Metal-Catalysed Reactions of Hydrocarbons / 13-Reactions of the Lower Alkanes with Hydrogen

REACTIONS OF THE LOWER ALKANES WITH HYDROGEN

585

47.G.C. Bond, J. Calhoun and A.D. Hooper, J. Chem. Soc. Faraday Trans., 92 (1996) 5117.

48.G. Leclercq, L. Leclercq and R. Maurel, Bull. Soc. Chim. Belg. 88 (1979) 599.

49.J. Barbier and P. Mar´ecot, Nouv. J. Chim. 5 (1981) 393.

50.G.A. Martin, Bull. Soc. Chim. Belg. 105 (1996) 131.

51.G.A. Martin, R. Dutartre, Shibin Yuan, C. M´arquez-Alvarez and C. Miradatos, J. Catal. 177 (1998) 105.

52.G.A. Martin, J. Catal. 60 (1979) 345, 452.

53.A. Frennet, A. Crucq, L. Degols and G. Lienard, Acta Chim. Acad. Sci. Hung. 111 (1982) 499.

54.A. Frennet in: Hydrogen Effects in Catalysis (Z. Pa´al and P.G. Menon, eds.), Marcel Dekker: New York (1988), p. 399.

55.A. Frennet, L. Degols, G. Lienard and A. Crucq, J. Catal. 35 (1974) 18.

56.L. Guczi, A. Frennet and V. Ponec, Acta Chim. Hung. 112 (1983) 127.

57.S.A. Goddard, M.D. Amiridis, J.E. Rekoske, N. Cardona-Martinez and J.A. Dumesic, J. Catal. 117 (1989) 155.

58.D.F. Rudd and J.A. Dumesic, Catal. Today 10 (1991) 147.

59.R.D. Cortright, R.H. Watwe and J.A. Dumesic, J. Molec. Catal. A: Chem. 163 (2000) 91.

60.L. Guczi, B.S. Gudkov and P. T´et´enyi, J. Catal. 24 (1972) 187.

61.S. Kristyan and R.B. Timmins, J. Chem. Soc. Faraday Trans. I 83 (1987) 2825.

62.S. Kristyan and J. Szamosi, J. Chem. Soc. Faraday Trans. I 80 (1984) 1645; 84 (1988) 917.

63.S.B. Shang and C.N. Kenney, J. Catal. 134 (1992) 134.

64.G.C. Bond, Ind. Eng. Chem. Res. 36 (1997) 3173; G.C. Bond, A.D. Hooper, J.C. Slaa and A.D. Taylor, J. Catal. 163 (1996) 319.

65.G.C. Bond and R.H. Cunningham, J. Catal. 166 (1997) 172.

66.G.C. Bond and Z. Pa´al, Appl. Catal. A: Gen. 86 (1992) 1.

67.G.C. Bond, J. Molec. Catal. 81 (1993) 99.

68.G.C. Bond, F. Garin and G. Maire, Appl. Catal. 41 (1988) 313.

69.G.C. Bond and P.B. Wells, Appl. Catal. 18 (1985) 221, 225.

70.G.C. Bond, R.H. Cunningham and J.C. Slaa, Topics in Catal. 1 (1994) 19.

71.G.C. Bond, M.A. Keane, H. Kral and J.A. Lercher, Catal. Rev.- Sci. Eng. 42 (2000) 323.

72.F.G. Gault, Adv. Catal. 30 (1981) 1.

73.G.C. Bond and A. Donato, J. Chem. Soc. Faraday Trans. 89 (1993) 3129.

74.G.C. Bond and J.C. Slaa, Catal. Lett. 23 (1994) 293.

75.G.C. Bond and J.C. Slaa, J. Molec. Catal. 89 (1994) 221.

76.G.C. Bond and J.C. Slaa, J. Molec. Catal. A: Chem. 98 (1995) 81.

77.G.C. Bond and J.C. Slaa, J. Molec. Catal. A: Chem. 101 (1995) 243.

78.G.C. Bond and J.C. Slaa, J. Chem. Tech. Biotechnol. 65 (1996) 15.

79.G.C. Bond and J.C. Slaa, J. Molec. Catal. A: Chem. 106 (1996) 135.

80.A. Masson in: NATO ASI Series (J. Davenas and P.A. Rabette, eds.) Martinus Nijhoff Publishers, (1986), p. 295.

81.M. Che and C.O. Bennett, Adv. Catal. 36 (1989) 55.

82.D. Nazimek and J. Ryczkowski, React. Kinet. Catal. Lett. 40 (1989) 137, 145.

83.M.J. Yacaman and A. Gomez,´ Appl. Surf. Sci. 19 (1984) 348.

84.Y. Hadj Romdhane, B. Bellamy, V. de Gouveia, A. Masson and M. Che in: Proc. 8thInternat. Congr. Catal. Verlag Chemie: Weinheim IV (1984) 333.

85.I. Zuburtikudis and H. Saltsburg, Science 258 (1992) 1337.

86.G.C. Bond and R. Burch in: Specialist Periodical Reports: Catalysis Vol. 6 (G.C. Bond and G. Webb, eds.), Roy. Soc. Chem. (1983) 27.

87.C. Lee, L.D. Schmidt, J.F. Mounder and T.W. Rusch, J. Catal. 99 (1986) 472.

88.L.D. Schmidt and K.R. Krause, Catal. Today, 12 (1992) 269.

89.S.D. Jackson, G.J. Kelly and G. Webb, Phys. Chem. Chem. Phys. 1 (1999) 2581.

586	CHAPTER 13

90.D.E. Resasco and G.L. Haller, J. Phys. Chem. 88 (1984) 4552.

91.S.M. Davis, F. Zaera and G.A. Somorjai, J. Am. Chem. Soc. 104 (1982) 7453; J. Catal. 77 (1982) 439; 85 (1984) 206.

92.D.W. Goodman, Catal. Today, 12 (1992) 189.

93.D. Kalakkad, S.L. Anderson, A.D. Logan, J. Pena,˜ E.J. Braunschweig, C.H.F. Peden and A.K. Datye, J. Phys. Chem. 97 (1993) 1437.

94.A.K. Datye, B.F. Hegarty and D.W. Goodman, Faraday Disc. Chem. Soc. 87 (1989) 337.

95.F. Rodr´ıguez-Reinoso, I. Rodr´ıguez-Ramos, C. Moreno-Castilla, A. Guerrero-Ruiz and J.D. Lopez´ -Gonz´alez, J. Catal. 107 (1987) 1.

96.C. Moreno-Castilla, A. Porcel-Jimenez, F. Carrasco-Marin and E. Utera-Hidalgo, J. Molec. Catal. 66 (1991) 329.

97.J.C. Kempling and R.B. Anderson, Ind. Eng. Chem. Proc. Des. Dev. 11 (1972) 146; 9 (1970) 116;

98.J. Monnier and R.B. Anderson, J. Catal. 78 (1982) 419.

99.G.C. Bond, R.R. Rajaram and R. Yahya, J. Molec. Catal. 69 (1991) 359.

100.G.C. Bond, R.R. Rajaram and R. Burch, J. Phys. Chem. 90 (1986) 4877.

101.G.C. Bond and Xu Yide, J. Chem. Soc. Faraday Trans. I 80 (1984) 3103; J. Chem. Soc. Chem. Comm. (1983) 1248.

102.G.C. Bond and R. Yahya, J. Chem. Soc. Faraday Trans. I 87 (1991) 775.

103.G.C. Bond. R.R. Rajaram and R. Burch, Proc. 9thInternat. Congr. Catal., (M.J. Phillips and M. Ternan, eds.), Chem. Inst. Canada: Ottawa 3 (1988) 1130.

104.D.M. Somerville, M.S. Nashner, R.G. Nuzzo and J.R. Shapley, Catal. Lett. 46 (1997) 17.

105.K. Foger, J. Catal. 78 (1982) 406.

106.G.C. Bond, R. Yahya and B. Coq, J. Chem. Soc. Faraday Trans. 86 (1990) 2297.

107.Y. Hadj Romdhane, A. Masson, B. Bellamy, V. de Gouveia and M. Che, Compt. Rend. Acad. Sci. Paris, 303 (Ser.II) (1986) 129.

108.G.C. Bond and Yide Xu, J. Molec. Catal. 25 (1984) 141; Proc. 8thInternat. Congr. Catal., Verlag Chemie: Weinheim IV (1984) 577.

109.Z. Karpinski,´ J. Catal. 77 (1982) 118.

110.Tran Manh Tri, J. Massardier, P. Gallezot and B. Imelik, Proc. 7thInternat. Congr. Catal. (T. Seiyama and K. Tanabe, eds.), Elsevier: Amsterdam (1980) 266.

111.G.C. Bond, Discuss. Faraday Soc. 41 (1966) 200.

112.G.C. Bond, R.R. Rajaram and R. Burch, Appl. Catal. 27 (1986) 379.

113.R. Burch, G.C. Bond and R.R. Rajaram, J. Chem. Soc. Faraday Trans. I 82 (1986) 1985.

114.G.C. Bond and R. Yahya, J. Molec. Catal. 68 (1991) 243.

115.B. Coq, E. Crabb, M. Warawdeker, G.C. Bond, J.C. Slaa, S. Galvagno, L. Mercadante, J. Garc´ıa Ruiz and M.C. Sanchez Sierra, J. Molec. Catal. 99 (1994) 1.

116.G.C. Bond, B. Coq, R. Dutartre, J. Garcia Ruiz, A.D. Hooper, M. Grazia Proietti, M.C. Sanchez Sierra and J.C. Slaa, J. Catal. 161 (1996) 480.

117.M.C. Sanchez Sierra, J. Garc´ıa Ruiz, M.G. Proietti and J. Blasco, J. Molec. Catal. A: Chem. 96 (1995) 65; Physica B 208-209 (1995) 705.

118.G.C. Bond, A.D. Hooper, J.C. Slaa and A.O. Taylor, J. Catal. 163 (1996) 319.

119.Metal-Support Interactions, Sintering and Redispersion (S.A. Stevenson, J.A. Dumesic, R.T.K. Baker and E. Ruckenstein, eds.) Van Nostrand Reinhold: New York (1987).

120.E.I. Ko and R.L. Garten, J. Catal 68 (1981) 233.

121.J.B.A. Anderson, R. Burch and J.A. Cairns, J. Catal. 107 (1987) 351, 364.

122.G.C. Bond and S. Flamerz, J. Chem. Soc. Faraday Trans. I 87 (1991) 767.

123.G.C. Bond, M.R. Gelsthorpe, R.R. Rajaram and R. Yahya in: Structure and Reactivity of Surfaces (C. Morterra, A. Zecchina and G. Costa, eds.), Studies in Surface Science and Catalysis, Elsevier: Amsterdam 48 (1989) 167.

124.G.C. Bond and R. Yahya, J. Molec. Catal. 69 (1991) 75.

REACTIONS OF THE LOWER ALKANES WITH HYDROGEN

587

125.K. Ebitani, T.M. Salama and H. Hattori, J. Catal. 134 (1992) 751.

126.D. Nishio, H. Shindo and K. Kunimori, J. Catal. 151 (1995) 460.

127.K. Kunimori, Y. Doi, K. Ito and T. Ochijima, J. Chem. Soc. Chem. Comm (1986) 965.

128.K. Kunimori, H. Nakamura, Z. Hu and T. Uchijima, Appl. Catal. 53 (1989) L11.

129.K. Kunimori, T. Watasugi, Z. Hu, H. Oyanagi, M. Imai, H. Asano and T. Uchijima, Catal. Lett, 7 (1990) 337.

130.E.I. Ko, J.M. Hupp and N.J. Wagner, J. Catal. 86 (1984) 315.

131.D.E. Resasco and G.L. Haller, SSSC 11 (1982) 105.

132.Jialiang Wang, J.A. Lercher and G.L. Haller, J. Catal. 88 (1984) 18.

133.G.A. Martin, R. Dutartre and J.A. Dalmon, React. Kinet. Catal. Lett.16 (1981) 329.

134.G.-A. Martin and J.A. Dalmon, React. Kinet. Catal. Lett. 16 (1981) 35.

135.You-Jyh Lin, D.E. Resasco and G.L. Haller, J. Chem. Soc. Faraday Trans. I 83 (1987) 2091.

136.G.C. Bond and M.A. Duarte, J. Catal. 111 (1988) 189.

137.D. Kalakkad and A.K. Datye, Appl. Catal. B. 1 (1992) 191.

138.G.L. Haller, D.E. Resasco and A.J. Rouco, Faraday Disc. Chem. Soc. 72 (1981) 109.

139.G.C. Bond and Lou Hui, J. Catal. 142 (1993) 512.

140.M. Arai, S.-L. Guo, M. Shirai, Y. Nishiyama and K. Toru,¨ J. Catal. 161 (1996) 704.

141.G.C. Bond and A.D. Hooper, React. Kinet. Catal. Lett. 68 (1999) 5.

142.T.E. Hoost and J.G. Goodwin Jr. J. Catal. 130 (1991) 283.

143.B.L. Mojet, J.T. Miller, D.E. Ramaker and D.C. Koningsberger, J. Catal. 186 (1999) 373.

144.J.T. Miller, B.L. Meyers, F.S. Modica, G.S. Lane, M. Vaarkamp and D.C. Koningsberger, J. Catal. 143 (1993) 395.

145.K.-W. Huang and J.G. Ekerdt, J. Catal. 92 (1983) 232.

146.J.K.A. Clarke, Chem. Rev. 75 (1975) 291.

147.V. Ponec, Appl. Catal. A: Gen. 222 (2001) 31.

148.C.T. Campbell, Ann. Rev. Phys. Chem. 41 (1990) 775.

149.R.M. Edreva-Kardjieva and A.A. Andreev, J. Catal. 94 (1985) 97.

150.Yu. I. Yermakov, B.N. Kuznetsov and Yu. A. Ryndin, J. Catal. 42 (1976) 73.

151.G. Leclercq, A. El Gharbi and S. Pietrzyk, J. Catal. 144 (1993) 118.

152.R. Szymanski and H. Charcosset, J. Molec. Catal. 25 (1984) 337.

153.D.E. Resasco and G.L. Haller, J. Catal. 82 (1983) 279.

154.T. Uchijima, Catal. Today, 28 (1996) 105.

155.M. Sprock, X. Wu and T.S. King, J. Catal. 138 (1992) 617.

156.M.W. Smale and T.S. King, J. Catal. 120 (1990) 335.

157.M.W. Smale and T.S. King, J. Catal. 119 (1989) 441.

158.J.K. Strohl and T.S. King, J. Catal. 116 (1989) 540.

159.J.A. Dalmon and G.-A. Martin, J. Catal. 66 (1980) 214.

160.I. Alstrap, V.E. Petersen and J.R. Rostrop-Nielsen, J. Catal. 191 (2000) 401.

161.J.H. Sinfelt, J. Catal. 29 (1973) 308.

162.J.H. Sinfelt, Y.L. Lam, J.A. Cusumano and A.E. Barnett, J. Catal. 42 (1976) 227.

163.D. Garden, C. Kemball and D.A. Whan, J. Chem. Soc. Faraday Trans. I 82 (1986) 3113.

164.J.H. Sinfelt, J.L. Carter and D.J.C. Yates, J. Catal. 24 (1973) 283.

165.T.J. Plunkett and J.K.A. Clarke, J. Chem. Soc. Faraday Trans. I 68 (1972) 600.

166.Z. Karpinski,´ W. Juczczyk and J. Stachurski, J. Chem. Soc. Faraday Trans. I 81 (1985) 1447.

167.D.I. Hagen and G.A. Somorjai, J. Catal. 41 (1976) 466.

168.P.A. Sermon, K. Keryou, J.M. Thomas and G.R. Millward in: Mat. Res. Soc. Symp. Proc. 111 (1988) 13.

169.P.A. Sermon, J.M. Thomas, K. Keryou and G.R. Millward, Angew. Chem. Ind. Edn. Eng. 26 (1987) 918.

170.J.-Y. Chen, J.M. Hill, R.M. Watwe, S.G. Podkolzin and J.A. Dumesic, Catal. Lett. 60 (1991) 1.

588	CHAPTER 13

171.H. Hamada, Appl. Catal. 27 (1986) 265.

172.C. Crisafulli, R. Maggiore, G. Schembari, S. Scir´e and S. Galvagno, J. Molec. Catal. 50 (1989) 67.

173.Bin Chen and J.G. Goodwin Jr., J. Catal. 154 (1995) 1.

174.Bin Chen and J.G. Goodwin Jr. J. Catal. 158 (1996) 228.

175.F.B. Passos, M. Schmal and M.A. Vannice, J. Catal. 160 (1996) 106.

176.J. Szanyi, S. Anderson and M.T. Paffett, J. Catal. 149 (1994) 438.

177.A.D. Logan and M.T. Paffett, Proc. 10thInternat. Congr. Catal., (L. Guczi, F. Solymosi and P. T´et´enyi, eds.), Akad´emiai Kiado:´ Budapest B (1992) 1595.

178.P. M´eriaudeau, A. Thangaraj, D.F. Dutel, P. Gelin and C. Naccache, J. Catal. 163 (1996) 338;

P.M´eriaudeau, A. Thangaraj, J.F. Dutel and C. Naccache, J. Catal. 167 (1997) 180.

179.D.J. Godbey, F. Garin and G.A. Somorjai, J. Catal. 117 (1989) 144.

180.C. Betizeau, G. Leclercq, R. Maurel, C. Bolivar, H. Charcosset, R. Frety and L. Tournayan,

J.Catal. 45 (1976) 179.

181.I.H.B. Haining, C. Kemball and D.A. Whan, J. Chem. Res. 5 (1977) 170.

182.R.W. Joyner and E.S. Shpiro, Catal. Lett. 9 (1991) 233.

183.J.A. Anderson, F.K. Chong and C.H. Rochester, J. Molec Catal. A: Chem. 140 (1999) 65.

184.F.K. Chong, J.A. Anderson and C.H. Rochester, Phys. Chem. Chem. Phys. 2 (2000) 5730.

185.G. Leclercq, H. Charcosset, R. Maurel, C. Betizeau, C. Bolivar, R. Frety, D. Jaunez, H. Mendes and L. Tournayan, Bull. Soc. Chim. Belg. 88 (1979) 577.

186.G. Leclercq, A. El Gharbi, L. Gengembre, T. Romero, L. Leclercq and S. Pietrzyk, J. Catal. 148 (1994) 550.

187.G. Leclercq, S. Pietrzyk, T. Romero, A. El Gharbi, L. Gengembre, J. Grimblot, F. A¨ıssi, M. Guelton, A. Latef and L. Leclercq, Ind. Eng. Chem. Res. 36 (1997) 4015.

188.Tran Manh Tri, J. Massardier, P. Gallezot and B. Imelik J. Molec. Catal. 25 (1984) 151; J. Catal. 85 (1984) 244.

189.J.R. Shapley, W.S. Uchiyama and R.A. Scott, J. Phys. Chem. 94 (1990) 1190.

190.L. Guzci, K. Matusek and M. Eszterle, J. Catal. 60 (1979) 121.

191.J.A. Oliver and C. Kemball, Proc. Roy. Soc. A 429 (1990) 17.

192.Teik Chen Wong, L.C. Chang, G.L. Haller, J.A. Oliver, N.R. Scaife and C Kemball, J. Catal. 87 (1984) 389.

193.Teik Chen Wong, L.F. Brown, G.L. Haller and C. Kemball, J. Chem. Soc. Faraday Trans. I 77 (1981) 519.

194.M. Ichikawa, L.-F. Rao, T. Kimura and A. Fukuoka, J. Molec. Catal. 62 (1990) 15.

195.D. Garden, C. Kemball and D.A. Whan, J. Chem. Soc. Faraday Trans. I 82 (1986) 3113.

196.M. Ichikawa, Lingfen Rao, T. Ito and A. Fukuoka, Faraday Discuss. Chem. Soc. 87 (1989) 321.

197.G. Leclercq, S. Pietrzyk, L. Gengembre and L. Leclercq, Appl. Catal. 27 (1986) 299.

198.Z. Karpinski,´ Adv. Catal. 37 (1990) 45.

199.J.R. Anderson and B.G. Baker in: Chemisorption and Reactions on Metal Films (J.R. Anderson, ed.) Academic Press: London, Vol. 2 (1971), p. 64.

200.G.C. Bond, Acc. Chem. Res. 26 (1993) 490.

201.J.R. Anderson, Adv. Catal. 23 (1973) 1.

202.J.K.A. Clarke and J.J. Rooney, Adv. Catal. 25 (1976) 125.

203.A.J. Hong, A.J. Rouco, D.E. Resasco and G.L. Haller, J. Phys. Chem. 91 (1987) 2665.

204.D.J.C. Yates and J.H. Sinfelt, J. Catal. 8 (1967) 348.

205.P.K. Tsjeng and R.B. Anderson, Canad. J. Chem. Eng. 54 (1976) 101.

206.D.G. Tajbl, Ind. Eng. Chem. Proc. Des. Dev. 8 (1969) 364.

207.S. Galvagno, J. Schwank, G. Gubitosa and G.R. Tauszik, J. Chem. Soc. Faraday Trans. I, 78 (1982) 2509.

208.A. Cimino, M. Boudart and H.S. Taylor, J. Am. Chem. Soc. 58 (1954) 796.

209.G.J. Haddad and J.G. Goodwin Jr. J. Catal. 157 (1995) 25.

REACTIONS OF THE LOWER ALKANES WITH HYDROGEN

589

210.J.L. Carter, J.A. Cusumano and J.H. Sinfelt, J. Phys. Chem. 70 (1966) 2257.

211.J.R. Anderson and B.G. Baker, Proc. Roy. Soc. A 271 (1963) 402.

212.J. Barbier, A. Morales and R. Maurel, Bull. Soc. Chim. Fr. 1–2 (1978) I-31.

213.Ihl Hyun Cho, Seung Bin Park, Sung June Cho and Ryong Ryoo, J. Catal. 173 (1998) 295.

214.K.J. Blankenberg and A.K. Datye, J. Catal. 128 (1991) 186.

215.R.A. Campbell, Jie Guan and T.E. Madey, Catal. Lett. 27 (1994) 273.

216.P.A. Sermon, K.M. Keryou and F. Ahmed, Phys. Chem. Chem. Phys. 2 (2000) 5723.

217.A. S´ark´any, L. Guczi and P. T´et´enyi, Acta Chim. Acad. Sci. Hung. 96 (1978) 27.

218.M.J. Holgado and V. Rives, React. Kinet. Catal. Lett. 32 (1986) 215, 221; Appl. Catal. 41 (1988) L1.

219.K. Kunimori, H. Shindo, D. Nishio, T. Sugiyama and T. Uchijima, Bull. Chem. Soc. Japan 67 (1994) 2567.

220.T. Ichijima, Catal. Today 28 (1996) 105.

221.D. Nazimek, React. Kinet. Catal. Lett. 27 (1985) 273.

222.G.R. Gallaher, J.G. Goodwin Jr. and L. Guczi, Appl. Catal. 73 (1991) 1.

223.R. Brown and C. Kemball, J. Chem. Soc. Faraday Trans. 89 (1993) 585.

224.P. T´et´enyi, React. Kinet. Catal. Lett. 53 (1994) 369.

225.D. Kalakkad, S.L. Anderson and A.K. Datye, Proc. 10thInternat. Congr. Catal. (L. Guczi, F. Solymosi and P. T´et´enyi, eds.), Akad´emiai Kiado:´ Budapest C (1992) 2411.

226.D.R. Rainer and D.W. Goodman, J. Molec. Catal. A: Chem. 131 (1998) 259.

227.P. Mahaffey and R.S. Hansen, J. Chem. Phys. 71 (1979) 1853.

228.K.-I. Tanaka, T. Miyazaki and K. Aomura, J. Catal. 81 (1983) 328.

229.D. Nazimek and J. Ryczkowski, Appl. Catal. 26 (1986) 47.

FURTHER READING

Hydrogenolysis of lower alkanes on single metals; 34, 56, 66, 68, 198–200 Hydrogenolysis of lower alkanes on standard platinum catalysts; 3, 4, 14, 64, 65, 70, 73

Hydrogenolysis on ruthenium catalysts; 70, 74–79, 100, 101, 103, 106, 115, 117, 121, 122

Mechanism of skeletal isomerisation; 9, 21, 91, 201, 202 Hydrogenolysis on RuCu/SiO2 catalysts; 108, 156, 157, 162, 173, 203 PtRe/Al 2 O3 catalysts: industrial use; 3, 43, 65, 178–180

For further information on Arrhenius parameters and orders of reaction (mainly), see the following references:

Iron 24, 25, 208 Cobalt 24–27, 31, 209

Nickel 15, 20, 24, 25, 27, 31, 60, 89, 141, 210, 211, 224, 226, 228

Copper 27

Ruthenium 15, 24, 31, 38, 97, 99, 100, 106, 117, 156, 157, 163, 172, 173, 192, 205–207, 219, 221, 223

Rhodium 12, 15, 24, 47, 90, 93, 136, 139, 191, 204, 218, 220, 222, 225 Palladium 24, 31, 39, 109, 217, 226

Osmium 102, 181

Iridium 8, 9, 24, 31, 34, 38, 57, 102, 104, 105, 108, 181, 227

Platinum 7, 12, 15, 17, 19, 31, 32, 41, 91, 95, 110, 138, 141, 151, 152, 176, 179, 212, 216