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Московский государственный университет тонких химических технологий им. М.В. Ломоносова
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Химия и технология основного органического синтеза
Файл:
Методы выдвижения гипотез о механизмах сложных реакций.doc
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►Содержание►

Приложение 3. Стадии реакции гидрогенолиза этана

  1. M–M + CH3–CH3 CH3–CH2M + MH

  2. M–M + H2 2MH

  3. CH3–CH2M + M–M MH + MCH2–CH2M

  4. CH3–CH2M + M–M MH + CH3–CHM2

  5. MCH2–CH2M + M–M MH + MCH2–CHM2

  6. CH3–CHM2+ M–M MH + MCH2–CHM2

  7. CH3–CHM2+ M–M MH + CH3–CM3

  8. MCH2–CHM2+ M–M MH + M2CH–CHM2

  9. MCH2–CHM2+ M–M MH + MCH2–CM3

  10. CH3–CM3+ M–M MH + MCH2–CM3

  11. M2CH–CHM2+ M–M MH + M2CH–CM3

  12. MCH2–CM3+ M–M MH + M2CH–CM3

  13. M2CH–CM3+ M–M MH + M3CCM3

  14. MH + CH3–CH3 H2+ CH3–CH2M

  15. MCH2–CH2M + CH3–CH3 2CH3–CH2M

  16. CH3–CHM2+ CH3–CH3 2CH3–CH2M

  17. MCH2–CHM2+ CH3–CH3 CH3–CH2M + CH3–CHM2

  18. MCH2–CHM2+ CH3–CH3 CH3–CH2M + MCH2–CH2M

  19. CH3–CM3+ CH3–CH3 CH3–CH2M + CH3–CHM2

  20. M2CH–CHM2+ CH3–CH3 CH3–CH2M + MCH2–CHM2

  21. MCH2–CM3+ CH3–CH3 CH3–CH2M + CH3–CM3

  22. MCH2–CM3+ CH3–CH3 CH3–CH2M + MCH2–CHM2

  23. M2CH–CM3+ CH3–CH3 CH3–CH2M + MCH2–CM3

  24. M2CH–CM3+ CH3–CH3 CH3–CH2M + M2CH–CHM2

  25. M3CCM3+ CH3–CH3 CH3–CH2M + M2CH–CM3

  26. MH + CH3–CH2M H2+ MCH2–CH2M

  27. MH + CH3–CH2M H2+ CH3–CHM2

  28. MCH2–CH2M + CH3–CH2M CH3–CH2M + CH3–CHM2

  29. MCH2–CHM2+ CH3–CH2M MCH2–CH2M + CH3–CHM2

  30. MCH2–CHM2+ CH3–CH2M 2MCH2–CH2M

  31. MCH2–CHM2+ CH3–CH2M 2CH3–CHM2

  32. CH3–CM3+ CH3–CH2M MCH2–CH2M + CH3–CHM2

  33. CH3–CM3+ CH3–CH2M 2CH3–CHM2

  34. M2CH–CHM2+ CH3–CH2M MCH2–CH2M + MCH2–CHM2

  35. M2CH–CHM2+ CH3–CH2M CH3–CHM2+ MCH2–CHM2

  36. MCH2–CM3+ CH3–CH2M MCH2–CH2M + CH3–CM3

  37. MCH2–CM3+ CH3–CH2M MCH2–CH2M + MCH2–CHM2

  38. MCH2–CM3+ CH3–CH2M CH3–CHM2+ CH3–CM3

  39. MCH2–CM3+ CH3–CH2M CH3–CHM2+ MCH2–CHM2

  40. M2CH–CM3+ CH3–CH2M MCH2–CH2M + MCH2–CM3

  41. M2CH–CM3+ CH3–CH2M MCH2–CH2M + M2CH–CHM2

  42. M2CH–CM3+ CH3–CH2M CH3–CHM2+ MCH2–CM3

  43. M2CH–CM3+ CH3–CH2M CH3–CHM2+ M2CH–CHM2

  44. M3CCM3+ CH3–CH2M MCH2–CH2M + M2CH–CM3

  45. M3CCM3+ CH3–CH2M CH3–CHM2+ M2CH–CM3

  46. MCH2–CH2M + MH H2+ MCH2–CHM2

  47. MCH2–CHM2+ MCH2–CH2M CH3–CHM2+ MCH2–CHM2

  48. CH3–CM3+ MCH2–CH2M CH3–CHM2+ MCH2–CHM2

  49. M2CH–CHM2+ MCH2–CH2M 2MCH2–CHM2

  50. MCH2–CM3+ MCH2–CH2M MCH2–CHM2+ CH3–CM3

  51. MCH2–CM3+ MCH2–CH2M 2MCH2–CHM2

  52. M2CH–CM3+ MCH2–CH2M MCH2–CHM2+ MCH2–CM3

  53. M2CH–CM3+ MCH2–CH2M MCH2–CHM2+ M2CH–CHM2

  54. M3CCM3+ MCH2–CH2M MCH2–CHM2+ M2CH–CM3

  55. CH3–CHM2+ MH H2+ MCH2–CHM2

  56. CH3–CHM2+ MH H2+ CH3–CM3

  57. MCH2–CHM2+ CH3–CHM2 CH3–CHM2+ CH3–CM3

  58. M2CH–CHM2+ CH3–CHM2 2MCH2–CHM2

  59. M2CH–CHM2+ CH3–CHM2 MCH2–CHM2+ CH3–CM3

  60. MCH2–CM3+ CH3–CHM2 MCH2–CHM2+ CH3–CM3

  61. MCH2–CM3+ CH3–CHM2 2MCH2–CHM2

  62. MCH2–CM3+ CH3–CHM2 2CH3–CM3

  63. M2CH–CM3+ CH3–CHM2 MCH2–CHM2+ MCH2–CM3

  64. M2CH–CM3+ CH3–CHM2 MCH2–CHM2+ M2CH–CHM2

  65. M2CH–CM3+ CH3–CHM2 CH3–CM3+ MCH2–CM3

  66. M2CH–CM3+ CH3–CHM2 CH3–CM3+ M2CH–CHM2

  67. M3CCM3+ CH3–CHM2 MCH2–CHM2+ M2CH–CM3

  68. M3CCM3+ CH3–CHM2 CH3–CM3+ M2CH–CM3

  69. MCH2–CHM2+ MH H2+ M2CH–CHM2

  70. MCH2–CHM2+ MH H2+ MCH2–CM3

  71. M2CH–CHM2+ MCH2–CHM2 MCH2–CHM2+ MCH2–CM3

  72. MCH2–CM3+ MCH2–CHM2 CH3–CM3+ M2CH–CHM2

  73. MCH2–CM3+ MCH2–CHM2 CH3–CM3+ MCH2–CM3

  74. M2CH–CM3+ MCH2–CHM2 M2CH–CHM2+ MCH2–CM3

  75. M2CH–CM3+ MCH2–CHM2 2M2CH–CHM2

  76. M2CH–CM3+ MCH2–CHM2 2MCH2–CM3

  77. M3CCM3+ MCH2–CHM2 M2CH–CHM2+ M2CH–CM3

  78. M3CCM3+ MCH2–CHM2 MCH2–CM3+ M2CH–CM3

  79. CH3–CM3+ MH H2+ MCH2–CM3

  80. M2CH–CM3+ CH3–CM3 2MCH2–CM3

  81. M2CH–CM3+ CH3–CM3 M2CH–CHM2+ MCH2–CM3

  82. M3CCM3+ CH3–CM3 MCH2–CM3+ M2CH–CM3

  83. M2CH–CHM2+ MH H2+ M2CH–CM3

  84. M2CH–CM3+ M2CH–CHM2 MCH2–CM3+ M2CH–CM3

  85. M3CCM3+ M2CH–CHM2 2M2CH–CM3

  86. MCH2–CM3+ MH H2+ M2CH–CM3

  87. M3CCM3+ MCH2–CM3 2M2CH–CM3

  88. M2CH–CM3+ MH H2+ M3CCM3

  89. MCH2–CH3+ M–MM2CH2+ MCH3

  90. M2CH–CH3+ M–MM3CH + MCH3

  91. M3C–CH3+ M–MM4C + MCH3

  92. MCH2–CH2M + M–M2M2CH2

  93. MCH2–CHM2+ M–MM2CH2+ M3CH

  94. M2CH–CH2M + M–MM3CH + M2CH2

  95. M2CH–CHM2+ M–M2M3CH

  96. M2CH–CM3+ M–MM3CH + M4C

  97. M3C–CM3+ M–M2M4C

  98. M3CH + M–M MH + M4C

  99. M3CH + MH M–M + M2CH2

  100. M2CH2+ MH M–M + MCH3

  101. MCH3+ MH M–M + CH4

  102. M3CH + CH3–CH3 CH3–CH2M + M2CH2

  103. M4C + CH3–CH3 CH3–CH2M + M3CH

  104. M2CH2+ CH3–CH3 CH3–CH2M + MCH3

  105. MCH3+ CH3–CH3 CH3–CH2M + CH4

  106. M3CH + CH3–CH2M MCH2–CH2M + M2CH2

  107. M3CH + CH3–CH2M CH3–CHM2+ M2CH2

  108. M4C + CH3–CH2M MCH2–CH2M + M3CH

  109. M4C + CH3–CH2M CH3–CHM2+ M3CH

  110. M2CH2+ CH3–CH2M MCH2–CH2M + MCH3

  111. M2CH2+ CH3–CH2M CH3–CHM2+ MCH3

  112. MCH3+ CH3–CH2M MCH2–CH2M + CH4

  113. MCH3+ CH3–CH2M CH3–CHM2+ CH4

  114. M3CH + MCH2–CH2M MCH2–CHM2+ M2CH2

  115. M4C + MCH2–CH2M MCH2–CHM2+ M3CH

  116. M2CH2+ MCH2–CH2M MCH2–CHM2+ MCH3

  117. MCH3+ MCH2–CH2M MCH2–CHM2+ CH4

  118. M3CH + CH3–CHM2 MCH2–CHM2+ M2CH2

  119. M3CH + CH3–CHM2 CH3–CM3+ M2CH2

  120. M4C + CH3–CHM2 MCH2–CHM2+ M3CH

  121. M4C + CH3–CHM2 CH3–CM3+ M3CH

  122. M2CH2+ CH3–CHM2 MCH2–CHM2+ MCH3

  123. M2CH2+ CH3–CHM2 CH3–CM3+ MCH3

  124. MCH3+ CH3–CHM2 MCH2–CHM2+ CH4

  125. MCH3+ CH3–CHM2 CH3–CM3+ CH4

  126. M3CH + MCH2–CHM2 M2CH–CHM2+ M2CH2

  127. M3CH + MCH2–CHM2 MCH2–CM3+ M2CH2

  128. M4C + MCH2–CHM2 M2CH–CHM2+ M3CH

  129. M4C + MCH2–CHM2 MCH2–CM3+ M3CH

  130. M2CH2+ MCH2–CHM2 M2CH–CHM2+ MCH3

  131. M2CH2+ MCH2–CHM2 MCH2–CM3+ MCH3

  132. MCH3+ MCH2–CHM2 M2CH–CHM2+ CH4

  133. MCH3+ MCH2–CHM2 MCH2–CM3+ CH4

  134. M3CH + CH3–CM3 MCH2–CM3+ M2CH2

  135. M4C + CH3–CM3 MCH2–CM3+ M3CH

  136. M2CH2+ CH3–CM3 MCH2–CM3+ MCH3

  137. MCH3+ CH3–CM3 MCH2–CM3+ CH4

  138. M3CH + M2CH–CHM2 M2CH–CM3+ M2CH2

  139. M4C + M2CH–CHM2 M2CH–CM3+ M3CH

  140. M2CH2+ M2CH–CHM2 M2CH–CM3+ MCH3

  141. MCH3+ M2CH–CHM2 M2CH–CM3+ CH4

  142. M3CH + MCH2–CM3 M2CH–CM3+ M2CH2

  143. M4C + MCH2–CM3 M2CH–CM3+ M3CH

  144. M2CH2+ MCH2–CM3 M2CH–CM3+ MCH3

  145. MCH3+ MCH2–CM3 M2CH–CM3+ CH4

  146. M3CH + M2CH–CM3 M3CCM3+ M2CH2

  147. M4C + M2CH–CM3 M3CCM3+ M3CH

  148. M2CH2+ M2CH–CM3 M3CCM3+ MCH3

  149. MCH3+ M2CH–CM3 M3CCM3+ CH4

  150. M3CH + MH H2+ M4C

  151. 2M3CH M4C + M2CH2

  152. M2CH2+ M3CH M4C + MCH3

  153. MCH3+ M3CH M4C + CH4

  154. M2CH2+ MH H2+ M3CH

  155. 2M2CH2 M3CH + MCH3

  156. MCH3+ M2CH2 M3CH + CH4

  157. MCH3+ MH H2+ M2CH2

  158. 2MCH3 M2CH2+ CH4

  159. CH4+ MH H2+ MCH3

  160. MCH2–CH3+ M–HM2CH2+ CH4

  161. MCH2–CH2M + M–HM2CH2+ MCH3

  162. M3C–CH3+ M–HM4C + CH4

  163. MCH2–CHM2+ M–H2M2CH2

  164. M2CH–CH2M + M–HM3CH + MCH3

  165. M2CH–CHM2+ M–HM3CH + M2CH2

  166. M2CH–CM3+ M–H2M3CH

  167. MCH2–CH3+ M–H2MCH3

  168. M2CH–CH3+ M–HM2CH2+ MCH3

  169. M3C–CH3+ M–HM3CH + M2CH2

  170. M2CH–CH2M + M–H2M2CH2

  171. MCH2–CHM2+ M–HMCH3+ M3CH

  172. M2CH–CM3+ M–HM2CH2+ M4C

  173. M2CH–CH3+ M–HM3CH + CH4

  174. M3C–CM3+ M–HM4C + M3CH

1Подумайте, какие механизмы может генерировать программа, если такое ограничение не использовать.

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