Chen The electron capture detector

TABLES OF EVALUATED ELECTRON AFFINITIES

377

16.Heinis, T.; Chowdhury, S.; and Kebarle, P. Org. Mass Spectrom. 1993, 28, 358.

17.Chowdhury, S. and Kebarle, P. J. Amer. Chem. Soc. 1986, 108, 5453.

18.Mock, R. S. and Grimsrud, E. P. J. Amer. Chem. Soc. 1989, 111, 2861.

19.Mishima, M.; Huh, C.; Lee, H. W.; Nakamura, H.; Fujio, M.; and Tsuno, Y. 1995, 36, 2265.

20.Bartmess, J. E. J. Amer. Chem. Soc. 1980, 102, 2483.

21.Burinsky, D. J.; Fukuda, E. K.; and Campana, J. J. Amer. Chem. Soc. 1984, 106, 2270.

22.Page, F. M. and Goode, G. C. Negative Ions and the Magnetron. New York: WileyInterscience, 1969.

23.Dillow, G. W. and Kebarle, P. J. Amer. Chem. Soc. 1989, 111, 5592.

24.Sharpe, P.; Alameddin, N. G.; and Richardson, D. E. J. Amer. Chem. Soc. 1994, 116, 11098.

25.Harland, P. W. Int. J. Mass Spectrom. Ion Phys. 1977, 25, 61.

26.National Institute of Standards and Technology (NIST). Chemistry WebBook, 2003. Available at http://webbook.nist.gov.

TABLE A6.1 Bergman Dewar Set

0	Benzene	0þ	eV	42	Tetrabenz[de,h,kl,rst]-	1.70	eV
1	Naphthalene	0.16	eV		pentaphene
2	Anthracene	0.68	eV	43	Tetrabenz[de,hi,op,st]pentacene 1.68 eV
3	Tetracene	1.08	eV	44	Pyrene	0.61	eV
4	Pentacene	1.39	eV	45	Benz[e]pyrene	0.56	eV
5	Phenanthrene	0.30	eV	46	Benz[a]pyrene	0.82	eV
6	Benz[a]anthracene	0.72	eV	47	Dibenz[b,e]pyrene	1.10	eV
7	Benz[a]tetracene	1.04	eV	48	Dibenz[a,e]pyrene	0.88	eV
8	Benz[a]pentacene	1.38	eV	49	Dibenz[e,l]pyrene	0.59	eV
9	Triphenylene	0.29	eV	50	Dibenz[a,h]pyrene	1.16	eV
10	Dibenz[a,c]anthracene	0.69	eV	51	Dibenz[a,i]pyrene	1.06	eV
11	Dibenz[a,c]naphthacene	1.02	eV	52	Naphtho[2,3,b]-pyrene	0.67	eV
12	Dibenz[a,c]pentacene	1.30	eV	53	Naphtho[2,3,e]-pyrene	1.23	eV
13	Dibenz[a,h]anthracene	0.70	eV	54	Dinaphtho[a,h]pyrene	1.55	eV
14	Dibenz[a,h]naphthacene´	1.03	eV	55	Benz[x,y,z]heptaphene	1.28	eV
15	Dibenz[a,h]pentacene	1.43	eV	56	Tribenz[a,e,1]pyrene	1.03	eV
16	Chrysene	0.42	eV	57	Dibenz[cd,lm]perylene	1.25	eV
17	Ben[b]chrysene	0.89	eV	58	Tetrabenz[a,cd,j,lm]-perylene	1.18	eV
18	Dibenz[b,k]chrysene	1.05	eV	59	Dibenz[def,nmno]-chrysene	1.14	eV
19	Benz[c]phenanthrene	0.58	eV	60	Pyranthene	1.32	eV
20	Dibenz[a,j]anthracene	0.66	eV	61	Naphthocenonaphthacene	1.65	eV
21	Benz[g]chrysene	0.58	eV	62	Fluoranthene	0.82	eV
22	Tribenz[a,c,f]-anthracene	0.61	eV	63	Benz[a]fluoranthene	1.25	eV
23	Dibenz[pg,p]chrysene	0.79	eV	64	Dibenz[a,f]-fluoranthene	1.58	eV
24	Benz[c]chrysene	0.60	eV	65	Benz[b]fluoranthene	0.95	eV
25	Dibenz[b,g]phenanthrene	0.78	eV	66	Benz[j]fluoranthene	1.01	eV
26	Picene	0.54	eV	67	Benz[k]fluoranthene	0.89	eV
27	Pentaphene	0.75	eV	68	Naphtho-[2,3,j]fluoranthene	1.17	eV
28	Hexaphene	1.06	eV	69	Naphtho-[2,3,k]fluoranthene	0.90	eV
29	Benz[p]pentaphene	0.78	eV	70 s-Indenofluoranthene		1.33	eV

378		APPENDIX IV
TABLE A6.1 (Continued)
30	Dibenz[c,m]pentaphene		0.76	eV	71	Benz-indenofluoranthene	1.73	eV
31	Naphtho[2,3-c]pentaphene		0.91	eV	72	Diindenonaphthacene	2.04	eV
32	Perylene		0.98	eV	73	Biphenyl	0.13	eV
33	Benz[a]perylene		1.24	eV	74 p-Terphenyl		0.27	eV
34	Dibenz[a,j]perylene		1.45	eV	75 p-Quarterphenyl		0.41	eV
35	Dibenz[a,n]perylene		1.28	eV	76	Dibenz[de,mn]-tetracene	1.44	eV
36	Benz[g,h.i]perylene		0.89	eV	77	Benzbenz[c]phenanthrene	0.58	eV
37	Dibenz[b,pqr]perylene		0.86	eV	78	Pentabenzpentaphene	1.90	eV
38	Benz[qr]naphthopentacene		1.03	eV	79	Hexacene	1.60	eV
39	Coronene		0.80	eV	80	Styrene	0.10	eV
40	Dibenz[fg,qr]-naphthacene		1.10	eV	81	Azulene	0.84	eV
41	Dibenz[bc,hl]-coronene		1.41	eV

See Appendix II.

TABLE A6.2 Values Different from NIST Values

EVAL	NIST	Name/Formula	MW	Mtd.	Reference
		From Tables A2.1 and A2.3 CHX (in eV)
0.10(5)	—	Styrene (C8H8)	104	E	[2]
0.16(2)	0.200	Naphthalene (C10H8)	128	E	[1]
0.40(5)	0.890	Biphenylene (C12H8)	152	CI	[3]
0.42(4)	0.397	Chrysene (C18H12)	228	E	[1]
0.58(1)	0.545	Benzo[c]phenanthrene (C18H12)	228	E	[1]
0.60(5)	0.550	Anthracene, 1-methyl- (C15H12)	192	CI	[3]
0.61(2)	0.500	Pyrene (C16H10)	202	E	[1]
0.67(3)	0.591	Dibenz[a,j]anthracene (C22H14)	278	E	[1]
0.68(2)	0.530	Anthracene (C14H10)	178	E, P, T	[1, 4, 5]
0.69(3)	0.595	Dibenz[a,h]anthracene (C22H14)	278	E	[1]
0.69(3)	—	Dibenz[a,c]anthracene (C22H14)	278	E	[1]
0.72(1)	0.390	Benz[a]anthracene (C18H12)	228	E	[1]
0.80(10)	0.550	1,3,5,7-Cyclooctatetrene (C8H8)	104	E, P, T	[1, 6–8]
0.80(5)	0.403	Acenaphthylene (C12H8)	152	E	[1]
0.80(5)	0.470	Coronene (C24H12)	300	P, CI	[9, 10]
0.82(5)	0.630	Fluoranthene (C16H10)	202	E	[1]
0.84(5)	0.694	Azulene (C10H8)	128	E, P, T	[1, 11, 12]
0.2(1)	0.100	Ethene, 1,1-dichloro- (C2H2Cl2)	97	E	[1], this work
0.30(5)	0.094	Benzene, 1,2-dichloro- (C6H4Cl2)	147	E	[3], this work
0.46(5)	0.400	Trichloroethylene (C2HCl3)	131.5	E	[1, 4], this work
0.49(3)	0.340	Benzene, 1,3,5-trichloro- (C6H3Cl3)	181.5	E	[3], this work
0.70(5)	0.640	Tetrachloroethylene (C2Cl4)	166	E	[1, 4], this work
0.66(3)	0.450	Benzene, 1,2,4,5-tetrachloro-	216	E	[1, 3], this work
		(C6H2Cl4)
0.73(5)	0.434	Benzene, pentafluoro- (C6HF5)	168	E, T	[6, 7], this work
0.80(10)	0.720	1-Bromopyrene (C16H9Br)	281	E, T	[10]
0.86(2)	0.520	Benzene, hexafluoro- (C6F6)	186	E, T, P	[6, 7, 9, 11]

		TABLES OF EVALUATED ELECTRON AFFINITIES				379
TABLE A6.2 (Continued)
EVAL	NIST	Name/Formula	MW	Mtd.	Reference
0.90(10)	0.610	9-Bromoanthracene (C14H9Br)	257	CI	[10]
0.90(5)	0.729	Benzene, pentachloro- (C6HCl5)	250.5	E, T	[12]
1.0(2)	0.824	1,10-Biphenyl-decafluoro- (C12F10)	334	T	[6]
1.0(2)	0.859	Perfluorotoluene- (C7F8)	236	T	[6]
1.00(5)	0.815	Benzene, chloropentafluoro-	202.5	E, T	[6]
		(C6ClF5)
1.07(5)	1.062	Perfluoromethylcyclohexane (C7F14)	350	N, T	[14]
1.15(5)	0.915	Benzene, hexachloro- (C6Cl6)	285	E, T	[1, 12], this work
1.2(1)	0.110	Methyl iodide (CH3I)	142	A	[15, 16]
1.3(1)	1.149	Benzene, bromopentafluoro-	247	E	[6]
		(C6BrF5)
1.5(1)	1.414	Benzene, pentafluoroiodo- (C6F5I)	294	T	[6]
1.65(10)	0.622	Chloroform (CHCl3)	119.5	M, T	[11, 18]
1.8(2)	1.479	Ethane, hexachloro- (C2Cl6)	237	M	[11]
1.80(15)	0.911	Methane, bromotrifluoro- (CBrF3)	149	A	[16]
1.80(15)	1.101	Trichloromonofluoromethane (CCl3F)	137.5	A	[17, 18]
2.04(10)	0.805	Carbon tetrachloride (CCl4)	154	M, T	[11, 18]
2.20(20)	1.570	Methane, trifluoroiodo- (CF3I)	196	A	[19–21]
		From Table A3.1 CHNX (in eV)
0.50(5)	0.450	1,3,5-Triazine (C3H3N3)	144	Ered	[7]
0.95(5)	0.012	Adenine (C5H5N5)	135	DB	[1–4]
2.95(10)	3.166	Tetracyanoethylene (C6N4)	128	M, T	[13, 19]
		From Tables A4.1 and A4.3 CHOX (in eV)
0.338(2)	0.334	Acetophenone (C8H8O)	120	E	[4]
0.39(2)	0.373	Benzaldehyde, 4-methyl- (C8H8O)	120	E	[4]
0.457(5)	0.429	Benzaldehyde (C7H6O)	106	E	[4]
0.68(5)	0.620	Benzophenone (C13H10O)	1820	E, T	[1, 7–12]
0.85(5)	0.85	Ethanone, 1-(2-hydroxyphenyl)-	136	T	[11]
		(C8H8O2)
0.9(1)	0.823	Cinnamylaldehyde (C9H8O)	132	E	[1]
1.03(9)	0.971	M-phthalaldehyde (C8H6O2)	134	T	[9, 10]
1.07(9)	1.158	4-HC(O)-C6H4-COOCH3 (C9H8O3)	164	T	[9, 10]
1.30(9)	1.236	1,4-Benzenedicarboxaldehyde	134	T	[9, 10]
		(C8H6O2)
0.52(5)	0.395	Ethanone, 1-(4-fluorophenyl)-	138	E	[4]
		(C8H7FO)
0.49(3)	0.442	o-Fluoroacetophenone (C8H7FO)	138	E	[4]
0.57(5)	0.486	Benzaldehyde, 4-fluoro- (C7H5FO)	124	E	[4]
0.64(5)	0.585	Ethanone, 1-(4-chlorophenyl)-	155	E, T	[1, 9–11]
		(C8H7ClO)
0.67(5)	0.616	Acetophenone, 30-chloro- (C8H7ClO)	155	E	[4]
0.70(5)	0.620	4-Fluorobenzophenone (C13H9FO)	200	T	[9, 10, 12]
0.66(4)	0.637	Benzaldehyde, 2-fluoro- (C7H5FO)	124	E	[4]

380	APPENDIX IV
TABLE A6.2 (Continued)
EVAL	NIST	Name/Formula	MW	Mtd.	Reference
0.79(5)	0.642	20-(Trifluoromethyl)acetophenone	188	E	[4]
		(C9H7F3O)
0.68(9)	0.659	Benzaldehyde, 4-chloro- (C7H5ClO)	141	T	[9, 10]
0.71(9)	0.668	Benzaldehyde, 3-chloro- (C7H5ClO)	141	T	[9, 10]
0.85(10)	0.815	Benzaldehyde, 3-(CF3)- (C8H5F3O)	174	T	[9, 10]
0.97(10)	0.941	p-CF3C6H4CHO (C8H5F3O)	174	T	[10]
1.03(9)	0.989	3,5-Dichlorobenzaldehyde	175	T	[10]
		(C7H4Cl2O)
1.15(9)	1.106	3,5-diCl-benzophenone	251	T	[10]
		(C13H8Cl2O)
1.29(9)	1.232	3,5-Bis(CF3)benzaldehyde	242	T	[10]
		(C9H4F6O)
1.3(1)	0.77	Di-MeTerephthalate tetraCl-	332	E	this work
		(C10H6Cl4O4)
2.1(15)	1.461	Fluoro-p-benzoquinone (C6H3FO2)	126	M	[15]
		From Table A5.1 CHON (in eV)
0.56(5)	0.086	Cytosine (C4H5N3O)	111	text	this work
0.56(5)	0.230	Cytosine (C4H5N3O)	111	text	this work
0.79(5)	0.069	Thymine (C5H6N2O2)	126	text	this work
0.80(5)	0.086	Uracil (C4H4N2O2)	112	text	this work
0.90(5)	0.854	Benzene, 1,2-dimethyl-3-nitro-	151	E, T [7, 8], this work
		(C8H9NO2)
0.92(7)	0.850	4-Cyanobenzoic acid methyl ester	161	Misc.	[5, 6]
		(C9H7NO2)
1.1(1)	2.168	p-t-amyl-nitrobenzene radical	193	CI	[21]
		(C11H15NO2)
1.51(5)	—	Guanine(C5H3N5O)	149	text	this work
TABLE A6.3 Unpublished or Updated Gas Phase Values not in NIST Tables
EVAL		Name/Formula		Mtd.	Table
0.00(20)	Pyridine (C5H5N)			E	12.01
0.13(5)	C6H5F			E	11.06
0.07((5)	C6H5F*			E	11.06
0.10(5)	Styrene (C8H8)			E	10.06
0.14(5)	1,2CH3C6H4Cl			E	11.07
0.17(10)	C6H5Cl			E	11.07
0.19(5)	p-C6H4F2*			E	11.06
0.20(5)	Benzyl acetate			E	10.10
0.20(5)	Ethyl acetate			E	10.10
0.21(5)	Acetic anhydride			E	10.10
0.25(5)	p-C6H4F2			E	11.06
0.25(10)	1,2CH3C6H4Br			E, CEC	11.10
0.45(15)	CF3CHF2			E	11.05
0.26(15)	CF3CHF2*			E	11.05
0.30(10)	C6H5Br			E, CEC	11.10

	TABLES OF EVALUATED ELECTRON AFFINITIES		381
TABLE A6.3	(Continued)
EVAL	Name/Formula	Mtd.	Table
0.32(10)	Dibenzofuran (C12H8O)	E	11.13
0.38(15)	CF3CH2F	E	11.05
0.38(5)	1,4CF3C6H4Cl	E	11.07
0.40(5)	1,2,3,4-C6H2F4*	E	11.06
0.52(5)	1,2,3,4-C6H2F4	E	11.06
0.40(5)	1,2CF3C6H4C1 (possible excited state)	E, CEC	11.10
0.42(10)	Xanthene (C13H10O)	E	11.13
0.50(15)	CF3CHClF (possible excited state)	E, CEC	11.05
0.50(15)	Benzoquinoline (C13H9N)	E	12.01
0.50(10)	1,2FC6H4Br	E, CEC	11.10
0.50(15)	CHC1F2	E	11.05
0.50(5)	1,3,4-FC6H3C12	E	11.07
0.55(5)	1,2,4CF3C6H3C12	E	11.07
0.13(10)	Cytosine*** (C4H5N3O)	Est. PES	12.03
0.30(10)	Cytosine**(C4H5N3O)	Est. PES	12.03
0.45(10)	Cytosine* (C4H5N3O)	Est. PES	12.03
0.60(10)	Cytosine (C4H3N3O)	Est. PES	12.03
0.60(15)	CF3CHClF (possible excited state)	E	11.05
0.61(5)	Benzophenone-4-methoxy (C14H12O2)	E	10.09
0.64(5)	Benzophenone-4-methyl (C14H12O)	E	10.09
0.64(5)	Benzophenone-4-ethyl (C15H14O)	E	10.09
0.69(3)	Dibenz[a,c]anthracene (C22H14)	E	10.06
0.70(10)	1,3CF3C6H4Br	E, CEC	11.10
0.77(5)	m-hydroxyacetophenone	E	10.10
0.78(10)	Benzophenone-p-Cl (C13H9OC1)	E	10.09
0.12(10)	Thymine***(C5H5N2O2)	Est. PES	12.03
0.30(10)	Thymine**(C5H5N2O2)	Est. PES	12.03
0.50(10)	Thymine* (C5H5N2O2)	Est. PES	12.03
0.79(10)	Thymine (C5H5N2O2)	Est. PES	12.03
0.15(10)	Uracil*** (C4H3N2O2)	Est. PES	12.03
0.30(10)	Uracil** (C4H3N2O2)	Est. PES	12.03
0.50(10)	Uracil* (C4H3N2O2)	Est. PES	12.03
0.80(10)	Uracil (C4H3N2O2)	Est. PES	12.03
0.8(1)	Ethyl trifluroacetate	E	10.10
0.90(10)	Benzophenone-p-Br (C13H9OBr)	E	10.09
1.02(5)	CF3C5F9	NIMS	11.06
1.06(5)	CF3C6F11	NIMS	11.06
1.09(5)	3-Cl,6-Me-nitrobenzene (C7H6C1NO2)	E	10.12
1.10(20)	Benzophenone-p-I (C13H9O1)	E	10.09
1.30(15)	CH2Cl2	M	10.01
1.50(20)	Benzophenone-p-NO2 (C13H9NO3)	E	10.09
2.06 (10)	CBr4	M	10.01

E ¼ electron capture detector.

E, CEC ¼ electron capture detector and CURES-EC. M ¼ magnetron.

NIMS ¼ negative-ion mass spectrometry.

Analyze PES ¼ assign peaks found in PES spectra.First excited state.

Second excited state.

Third excited state.

382	APPENDIX IV
TABLE A6.4 Values for Adenine, Guanine, Cytosine, Uracil, Thymine, and
Their Hydrates (in eV)
EVAL	NIST	Name/Formula
1.51(5)	—	Guanine(C5H3N5O)
0.95(5)	0.012	Adenine (C5H5N5)
0.80(5)	0.086	Uracil (C4H4N2O2)
1.00(5)	0.370	H2O uracil radical anion (C4H6N2O3 )
1.20(5)	0.700	(H2O)2 uracil radical anion (C4H8N2O4 )
1.40(5)	0.940	(H2O)3 uracil radical anion (C4H10N2O5 )
0.79(5)	0.069	Thymine (C5H6N2O2)
0.99(5)	0.300	H2O thymine radical anion (C5H8N2O3 )
1.19(5)	0.570	(H2O)2 thymine radical anion (C5H10N2O4 )
1.39(5)	0.820	(H2O)3 thymine radical anion (C5H12N2O5 )
1.59(5)	1.000	(H2O)4 thymine radical anion (C5H14N2O6 )
1.79(5)	1.170	(H2O)5 thymine radical anion (C5H16N2O7 )
0.56(5)	0.086	Cytosine (C4H5N3O)
0.56(5)	0.230	Cytosine (C4H5N3O)
0.76(5)	0.320	H2O cytosine radical anion (C4H7N3O2 )
0.96(5)	0.490	(H2O)2 cytosine radical anion (C4H9N3O3 )
1.16(5)	0.690	(H2O)3 cytosine radical anion (C4H11N3O4 )
1.36(5)	0.850	(H2O)4 cytosine radical anion (C4H13N3O5 )
1.56(5)	1.040	(H2O)5 cytosine radical anion (C4H15N3O6 )

TABLE A6.5 Values for Charge Transfer Complex Acceptors not in NIST Tables

Selected	CT	Compound
1.55(5)	1.47(10)	Dimethylaminobenzoquinone
1.65(10)	1.65(10)	Tetracyanoxylene
1.66(5)	1.57(10)	2,5-Di-t-butylbenzoquinone
1.67(10)	1.67(10)	2,4-Dinitrotoluene
1.70(10)	1.70(10)	Tetrachlorophthalic anhydride
1.76(5)	1.69(10)	Methoxybenzoquinone
2.18(10)	2.18(10)	1,2,3-Trinitrobenzene
2.19(10)	2.19(10)	Pentacyanotoluene
2.19(5)	2.21(10)	Bromobenzoquinone
2.20(10)	2.20(10)	Iodobenzoquinone
2.20(5)	2.20(10)	2,3-dichloro-1,4-naphthoquinone
2.21(5)	2.29(10)	Acetylbenzoquinone
2.25(5)	2.35(10)	Di-bromo-dimethylbenzoquinone
2.30(10)	2.30(10)	Bromochloro-1,4-naphthoquinone
2.30(5)	2.22(10)	Cyanobenzoquinone
2.32(5)	2.38(10)	Trifluoromethylbenzoquinone
2.37(10)	2.37(10)	2,4,6-Trinitro-p-xylene
2.40(10)	2.40(10)	Trinitrofluorenone
2.41(10)	2.41(10)	Dibromo-1,4-naphthoquinone
2.52(10)	2.52(10)	2,4,6-Trinitroanisole
2.57(10)	2.57(10)	2,4,6-Trinitrotoluene

		TABLES OF EVALUATED ELECTRON AFFINITIES	383
TABLE A6.5	(Continued)
Selected	CT	Compound
2.59(10)	2.59(10)	1,2,4-Trinitrobenzene
2.61(10)	2.61(10)	Di-bromobenzoquinone
2.63(10)	2.63(10)	Nitrobenzoquinone
2.64(10)	2.64(10)	2,4,6-Trinitrobenzoic acid
2.66(5)	2.66(10)	2,3-dicyano-1,4-naphthoquinone
2.67(10)	2.67(10)	o-tetrachlorobenzoquinone
2.78(10)	2.78(10)	2,3-dicyanobenzoquinone
2.78(5)	2.78(10)	p-tetrabromobenzoquinone
2.81(10)	2.81(10)	1,2,3,5-Tetranitrobenzene
2.83(10)	2.83(10)	p-tetraiodobenzoquinone
2.87(10)	2.87(10)	Tetracyanobenzoquinone

The values with the lower uncertainty are the average of the charge transfer complex value and the reduction potential value.

TABLE A6.6 Values for Chlorinated Hydrocarbons from Reduction Potentials and CURES-EC (in eV) [22 and this work]

Species	Ea(E1=2)	Ea(CEC)	Difference
C6H5C1	0.17	0.10		0.07
2-C10H7C1	0.30	0.35	0.05
2,20-C12H8C12	0.37	0.60	0.23
3-C12H9C1	0.39	0.41	0.02
2-C12H9C1	0.40	0.38		0.02
4-C12H9C1	0.44	0.40		0.04
2,40-C12H8C12	0.46	0.48	0.02
1,2,4-C6H3C13	0.47	0.49	0.02
3,30-C12H8C12	0.47	0.66		0.19
4,40-C12H8C12	0.50	0.66		0.16
1,6-C10H6C12	0.51	0.50		0.01
1,2,3-C6H3C13	0.51	0.45		0.06
1,7-C10H6C12	0.52	0.49		0.03
2,4-C12H8C12	0.52	0.66	0.14
2,3-C10H6C12	0.54	0.50		0.04
2,3-C12H8C12	0.54	0.61	0.07
2,3-C12H8C12	0.54	0.61	0.07
1,5-C10H6C12	0.55	0.51		0.04
1,3-C10H6C12	0.56	0.52		0.04
1,4-C10H6C12	0.56	0.51		0.05
2,5-C12H8C12	0.56	0.66	0.10
1,2-C10H6C12	0.58	0.64	0.06
2,6-C10H6C12	0.58	0.64	0.06
2,7-C10H6C12	0.58	0.64	0.06

384 APPENDIX IV

TABLE A6.6 (Continued)

	Species	Ea(E1=2)	Ea(CEC)	Difference
	2,6,20,60-C12H6C14	0.58	0.61	0.03
	3,5-C12H8C12	0.60	0.65	0.05
	1,8-C10H6C12	0.61	0.65	0.04
	3,4-C12H8C12	0.63	0.66	0.03
	2,3,6-C12H7C13	0.66	0.70	0.04
	1,2,3,5-C6H2C14	0.68	0.70	0.02
	1,2,3,4-C6H2C14	0.73	0.72		0.01
	1,3,6-C10H5C13	0.73	0.79	0.06
	1,3,7-C10H5C13	0.73	0.78	0.05
	1,2,6-C10H5C13	0.74	0.78	0.04
	1,4,6-C10H5C13	0.74	0.77	0.03
	1,2,7-C10H5C13	0.75	0.74		0.01
	1,6,7-C10H5C13	0.76	0.76		0.00
	2,4,5-C12H7C13	0.76	0.89	0.13
	1,2,6-C10H5C13	0.78	0.75		0.03
	1,3,5-C10H5C13	0.78	0.77		0.01
	1,2,4-C10H5C13	0.80	0.75		0.05
	2,5,20,50-C12H6C14	0.80	0.80		0.00
	1,2,3-C10H5C13	0.81	0.74		0.07
	1,3,8-C10H5C13	0.82	0.77		0.05
	1,4,5-C10H5C13	0.82	0.75		0.07
	2,3,5-C12H7C13	0.82	0.83	0.01
	20,50,2,4,5-C12H5Cl5	0.83	0.78		0.05
	1,2,8-C10H5C13	0.85	0.74		0.11
	20,4060,2,4,6-C12H4C16	0.89	0.96		0.07
	3,4,5-C12H7C13	0.90	0.86		0.04
	2,3,5,6-C12H6C14	0.91	0.91		0.00
	2,3,4,6-C12H6C14	0.92	0.88		0.04
	3,4,30,40-C12H6C14	0.94	1.05		0.11
	1,2,3,7-C10H4C14	0.97	0.92		0.05
	1,2,4,6-C10H4C14	0.97	1.02	0.05
	1,3,5,7-C10H4C14	0.97	1.03	0.06
	3,5,30,50-C12H6C14	0.98	1.02	0.04
	1,4,6,7-C10H4C14	0.99	1.02	0.03
	1,2,3,5-C10H4C14	1.00	1.00		0.00
	1,2,3,4-C10H4C14	1.02	0.98		0.04
	2,3,4,5-C12H6C14	1.02	1.06	0.04
	2,3,4,5,7-C12H5C15	1.03	1.03		0.00
	1,3,5,8-C12H6C14	1.04	1.02		0.02
	20,40,50,2,4,5-C12H4C16	1.04	1.16		0.12
	1,4,5,8-C10H4C14	1.07	1.00		0.07
	1,2,3,5,7-C10H3C15	1.07	1.29	0.22
	C12Cl10	1.39	1.57	0.18
	C10C18	1.57	1.63	0.06

	TABLES OF EVALUATED ELECTRON AFFINITIES			385
TABLE A6.7 Values for Biological Compounds from Reduction Potentials
Molecule	Ea (eV)	CEC	Table
Cyanopyridine C6H5N2	1.05(5)	1.08	12.01
Hydroxyquinoline C7H8NO	0.85(5)	0.85	12.01
Purine	1.04(5)	1.05	12.06
Vitamin K	1.81(10)	1.83	12.06
1,2,4,5-Tetrazine	1.67(10)	1.67	12.06
Riboflavin	1.60(10)	1.66	12.06
1,2,4-Triazine	0.91(10)	0.89	12.06
Vitamin A acetate	0.90(10)	0.91	12.06
Vitamin A alcohol	0.75(10)	0.76	12.06
Quinoline	0.50(15)	0.45	12.06
Benzoquinoline	0.50(15)	0.55	12.01
Pyrazine	0.36(5)	0.38	12.06
Pyradazine	0.31(5)	0.33	12.06
Pyrimidine	0.20(5)	0.22	12.06
Butadiene	0.00(10)	0.00	12.05
Hexatriene	0.44(10)	0.41	12.05
Octatetrene	0.66(10)	0.64	12.05
Decapentaene	0.85(10)	0.80	12.05

Author Index

Abdoul-Carmine, H., 135, 136, 327, 328,

361

Abouaf, R., 166, 230

Achiba, Y., 191

Adams, N.G., 138

Aflatooni, K., 327

Alajajian, S.H., 138

Alameddin, N.G., 377

Albyns, K., 73, 294

Alge, E., 138

Allan, M.J., 137, 167

Allouche, A.R., 191

Almeida, D.P., 233

Altshuler, A.P., 294

Anbar, M., 327

Andersen, T., 45, 190, 352, 353

Andersson, K.T., 353

Ansdell, D.A., 191

Arnold, C.C., 354

Arnold, D.W., 192, 231

Arnold, S.T., 233, 354

Arshardi, 295

Aten, A., 360

Aubert-Frecon, M., 192

Austin, T.J., 328

Ayala, J.A., 44, 167, 230

Ayotte, P., 360

Ayres, P.W., 230

Azria, R., 167, 230

Babcock, L.M., 233

Babic, D.S., 230

Baeda, A.P.M., 102, 230

Baguenard, B., 192

Bailey, C.G., 362

Bailey, T.L., 102, 191, 231

Balling, P., 353

Bansal, K.M., 137

Barden, C.J., 134

Bartlett, R.J., 20, 263

Bartmess, J.E., 136, 377

Bass, A.D., 231

Bates, D.R., 231

Batista, V.S., 167, 230

Batten, C.F., 73, 101, 233, 263, 294, 359,

376

Bauschlicher, C.W., 230

Beauchamp, J.L., 328

Beck, D.R., 353

Becker, R.S., 43, 44, 74, 101, 265, 361, 370,

376

Belic, D.S., 230

Bengali, A.A., 354

Bengtsson, G., 328

Bennett, J.C., 328

Bennett, R.A., 102, 230

Berger, S., 370, 376

Bergman, I., 265

Berkout, V., 20, 101

Berkowitz, J., 136, 231

Berry, R.S., 135, 190

Berthold, H., 43, 327

Berzinsh, U., 353

Besler, B., 327

Biakowski, S.E., 294

Biernbaum, V.M., 232, 265

Bilodeau, R.C., 352, 353, 354

Blondel, C., 352, 353

Boesch, S.E., 134, 136

Bognar, J.A., 294, 359

Bordas, Ch., 191

Borden, W.T., 264

Boulas, P., 45, 265

Bowen, K.H., 135, 136, 231, 232, 263, 264,

327, 328, 353, 354, 376

Bowie, J.H., 328

The Electron Capture Detector and the Study of Reactions with Thermal Electrons by E. C. M. Chen and E. S. D. Chen

ISBN 0-471-32622-4 # 2004 John Wiley & Sons, Inc.

387