		167
c	506.0	406.6	155.2
aq	465.6	403.3	279.5	99.2
c	345.8	308.2	146.9	76.0
c	417.2	370.7	98.7	67.9
aq	488.3	449.3	122.3
aq	1184.9	1066.9	485.8
aq	483.7	498.3	251.0
aq		454.8

6.90			SECTION	6
TABLE 6.3	Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements
	and Inorganic Compounds (		Continued	)
	Physical		fH	fG		S			C	p
Substance	State	kJ · mol	1	kJ · mol	1	1	· mol	1	1	· mol	1
						J · deg			J · deg

Cs		2 SO		4
		std. state
Chlorine
Cl	atomic
Cl	std. state
Cl	2
ClF
ClF		3
ClF		5
ClO
ClO		std. state
ClO		2
ClO		2 std. state
ClO		3 std. state
ClO		3 F perchloryl fluoride
ClO		4 std. state
Cl	2 O
Cl	2 O		7
Chromium
Cr
Cr		2 std. state
CrBr			2
CrCl			2
CrCl			3
Cr(CO)					6 hexacarbonyl
CrF		2
CrF		3
Cr		2 FeO			4
CrI		2
CrI		3
CrN
CrO		2
Cr		2 O	3
Cr		3 O	4
CrO		2 Cl			2
CrO		2		std. state
		4
HCrO			4 std. state
Cr O2			2		std. state
			7
Cr		2 (SO 4)3
Cobalt
Co
Co		2 std. state
Co		3 std. state
CoBr			2
		std. state
CoCl			2
		std. state
CoCO				3
CoF		2
CoF		3

c	1443.0	1323.6	211.9	134.9
aq	1425.8	1328.6	286.2
g	121.301(8)		165.190(4)
aq	167.08(10)	131.3	56.60(20)	136.4
g	0	0	233.08(10)	33.95
g	50.3	51.84	217.9	32.08
g	163.2	123.0	281.6	63.85
g	239	147	310.74	97.17
g	101.8	98.1	226.6	31.5
aq	107.1	36.8	41.8
g	102.5	120.5	256.8	42.00
aq	66.5	17.2	101.3
aq	104.0	8.0	162.3
g	23.8	48.2	279.0	64.9
aq	128.10(40)	8.62	184.0(15)
g	80.3	97.9	266.2	45.4
lq	238.1
g	1138
c	0	0	23.8	23.43
aq	143.5
c	302.1
c	395.4	356.0	115.3	71.2
c	556.5	486.1	123.0	91.8
c	1077.8		293.01	226.23
c	778.0
c	1159	1088	93.9	78.7
c	1444.7	1343.8	146.0	133.6
c	156.9
c	205.0
c	117	93	38	52.7
c	598.0
c	1140	1058.1	81.2	118.7
c	1131.0
g	538.1	501.6	329.8	84.5
aq	881.15	727.85	50.21
aq	878.22	764.84	184.1
aq	1490.3	1301.2	261.9
c	609.6		269.9	302.6
c	0	0	30.0	24.8
aq	58.2	54.4	113
aq	92	134	305
c	220.9			79.5
aq	301.3	262.3	50
c	312.5	269.8	109.2	78.49
aq	392.5	316.7	0
c	713.0
c	692	647	82.4	68.9
c	790	719	95	92